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Cellulose

, Volume 26, Issue 10, pp 6333–6347 | Cite as

A reactive fluorine-free, efficient superhydrophobic and flame-retardant finishing agent for cotton fabrics

  • Shengnan Li
  • Ling Zhong
  • Shuo Huang
  • Dingfei Wang
  • Fengxiu Zhang
  • Guangxian ZhangEmail author
Original Research
  • 85 Downloads

Abstract

A novel finishing agent, N,N-dimethyl-octadecyl phosphate acrylamide (NDOPA), was synthesized with octadecanol, phosphorous acid, formaldehyde and acrylamide, and applied to cotton fabrics by ultraviolet curing to endow cotton fabrics with superhydrophobicity and flame retardancy. Results showed that NDOPA could be grafted onto cotton fabrics through C–O–C covalent bonds during the ultraviolet curing process. The contact angle of cotton fabric treated with the 10% NDOPA agent could reach 157.5°. The treated cotton fabrics exhibited clear flame retardancy. The treated cotton retained strong hydrophobicity and flame retardancy after 30 laundering cycles, indicating that the treated cotton fabrics had excellent durability. Thermogravimetric analysis revealed that the treated samples had flame-retardant properties. The results of Fourier-transform infrared spectroscopy, energy dispersive X-ray analysis and scanning electron micrography showed that NDOPA was successfully grafted onto the cotton fabrics; X-ray diffraction analysis indicated that the crystallized structure of treated cotton fibers nearly did not change.

