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Cellulose

, Volume 26, Issue 10, pp 6365–6378 | Cite as

Sol–gel finishing of bamboo fabric with nanoparticles for water repellency, soil release and UV resistant characteristics

  • Abdul Khalique Jhatial
  • Awais KhatriEmail author
  • Shamshad Ali
  • Aijaz Ahmed Babar
Original Research
  • 63 Downloads

Abstract

This research work reports on the preparation of a durable hydrophobic bamboo knitted fabric with multifunctional properties using sol–gel coating method. The titania nanoparticles (TNPs) and silica nanoparticles (SNPs) composite sols were made using citric acid as cross-linking agent. The bamboo knitted fabric was functionalized by the dip-pad-dry-pad-cure method. Different ratios of TNPs and SNPs were made. All process and solution parameters of sol–gel coating method were optimized to achieve the desired fabric properties. ATR-FTIR spectroscopy, EDS and SEM analysis were carried out to characterize the untreated and sol–gel coated bamboo knitted fabrics. The hydrophobicity, soil release, UV resistance and wash-durability of bamboo knitted fabrics functionalized with NPs (nanoparticles) were measured. The results revealed that the sol–gel coating of TNPs and SNPs on bamboo fabric was durable up to five industrial washes. Moreover, air permeability and fabric handle did not change after sol–gel finishing indicating that the fabric inherent comfort remained unaffected.

Graphic abstract

Keywords

Bamboo knitted fabric Sol–gel finishing Titania nanoparticles Silica nanoparticles Hydrophobicity UV resistance Soil release 

Abbreviations

NPs

Nanoparticles

TNPs

Titania nanoparticles

SNPs

Silica nanoparticles

NaH2PO2

Sodium hypophosphite

CA

Citric acid

DTMS

Dodecyltrimethoxysilane

UV

Ultraviolet

WCA

Water contact angle

AATCC

American Association of Textile Chemist and Colorists

ISO

Organization for International Standardization

ASTM

American Standards for Testing Materials

SEM

Scanning electron microscopy

Notes

Acknowledgments

We are thankful to the Mehran University of Engineering and Technology Jamshoro Sindh Pakistan.

