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Cellulose

pp 1–10 | Cite as

The effect of acid washing pretreatment on bio-oil production in fast pyrolysis of rice husk

  • Yuna Ma
  • Huiyan ZhangEmail author
  • Huaizhou Yang
  • Yaping Zhang
Original Research
  • 12 Downloads

Abstract

Rice husk is a kind of biomass feedstock with high ash content. The effect of acid washing (HCl, HF and H3PO4) on the inorganic contents in rice husk was analyzed in this study. The optimal pretreatment conditions for pyrolysis product distribution, including acid concentration, washing temperature and washing time, were investigated via pyrolysis–gas chromatography/mass spectrometry (Py–GC/MS). Compared with HF and H3PO4, HCl showed the best removal efficiency of alkali and alkaline earth metals (AAEMs) with removal efficiency up to 98% for K, 93% for Ca, 100% for Na and 91% for Mg. Acid washing could increase the yield of specific products, especially sugars. Considering economic costs and the wide range of applications, HCl is the most suitable acid for washing. In order to get the highest yield of all kinds of products, the optimal pretreatment condition of HCl washing is the concentration for 2 mol/L, washing temperature for 60 °C and washing time for 1 h.

Keywords

Biomass Bio-oil Acid-washing pretreatment Fast pyrolysis 

Notes

Acknowledgments

This work was supported by the National Nature Science Fund of China for Excellent Young Scholar (51822604, 51676045), Nature Science Fund of Jiangsu Province for Distinguished Young Scholar (BK20180014) and the Jiangsu Natural Science Foundation (BK20170081).

