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Cellulose

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TBAH/Urea/H2O solvent for room temperature wet-spinning of cellulose and optimization of drawing process

  • Jingyu Zhang
  • Mengdie Wang
  • Wei Li
  • Wei WeiEmail author
  • Jinyang Li
  • Man Jiang
  • Yong Wang
  • Zuowan ZhouEmail author
Original Research
  • 34 Downloads

Abstract

TBAH(tetra-butylammonium hydroxide)/Urea/H2O solvent has been applied for the solvent wet-spinning of cellulose, due to its room temperature operation, good stability and spinnability of the cellulose solution, as well as the unconditional string of low DP (degree of polymerization) for dissolving cellulose. Most importantly, it is found that the stability of the cellulose solution can be dramatically improved by the addition of urea, as indicated by the rheological property of the cellulose solution. With the help of urea, it has been preliminarily studied about the effect of the drawing process, including tnf (time for the formation of nascent fiber in coagulation bath), δ1 (primary drawing ratio) and δ2 (secondary drawing ratio), on the orientation structure and the mechanical performances of the spun fibers. The correlations between the drawing process and the mechanical performance have been established by mathematical models. The tensile strength of the spun fibers improved up to ca. 96% (1.3 cN/dtex) through our optimization of the drawing process. Morphological observations indicated that the spun fibers exhibited regular shape with a circular cross-section. X-ray diffraction and scattering analysis demonstrated that the orientation structure of fibers spun by TBAH/Urea/H2O is similar to that of the commercial viscose and Tencel fibers.

Graphic abstract

Keywords

Cellulose fiber Wet-spinning TBAH Urea Aqueous solvent 

Notes

Acknowledgments

This work is financially supported by the Science and Technology Planning Project of Sichuan Province (Grant Nos. 2018HH0087 and 2018GZ0462) and the Fundamental Research Funds for the Central Universities (No. 2682016CX069). In addition, we are grateful for the 2D wide angle X-ray diffraction and small angle X-ray scattering measurements provided by “Ceshigo” corporation (www.ceshigo.com).

Supplementary material

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Supplementary material 1 (MP4 8134 kb)
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Supplementary material 2 (TIFF 3951 kb)
10570_2019_2536_MOESM3_ESM.docx (338 kb)
Supplementary material 3 (DOCX 338 kb)