References

  1. Abbas R, Khereby MA, Sadik WA, El Demerdash AGM (2015) Fabrication of durable and cost effective superhydrophobic cotton textiles via simple one step process. Cellulose 22(1):887–896CrossRefGoogle Scholar
  2. Abidi N, Hequet E, Tarimala S, Dai LL (2007) Cotton fabric surface modification for improved UV radiation protection using sol–gel process. J Appl Polym Sci 104(1):111–117CrossRefGoogle Scholar
  3. Babar AA, Wang X, Iqbal N, Yu J, Ding B (2017) Tailoring differential moisture transfer performance of nonwoven/polyacrylonitrile-SiO2 nanofiber composite membranes. ADV Mater Interfaces 4(15):1700062CrossRefGoogle Scholar
  4. Babar AA, Miao D, Ali N, Zhao J, Wang X, Yu J, Ding B (2018) Breathable and colorful cellulose acetate-based Nanofibrous membranes for directional moisture transport. ACS Appl Mater Interfaces 10(26):22866–22875CrossRefGoogle Scholar
  5. Brinker CJ, Scherer GW (2013) Sol-gel science: the physics and chemistry of sol-gel processing. Academic press, New York, p 2Google Scholar
  6. Chinta SK, Landage SM, Swapnal J (2013) Water repellency of textiles through nanotechnology. Int J Adv Res IT Eng 2(1):36–57Google Scholar
  7. Daoud WA, Xin JH, Tao X (2004) Superhydrophobic silica nanocomposite coating by a low-temperature process. J Am Ceram Soc 87(9):1782–1784CrossRefGoogle Scholar
  8. Dastjerdi R, Montazer M, Shahsavan S (2010) A novel technique for producing durable multifunctional textiles using nanocomposite coating. Colloids Surf B 81(1):32–41CrossRefGoogle Scholar
  9. Gashti MP, Alimohammadi F, Shamei A (2012) Preparation of water-repellent cellulose fibers using a polycarboxylic acid/hydrophobic silica nanocomposite coating. Surf Coat Technol 206(14):3208–3215CrossRefGoogle Scholar
  10. Golraa OA, Luqmanc A, Buttd NM (2011) Strategy for introducing nanotechnology in textile industry of Pakistan. Int J Chem Environ Eng 2(4):276–283Google Scholar
  11. Guo F, Wen Q, Peng Y, Guo Z (2017) Multifunctional hollow superhydrophobic SiO2 microspheres with robust and self-cleaning and separation of oil/water emulsions properties. J Colloid Interface Sci 494:54–63CrossRefGoogle Scholar
  12. Huang Z, Gurney RS, Wang T, Liu D (2018) Environmentally durable superhydrophobic surfaces with robust photocatalytic self-cleaning and self-healing properties prepared via versatile film deposition methods. J Colloid Interface Sci 527:107–116CrossRefGoogle Scholar
  13. Karimi L, Mirjalili M, Yazdanshenas ME, Nazari A (2010) Effect of nano TiO2 on self-cleaning property of cross-linking cotton fabric with succinic acid under UV irradiation. Photochem Photobiol 86(5):1030–1037CrossRefGoogle Scholar
  14. Li J, Zheng H, Sun Q, Han S, Fan B, Yao Q, Jin C (2015) Fabrication of superhydrophobic bamboo timber based on an anatase TiO 2 film for acid rain protection and flame retardancy. RSC Adv. 5(76):62265–62272CrossRefGoogle Scholar
  15. Liu J, Huang W, Xing Y, Li R, Dai J (2011) Preparation of durable superhydrophobic surface by sol–gel method with water glass and citric acid. J Solgel Sci Technol 58(1):18–23CrossRefGoogle Scholar
  16. Moafi HF, Shojaie AF, Zanjanchi MA (2010) The comparison of photocatalytic activity of synthesized TiO2 and ZrO2 nanosize onto wool fibers. Appl Surf Sci 256(13):4310–4316CrossRefGoogle Scholar
  17. Montazer M, Alimohammadi F, Shamei A, Rahimi MK (2012) Durable antibacterial and cross-linking cotton with colloidal silver nanoparticles and butane tetracarboxylic acid without yellowing. Colloids Surf B 89:196–202CrossRefGoogle Scholar
  18. Mura S, Greppi G, Malfatti L, Lasio B, Sanna V, Mura ME, Lugliè A (2015) Multifunctionalization of wool fabrics through nanoparticles: a chemical route towards smart textiles. J Colloid Interface Sci 456:85–92CrossRefGoogle Scholar
  19. Pakdel E, Daoud WA (2013) Self-cleaning cotton functionalized with TiO2/SiO2: focus on the role of silica. J Colloid Interface Sci 401:1–7CrossRefGoogle Scholar
  20. Pierre AC (2019) From random glass networks to random silica gel networks and their use as host for biocatalytic applications. J Solgel Sci Technol. 90(1):172–186CrossRefGoogle Scholar
  21. Qin Z, Chen Y, Zhang P, Zhang G, Liu Y (2010) Structure and properties of Cu (II) complex bamboo pulp fabrics. J Appl Polym Sci 117(3):1843–1850Google Scholar