Graphical abstract

Keywords

Superhydrophpbicity Flame retardant Cotton fabrics Efficient Durability 

Notes

References

  1. Alongi J, Malucelli G (2015) Cotton flame retardancy: state of the art and future perspectives. RSC Adv 5:24239–24263CrossRefGoogle Scholar
  2. Alongi J, Carosio F, Malucelli G (2012a) Influence of ammonium polyphosphate-/poly(acrylic acid)-based layer by layer architectures on the char formation in cotton, polyester and their blends. Polym Degrad Stab 97:1644–1653CrossRefGoogle Scholar
  3. Alongi J, Colleoni C, Malucelli G, Rosaceb G (2012b) Hybrid phosphorus-doped silica architectures derived from a multistep sol–gel process for improving thermal stability and flame retardancy of cotton fabrics. Polym Degrad Stab 97:1334–1344CrossRefGoogle Scholar
  4. Alongi J, Milnes J, Malucelli G, Bourbigot S, Kandola B (2014) Thermal degradation of DNA-treated cotton fabrics under different heating conditions. J Anal Appl Pyrolysis 108:212–221CrossRefGoogle Scholar
  5. Annalisa C, Francesca B, Giulio M, Chiara M, Monica P (2016) DNA-chitosan cross-linking and photografting to cotton fabrics to improve washing fastness of the fire-resistant finishing. Cellulose 23:3963–3984CrossRefGoogle Scholar
  6. Chang SC, Slopek RP, Condon B, Grunlan JC (2014) Surface coating for flame-retardant behavior of cotton fabric using a continuous layer-by-layer process. Ind Eng Chem Res 53:3805–3812CrossRefGoogle Scholar
  7. Cheema HA, Elshafei A, Hauser PJ (2013) Conferring flame retardancy on cotton using novel halogen-free flame retardant bifunctional monomers: synthesis, characterizations and applications. Carbohydr Polym 92:885–893CrossRefGoogle Scholar
  8. Colleoni C, Donelli I, Freddi G, Guido E, Migani V, Rosace G (2013) A novel sol–gel multi-layer approach for cotton fabric finishing by tetraethoxysilane precursor. Surf Coat Technol 235:192–203CrossRefGoogle Scholar
  9. Feng Y, Zhou Y, Li D, He S, Zhang F, Zhang G (2017) A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric. Carbohydr Polym 175:636–644CrossRefGoogle Scholar
  10. French AD (2013) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896CrossRefGoogle Scholar
  11. Gao W-W, Zhang G-X, Zhang F-X (2015) Enhancement of flame retardancy of cotton fabrics by grafting a novel organic phosphorous-based flame retardant. Cellulose 22:2787–2796CrossRefGoogle Scholar
  12. Horrocks AR (2013) Textile flammability research since 1980—personal challenges and partial solutions. Polym Degrad Stab 98:2813–2824CrossRefGoogle Scholar
  13. Huang Z, Gurney RS, Wang T, Liu D (2018) Environmentally durable superhydrophobic surfaces with robust photocatalytic self-cleaning and self-healing properties prepared via versatile film deposition methods. J Colloid Interface Sci 527:107–116CrossRefGoogle Scholar
  14. Jia Y, Hu Y, Zheng D, Zhang G, Zhang F, Liang Y (2016) Synthesis and evaluation of an efficient, durable, and environmentally friendly flame retardant for cotton. Cellulose 24:1159–1170CrossRefGoogle Scholar
  15. Jing J, Zhang Y, Fang Z-P, Wang D-Y (2018) Core-shell flame retardant/graphene oxide hybrid: a self-assembly strategy towards reducing fire hazard and improving toughness of polylactic acid. Compos Sci Technol 165:161–167CrossRefGoogle Scholar
  16. Keil DE, Mehlmann T, Butterworth L, Pedenadams MM (2008) Gestational exposure to perfluorooctane sulfonate suppresses immune function in B6C3F1 mice. Toxicol Sci 103:77–85CrossRefGoogle Scholar
  17. Lee CH, Johnson N, Drelich J, Yap YK (2011) The performance of superhydrophobic and superoleophilic carbon nanotube meshes in water–oil filtration. Carbon 49:669–676CrossRefGoogle Scholar
  18. Li Y, Li L, Sun J (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Ed 49:6129–6133CrossRefGoogle Scholar
  19. Li Z-F, Zhang C-J, Cui L, Zhu P, Yan C, Liu Y (2017) Fire retardant and thermal degradation properties of cotton fabrics based on APTES and sodium phytate through layer-by-layer assembly. J Anal Appl Pyrolysis 123:216–223CrossRefGoogle Scholar
  20. Lin D, Zeng X, Li H, Lai X (2018) Facile fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via layer-by-layer assembly. Cellulose 25:3135–3149CrossRefGoogle Scholar
  21. Lin D, Zeng X, Li H, Lai X, Wu T (2019) One-pot fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via sol-gel reaction. J Colloid Interface Sci 533:198–206CrossRefGoogle Scholar
  22. LTD DVRPRTP (1934) International year of natural fibres: 2009. Carnegie Endowment for International PeaceGoogle Scholar
  23. Maciejewski H, Karasiewicz J, Dutkiewicz M, Marciniec B (2015) Hydrophobic materials based on fluorocarbofunctional spherosilicates. Silicon 7:1–9CrossRefGoogle Scholar
  24. Mckeen LW (2006) Fluorinated coatings and finishes handbook. Elsevier, p 395Google Scholar
  25. Nguyen TM, Chang SC, Condon B, Slopek R, Graves E, Yoshiokatarver M (2013) Structural effect of phosphoramidate derivatives on the thermal and flame retardant behaviors of treated cotton cellulose. Ind Eng Chem Res 52:4715–4724CrossRefGoogle Scholar
  26. Pan H et al (2015) Construction of layer-by-layer assembled chitosan/titanate nanotubes based nanocoating on cotton fabrics: flame retardant performance and combustion behavior. Cellulose 22:911–923CrossRefGoogle Scholar
  27. Qian Y, Zhou S, Chen X (2018) Synergistic flame retardant effect between nano-silicon dioxide and layered double hydroxides in ethylene vinyl acetate composites. J Thermoplast Compos Mater 31:1295–1309CrossRefGoogle Scholar
  28. Rosace G, Colleoni C, Trovato V, Iacono G, Malucelli G (2017) Vinylphosphonic acid/methacrylamide system as a durable intumescent flame retardant for cotton fabric. Cellulose 24:3095–3108CrossRefGoogle Scholar
  29. Shanti R, Bella F, Salim YS, Chee SY, Ramesh S, Ramesh K (2016) Poly(methyl methacrylate-co-butyl acrylate-co-acrylic acid): physico-chemical characterization and targeted dye sensitized solar cell application. Mater Des 108:560–569CrossRefGoogle Scholar
  30. Sun D, Wang W, Yu D (2017) Highly hydrophobic cotton fabrics prepared with fluorine-free functionalized silsesquioxanes. Cellulose 24:4519–4531CrossRefGoogle Scholar
  31. Suryaprabha T, Sethuraman MG (2018) Fabrication of superhydrophobic and enhanced flame-retardant coatings over cotton fabric. Cellulose 25:3151–3161CrossRefGoogle Scholar
  32. Tragoonwichian S, Kothary P, Siriviriyanun A, O’Rear EA, Yanumet N (2011) Silicon-compound coating for preparation of water repellent cotton fabric by admicellar polymerization. Colloids Surf 384:381–387CrossRefGoogle Scholar
  33. Wei C, Tang Y, Zhang G, Zhang Q, Zhan X, Chen F (2016) Facile fabrication of highly omniphobic and self-cleaning surfaces based on water mediated fluorinated nanosilica aggregation. RSC Adv 6:74340–74348CrossRefGoogle Scholar
  34. Xing W, Jie G, Song L, Hu S, Lv X, Wang X, Hu Y (2011) Flame retardancy and thermal degradation of cotton textiles based on UV-curable flame retardant coatings. Thermochim Acta 513:75–82CrossRefGoogle Scholar
  35. Xue C-H, Chen J, Yin W, Jia S-T, Ma J-Z (2012) Superhydrophobic conductive textiles with antibacterial property by coating fibers with silver nanoparticles. Appl Surf Sci 258:2468–2472CrossRefGoogle Scholar
  36. Zhang D et al (2017) Flame retardant and hydrophobic coatings on cotton fabrics via sol-gel and self-assembly techniques. J Colloid Interface Sci 505:892–899CrossRefGoogle Scholar
  37. Zheng D, Zhou J, Zhong L, Zhang F, Zhang G (2016) A novel durable and high-phosphorous-containing flame retardant for cotton fabrics. Cellulose 23:2211–2220CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Shengnan Li
    • 1
    • 4
  • Ling Zhong
    • 2
  • Shuo Huang
    • 1
    • 4
  • Dingfei Wang
    • 1
    • 4
  • Fengxiu Zhang
    • 3
  • Guangxian Zhang
    • 1
    • 4
    Email author
  1. 1.College of Textile and GarmentSouthwest UniversityChongqingChina
  2. 2.Chongqing Municipality Fiber Inspection BureauChongqingChina
  3. 3.China Institute of Bioorganic and Medicinal Chemistry, College of Chemistry and Chemical EngineeringSouthwest UniversityChongqingChina
  4. 4.Chongqing Engineering Research Center of Biomaterial Fiber and Modem TextileChongqingChina

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