References

  1. Abe M, Fukaya Y, Ohno H (2012) Fast and facile dissolution of cellulose with tetrabutylphosphonium hydroxide containing 40 wt% water. Chem Commun 48(12):1808–1810Google Scholar
  2. Ahvenainen P, Kontro I, Svedström K (2016) Comparison of sample crystallinity determination methods by X-ray diffraction for challenging cellulose I materials. Cellulose 23(2):1073–1086Google Scholar
  3. Alves L, Medronho B, Antunes FE et al (2015) Dissolution state of cellulose in aqueous systems. 1. Alkaline solvents. Cellulose 23(1):247–258Google Scholar
  4. Bao Y, Qian H-J, Lu Z-Y et al (2015) Revealing the hydrophobicity of natural cellulose by single-molecule experiments. Macromolecules 48(11):3685–3690Google Scholar
  5. Biermann O, Hadicke E, Koltzenburg S et al (2001) Hydrophilicity and lipophilicity of cellulose crystal surfaces. Angew Chem Int Ed 40(20):3822–3825Google Scholar
  6. Budtova T, Navard P (2015) Viscosity-temperature dependence and activation energy of cellulose solutions. Nord Pulp Pap Res J 30(1):99–105Google Scholar
  7. Cai J, Zhang L (2006) Unique gelation behavior of cellulose in NaOH/urea aqueous solution. Biomacromolecules 7:183–189Google Scholar
  8. Cai J, Zhang L, Zhou J et al (2004) Novel fibers prepared from cellulose in NaOH/urea aqueous solution. Macromol Rapid Commun 25(17):1558–1562Google Scholar
  9. Cai J, Zhang L, Zhou J et al (2007) Multifilament fibers based on dissolution of cellulose in NaOH/urea aqueous solution: structure and properties. Adv Mater 19(6):821–825Google Scholar
  10. Cao J, Wei W, Gou G et al (2018) Cellulose films from the aqueous DMSO/TBAH-system. Cellulose 25(3):1975–1986Google Scholar
  11. Chen X, Burger C, Fang D et al (2006) X-ray studies of regenerated cellulose fibers wet spun from cotton linter pulp in NaOH/thiourea aqueous solutions. Polymer 47:2839–2848Google Scholar
  12. Chen X, Burger C, Wan F et al (2007) Structure study of cellulose fibers wet-spun from environmentally friendly NAOH/urea aqueous solutions. Biomacromolecules 8:1918–1926Google Scholar
  13. Chen J, Guan Y, Wang K et al (2015) Combined effects of raw materials and solvent systems on the preparation and properties of regenerated cellulose fibers. Carbohydr Polym 128:147–153Google Scholar
  14. Chen X, Chen X, Cai X-M et al (2018) Cellulose dissolution in a mixed solvent of tetra(n-butyl)ammonium hydroxide/dimethyl sulfoxide via radical reactions. ACS Sustain Chem Eng 6(3):2898–2904Google Scholar
  15. Connors K (1990) The study of reaction rates in solution in chemical kinetics. VCH Publishers, New YorkGoogle Scholar
  16. Crawshaw J, Cameron RE (2000) A small angle X-ray scattering study of pore structure in Tencel cellulose fibres and the effects of physical treatments. Polymer 41:4691–4698Google Scholar
  17. Dogan H, Hilmioglu ND (2009) Dissolution of cellulose with NMMO by microwave heating. Carbohydr Polym 75(1):90–94Google Scholar
  18. French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21(2):885–896Google Scholar
  19. Fu F, Yang Q, Zhou J et al (2014) Structure and properties of regenerated cellulose filaments prepared from cellulose carbamate–NaOH/ZnO aqueous solution. ACS Sustain Chem Eng 2(11):2604–2612Google Scholar
  20. Gao Q, Shen X, Lu X (2011) Regenerated bacterial cellulose fibers prepared by the NMMO·H2O process. Carbohydr Polym 83(3):1253–1256Google Scholar
  21. Gavillon R, Budtova T (2007) Kinetics of cellulose regeneration from cellulose − NaOH − water gels and comparison with cellulose − N-methylmorpholine-N-oxide − water solutions. Biomacromolecules 8(2):424–432Google Scholar
  22. Gericke M, Schlufter K, Liebert T et al (2009) Rheological properties of cellulose/ionic liquid solutions: from dilute to concentrated states. Biomacromolecules 10:1188–1194Google Scholar
  23. Glasser WG, Atalla RH, Blackwell J et al (2012) About the structure of cellulose: debating the Lindman hypothesis. Cellulose 19(3):589–598Google Scholar
  24. Guinier A, Fournet G (1955) Small-angle scattering of X-rays. Wiley, New YorkGoogle Scholar
  25. Hermans PH (1949) Physics and chemistry of cellulose fibres. Elsevier, AmsterdamGoogle Scholar
  26. Kosan B, Michels C, Meister F (2007) Dissolution and forming of cellulose with ionic liquids. Cellulose 15(1):59–66Google Scholar
  27. Li R, Chang C, Zhou J et al (2010) Primarily industrialized trial of novel fibers spun from cellulose dope in NaOH/urea aqueous solution. Ind Eng Chem Res 49:11380–11384Google Scholar
  28. Li X-Y, Zheng Z-B, Yu D-G et al (2017) Electrosprayed sperical ethylcellulose nanoparticles for an improved sustained-release profile of anticancer drug. Cellulose 24(12):5551–5564Google Scholar
  29. Lindman B, Karlström G, Stigsson L (2010) On the mechanism of dissolution of cellulose. J Mol Liq 156(1):76–81Google Scholar
  30. Liu X, Yang Y, Yu D-G et al (2019) Tunable zero-order drug delivery systems created by modified triaxial electrospinning. Chem Eng J 356:886–894Google Scholar
  31. Lu A, Liu Y, Zhang L et al (2011) Investigation on metastable solution of cellulose dissolved in NaOH/urea aqueous system at low temperature. J Phys Chem B 115(44):12801–12808Google Scholar