  22. Reddy N, Yang Y (2010) Citric acid cross-linking of starch films. Food Chem 118(3):702–711CrossRefGoogle Scholar
  23. Ren G, Song Y, Li X, Wang B, Zhou Y, Wang Y, Zhu X (2018) A simple way to an ultra-robust superhydrophobic fabric with mechanical stability, UV durability, and UV shielding property. J Colloid Interface Sci 522:57–62CrossRefGoogle Scholar
  24. Roe B, Zhang X (2009) Durable hydrophobic textile fabric finishing using silica nanoparticles and mixed silanes. Text Res J 79(12):1115–1122CrossRefGoogle Scholar
  25. Sawhney APS, Condon B, Singh KV, Pang SS, Li G, Hui D (2008) Modern applications of nanotechnology in textiles. Text Res J 78(8):731–739CrossRefGoogle Scholar
  26. Shen Q, Liu DS, Gao Y, Chen Y (2004) Surface properties of bamboo fiber and a comparison with cotton linter fibers. Colloids Surf B 35(3–4):193–195CrossRefGoogle Scholar
  27. Shirgholami MA, Khalil-Abad MS, Khajavi R, Yazdanshenas ME (2011) Fabrication of superhydrophobic polymethylsilsesquioxane nanostructures on cotton textiles by a solution–immersion process. J Colloid Interface Sci 359(2):530–535CrossRefGoogle Scholar
  28. Simoncic B, Tomsic B, Orel B, Jerman I (2010) Surface modification systems for creating stimuli responsiveness of textiles. University of Twente, The Netherlands, 17Google Scholar
  29. Song J, Rojas OJ (2013) Approaching super-hydrophobicity from cellulosic materials: a review. Nord Pulp Pap Res J 28(2):216–238CrossRefGoogle Scholar
  30. Stanssens D, Van den Abbeele H, Vonck L, Schoukens G, Deconinck M, Samyn P (2011) Creating water-repellent and super-hydrophobic cellulose substrates by deposition of organic nanoparticles. Mater Lett 65(12):1781–1784CrossRefGoogle Scholar
  31. Tang B, Sun L, Li J, Kaur J, Zhu H, Qin S, Wang X (2015) Functionalization of bamboo pulp fabrics with noble metal nanoparticles. Dyes Pigm 113:289–298CrossRefGoogle Scholar
  32. Tomšič B, Simončič B, Orel B, Černe L, Tavčer PF, Zorko M, Kovač J (2008) Sol–gel coating of cellulose fibres with antimicrobial and repellent properties. J Solgel Sci Technol 47(1):44–57CrossRefGoogle Scholar
  33. Ulrich DR (1990) Prospects for sol-gel processes. J Non-Cryst Solids 121(1–3):465–479CrossRefGoogle Scholar
  34. Wang N, Wang Y, Shang B, Wen P, Peng B, Deng Z (2018) Bioinspired one-step construction of hierarchical superhydrophobic surfaces for oil/water separation. J Colloid Interface Sci 531:300–310CrossRefGoogle Scholar
  35. Wong YWH, Yuen CWM, Leung MYS, Ku SKA, Lam HLI (2006) Selected applications of nanotechnology in textiles. AUTEX Res J 6:1–8Google Scholar
  36. Wu Y, Zhao M, Guo Z (2017) Robust, heat-resistant and multifunctional superhydrophobic coating of carbon microflowers with molybdenum trioxide nanoparticles. J Colloid Interface Sci 506:649–658CrossRefGoogle Scholar
  37. Xin JH, Daoud WA, Kong YY (2004) A new approach to UV-blocking treatment for cotton fabrics. Text Res J 74(2):97–100CrossRefGoogle Scholar
  38. Yang CQ, Wang X (1996) Formation of cyclic anhydride intermediates and esterification of cotton cellulose by multifunctional carboxylic acids: an infrared spectroscopy study. Text Res J 66(9):595–603CrossRefGoogle Scholar
  39. Yang H, Zhu S, Pan N (2004) Studying the mechanisms of titanium dioxide as ultraviolet-blocking additive for films and fabrics by an improved scheme. J Appl Polym Sci 92(5):3201–3210CrossRefGoogle Scholar
  40. Yang M, Liu W, Jiang C, He S, Xie Y, Wang Z (2018) Fabrication of superhydrophobic cotton fabric with fluorinated TiO2 sol by a green and one-step sol-gel process. Carbohy. Polym. 197:75–82CrossRefGoogle Scholar
  41. Zhao J, Milanova M, Warmoeskerken MM, Dutschk V (2012) Surface modification of TiO2 nanoparticles with silane coupling agents. Colloids Surf A Physicochem Eng Asp 413:273–279CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Textile EngineeringMehran University of Engineering and TechnologyJamshoroPakistan
  2. 2.State Key Laboratory for Modification of Chemical Fibres and Polymer Materials, College of Material Science and EngineeringDonghua UniversityShanghaiChina

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