References

  1. Carpenter D, Westover TL, Czernik S, Jablonski W (2014) Biomass feedstocks for renewable fuel production: a review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors. Green Chem 16:384–406CrossRefGoogle Scholar
  2. Casoni AI, Hoch PM, Volpe MA, Gutierrez VS (2018) Catalytic conversion of furfural from pyrolysis of sunflower seed hulls for producing bio-based furfuryl alcohol. J Clean Prod 178:237–246CrossRefGoogle Scholar
  3. Chen D, Gao D, Capareda SC, Huang S, Wang Y (2019a) Effects of hydrochloric acid washing on the microstructure and pyrolysis bio-oil components of sweet sorghum bagasse. Biores Technol 277:37–45CrossRefGoogle Scholar
  4. Chen J, Wang X, Huang Y, Lv S, Cao X, Yun J, Cao D (2019b) Adsorption removal of pollutant dyes in wastewater by nitrogen-doped porous carbons derived from natural leaves. Eng Sci 5:30–38Google Scholar
  5. Eom IY, Kim KH, Kim JY, Lee SM, Yeo HM, Choi IG, Choi JW (2011) Characterization of primary thermal degradation features of lignocellulosic biomass after removal of inorganic metals by diverse solvents. Biores Technol 102:3437–3444CrossRefGoogle Scholar
  6. Eom IY, Kim JY, Kim TS, Lee SM, Choi D, Choi IG, Choi JW (2012) Effect of essential inorganic metals on primary thermal degradation of lignocellulosic biomass. Biores Technol 104:687–694CrossRefGoogle Scholar
  7. Fahmi R, Bridgwater AV, Darvell LI, Jones JM, Yates N, Thain S, Donnison IS (2007) The effect of alkali metals on combustion and pyrolysis of Lolium and Festuca grasses, switchgrass and willow. Fuel 86:1560–1569CrossRefGoogle Scholar
  8. Huber GW, Iborra S, Corma A (2006) Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 106:4044–4098CrossRefGoogle Scholar
  9. Janković B (2014) The pyrolysis process of wood biomass samples under isothermal experimental conditions—energy density considerations: application of the distributed apparent activation energy model with a mixture of distribution functions. Cellulose 21:2285–2314CrossRefGoogle Scholar
  10. Jensen PA, Frandsen FJ, Dam-Johansen K, Sander B (2000) Experimental investigation of the transformation and release to gas phase of potassium and chlorine during straw pyrolysis. Energy Fuels 14:1280–1285CrossRefGoogle Scholar
  11. Kabir G, Hameed BH (2017) Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals. Renew Sustain Energy Rev 70:945–967CrossRefGoogle Scholar
  12. Kawamoto H, Yamamoto D, Saka S (2008) Influence of neutral inorganic chlorides on primary and secondary char formation from cellulose. J Wood Sci 54:242–246CrossRefGoogle Scholar
  13. Khelfa A, Finqueneisel G, Auber M, Weber JV (2008) Influence of some minerals on the cellulose thermal degradation mechanisms—thermogravimetic and pyrolysis–mass spectrometry studies. J Therm Anal Calorim 92:795–799CrossRefGoogle Scholar
  14. Liu Q, Wang S, Luo Z, Cen K (2008) Catalysis mechanism study of potassium salts on cellulose pyrolysis by using TGA-FTIR analysis. J Chem Eng Jpn 41:1133–1142CrossRefGoogle Scholar
  15. Lu Q, Yang X-c, Dong C-q, Zhang Z-f, Zhang X-m, Zhu X-f (2011) Influence of pyrolysis temperature and time on the cellulose fast pyrolysis products: analytical Py–GC/MS study. J Anal Appl Pyrol 92:430–438CrossRefGoogle Scholar
  16. Lv G, Wu S, Yang G, Chen J, Liu Y, Kong F (2013) Comparative study of pyrolysis behaviors of corn stalk and its three components. J Anal Appl Pyrol 104:185–193CrossRefGoogle Scholar
  17. Müller-Hagedorn M, Bockhorn H, Krebs L, Müller U (2003) A comparative kinetic study on the pyrolysis of three different wood species. J Anal Appl Pyrol 68–69:231–249CrossRefGoogle Scholar
  18. Oudenhoven SRG, Westerhof RJM, Kersten SRA (2015) Fast pyrolysis of organic acid leached wood, straw, hay and bagasse: improved oil and sugar yields. J Anal Appl Pyrol 116:253–262CrossRefGoogle Scholar
  19. Pattiya A, Chaow-u-thai A, Rittidech S (2013) The influence of pretreatment techniques on ash content of cassava residues. Int J Green Energy 10:544–552CrossRefGoogle Scholar
  20. Patwardhan PR, Satrio JA, Brown RC, Shanks BH (2010) Influence of inorganic salts on the primary pyrolysis products of cellulose. Biores Technol 101:4646–4655CrossRefGoogle Scholar
  21. Raveendran K, Ganesh A, Khilar KC (1995) Influence of mineral matter on biomass pyrolysis characteristics. Fuel 74:1812–1822CrossRefGoogle Scholar
  22. Stefanidis SD, Heracleous E, Patiaka DT, Kalogiannis KG, Michailof CM, Lappas AA (2015) Optimization of bio-oil yields by demineralization of low quality biomass. Biomass Bioenerg 83:105–115CrossRefGoogle Scholar
  23. Tan H, Wang S (2009) Experimental study of the effect of acid-washing pretreatment on biomass pyrolysis. J Fuel Chem Technol 37:668–672CrossRefGoogle Scholar
  24. Uetani K, Watanabe Y, Abe K, Yano H (2014) Influence of drying method and precipitated salts on pyrolysis for nanocelluloses. Cellulose 21:1631–1639CrossRefGoogle Scholar
  25. van der Stelt MJC, Gerhauser H, Kiel JHA, Ptasinski KJ (2011) Biomass upgrading by torrefaction for the production of biofuels: a review. Biomass Bioenerg 35:3748–3762Google Scholar
  26. Wang H, Srinivasan R, Yu F, Steele P, Li Q, Mitchell B (2011) Effect of acid, alkali, and steam explosion pretreatments on characteristics of bio-oil produced from pinewood. Energy Fuels 25:3758–3764CrossRefGoogle Scholar
  27. Yildiz G, Ronsse F, Venderbosch R, Rv Duren, Kersten SRA, Prins W (2015) Effect of biomass ash in catalytic fast pyrolysis of pine wood. Appl Catal B 168–169:203–211CrossRefGoogle Scholar
  28. Yoo H-M, Seo Y-C, Park S-W, Kang J-J, Choi HS, Oh C-H (2017) Removal effect of ash and metallic species by washing from empty fruit bunch byproducts in palm mills on pyrolytic characteristics to produce bio-crude oil. Waste Biomass Valoriz 9:491–502CrossRefGoogle Scholar
  29. Zhu C, Maduskar S, Paulsen AD, Dauenhauer PJ (2016) Alkaline-earth-metal-catalyzed thin-film pyrolysis of cellulose. ChemCatChem 8:818–829CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Ministry of Education of Key Laboratory of Energy Thermal Conversion and Control, School of Energy and EnvironmentSoutheast UniversityNanjingPeople’s Republic of China

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