  32. Lu F, Wang L, Zhang C et al (2015) Influence of temperature on the solution rheology of cellulose in 1-ethyl-3-methylimidazolium chloride/dimethyl sulfoxide. Cellulose 22(5):3077–3087Google Scholar
  33. Lue A, Zhang L (2009) Rheological behaviors in the regimes from dilute to concentrated in cellulose solutions dissolved at low temperature. Macromol Biosci 9(5):488–496Google Scholar
  34. Mazza M, Catana D-A, Vaca-Garcia C et al (2009) Influence of water on the dissolution of cellulose in selected ionic liquids. Cellulose 16:207–215Google Scholar
  35. Medronho B, Lindman B (2014) Competing forces during cellulose dissolution: from solvents to mechanisms. Curr Opin Colloid Interface Sci 19:32–40Google Scholar
  36. Medronho B, Romano A, Miguel MG et al (2012) Rationalizing cellulose (in)solubility: reviewing basic physicochemical aspects and role of hydrophobic interactions. Cellulose 19(3):581–587Google Scholar
  37. Meessen JH (2012) Urea in Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimGoogle Scholar
  38. Olsson C, Idstrom A, Nordstierna L et al (2014) Influence of water on swelling and dissolution of cellulose in 1-ethyl-3-methylimidazolium acetate. Carbohydr Polym 99:438–446Google Scholar
  39. Qi H, Chang C, Zhang L (2008) Effects of temperature and molecular weight on dissolution of cellulose in NaOH/urea aqueous solution. Cellulose 15(6):779–787Google Scholar
  40. Qi H, Yang Q, Zhang L et al (2011) The dissolution of cellulose in NaOH-based aqueous system by two-step process. Cellulose 18:237–245Google Scholar
  41. Rabideau BD, Ismail AE (2015) Mechanisms of hydrogen bond formation between ionic liquids and cellulose and the influence of water content. Phys Chem Chem Phys 17:5767–5775Google Scholar
  42. Rosenau T, Potthast A, Sixta H et al (2001) The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog Polym Sci 26:1763–1837Google Scholar
  43. Roy C, Budtova T, Navard P (2003) Rheological properties and gelation of aqueous cellulose–NaOH solutions. Biomacromolecules 4:259–264Google Scholar
  44. Ruland W (1969) Small-angle scattering studies on carbonized cellulose fibers. J Polym Sci Part C 28:143–151Google Scholar
  45. Sescousse R, Le KA, Ries ME et al (2010) Viscosity of cellulose-imidazolium-based ionic liquid solutions. J Phys Chem B 114:7222–7228Google Scholar
  46. Sixta H, Michud A, Hauru L et al (2015) Ioncell-F: a High-strength regenerated cellulose fibre. Nord Pulp Pap Res J 30(1):43–57Google Scholar
  47. Thygesen A, Oddershede J, Lilholt H et al (2005) On the determination of crystallinity and cellulose content in plant fibres. Cellulose 12(6):563–576Google Scholar
  48. Vehviläinen M, Kamppuri T, Rom M et al (2008) Effect of wet spinning parameters on the properties of novel cellulosic fibres. Cellulose 15(5):671–680Google Scholar
  49. Vickers ME, Briggs NP, Ibbett RN et al (2001) Small angle X-ray scattering studies on lyocell cellulosic fibres: the effects of drying, re-wetting and changing coagulation temperature. Polymer 42:8241–8248Google Scholar
  50. Wang W, Zhang P, Zhang S et al (2013) Structure and properties of novel regenerated cellulose fibers prepared in NaOH complex solution. Carbohydr Polym 98:1031–1038Google Scholar
  51. Wang S, Lu A, Zhang L (2015) Recent advances in regenerated cellulose materials. Prog Polym Sci 53:169–206Google Scholar
  52. Wei W, Wei X, Gou G et al (2015) Improved dissolution of cellulose in quaternary ammonium hydroxide by adjusting temperature. RSC Adv 5:39080–39083Google Scholar
  53. Wei W, Meng F, Cui Y et al (2017) Room temperature dissolution of cellulose in tetra-butylammonium hydroxide aqueous solvent through adjustment of solvent amphiphilicity. Cellulose 24:49–59Google Scholar
  54. Weng L, Zhang L, Ruan D et al (2004) Thermal gelation of cellulose in a NaOH/thiourea aqueous solution. Langmuir 20:2086–2093Google Scholar
  55. Wilchinsky ZW (1959) On crystal orientation in polycrystalline materials. J Appl Phys 30(5):792Google Scholar
  56. Yang Y, Zhang Y, Dawelbeit A et al (2017) Structure and properties of regenerated cellulose fibers from aqueous NaOH/thiourea/urea solution. Cellulose 24(10):4123–4137Google Scholar
  57. You J, Zhou J, Li Q et al (2012) Rheological study of physical cross-linked quaternized cellulose hydrogels induced by beta-glycerophosphate. Langmuir 28(11):4965–4973Google Scholar
  58. Yu DG, Li JJ, Williams GR et al (2018) Electrospun amorphous solid dispersions of poorly water-soluble drugs: a review. J Controlled Release 292:91–110Google Scholar
  59. Zhang DRALL (2008) Gelation behaviors of cellulose solution dissolved in aqueous NaOH/thiourea at low temperature. Polymer 49:1027–1036Google Scholar
  60. Zhao Y, Liu X, Wang J et al (2013) Insight into the cosolvent effect of cellulose dissolution in imidazolium-based ionic liquid systems. J Phys Chem B 117(30):9042–9049Google Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and EngineeringSouthwest Jiaotong UniversityChengduChina

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