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Cellulose

, Volume 26, Issue 10, pp 5821–5829 | Cite as

Strong and tough long cellulose fibers made by aligning cellulose nanofibers under magnetic and electric fields

  • Hyun Chan Kim
  • Jung Woong Kim
  • Lindong Zhai
  • Jaehwan KimEmail author
Communication
  • 69 Downloads

Abstract

This paper reports a strong and tough cellulose long fiber (CLF) fabrication by aligning cellulose nanofiber (CNF) through simultaneous application of magnetic and electric fields. As an ingredient of the CLF, CNF is isolated from hardwood by the combination of chemical and physical methods. A wet-state cellulose long fiber (WCLF) is fabricated by wet spinning. 5T magnetic field, generated in a superconducting DC magnet, is applied to perpendicular to the WCLF. An electric field of 50 V/cm at 100 Hz is applied along the WCLF between two electrode supports. Scanning electron microscopy, two-dimensional wide-angle X-ray diffraction and tensile test demonstrate that when the magnetic and electric fields are applied simultaneously, its Young’s modulus, tensile strength, yield strength, strain at break and toughness of the fabricated CLF are greatly improved with the highest degree of CNF orientation. Unusual toughness improvement of the CLF with other mechanical properties is very promising for fabricating strong and tough CLF.

Keywords

Nanocellulose Fiber Alignment Magnetic field Electric field 

Notes

Acknowledgments

This research was supported by Creative Research Initiatives Program through the National Research Foundation of Korea (NRF-2015R1A3A2066301).

References

  1. Bordel D, Putaux JL, Heux L (2006) Orientation of native cellulose in an electric field. Langmuir 22:4899–4901CrossRefGoogle Scholar
  2. Clemons C (2016) Nanocellulose in spun continuous fibers: a review and future outlook. J Renew Mater 4:327–339CrossRefGoogle Scholar
  3. Crespy D, Friedemann K, Popa AM (2012) Colloid-electrospinning: fabrication of multicompartment nanofibers by the electrospinning of organic or/and inorganic dispersions and emulsions. Macromol Rapid Commun 33:1978–1995CrossRefGoogle Scholar
  4. Hai LV, Zhai L, Kim HC, Kim JW, Choi ES, Kim J (2018) Cellulose nanofibers isolated by TEMPO-oxidation and aqueous counter collision methods. Carbohydr Polym 191:65–70CrossRefGoogle Scholar
  5. Hubbe MA, Rojas OJ, Lucia LA, Sain M (2008) Cellulosic nanocomposites: a review. BioResources 3:929–980Google Scholar
  6. Kafy A, Kim HC, Zhai L, Kim JW, Hai LV, Kang TJ, Kim J (2017) Cellulose long fibers fabricated from cellulose nanofibers and its strong and tough characteristics. Sci Rep 7:17683CrossRefGoogle Scholar
  7. Kim J, Chen Y, Kang KS, Park YB, Schwartz M (2008) Magnetic field effect for cellulose nanofiber alignment. J Appl Phys 104:096104CrossRefGoogle Scholar
  8. Kim JH, Shim BS, Kim HS, Lee YJ, Min SK, Jang D, Kim J (2015) Review of nanocellulose for sustainable future materials. Int J Precis Eng Manuf Green Technol 2:197–213CrossRefGoogle Scholar
  9. Kim HC, Mun S, Ko HU, Zhai L, Kafy A, Kim J (2016) Renewable smart materials. Smart Mater Struct 25:073001CrossRefGoogle Scholar
  10. Kim HC, Kim D, Lee JY, Zhai L, Kim J (2019) Effect of wet spinning and stretching to enhance mechanical properties of cellulose nanofiber filament. Int J Precis Eng Manuf Green Technol (in press).  https://doi.org/10.1007/s40684-019-00070-z
  11. Kondo T, Kose R, Naito H, Kasai W (2014) Aqueous counter collision using paired water jets as a novel means of preparing bio-nanofibers. Carbohydr Polym 112:284–290CrossRefGoogle Scholar
  12. Ku H, Wang H, Pattarachaiyakoop N, Trada M (2011) A review on the tensile properties of natural fiber reinforced polymer composites. Compos Part B 42:856–873CrossRefGoogle Scholar
  13. Mao Y, Bleuel M, Lyu Y, Zhang X, Henderson D, Wang H, Briber RM (2018) Phase separation and stack alignment in aqueous cellulose nanocrystal suspension under weak magnetic field. Langmuir 34:8042–8051CrossRefGoogle Scholar
  14. Mittal N, Ansari F, Gowda VK, Brouzet C, Chen P, Larsson PT, Roth SV, Lundell F, Wågberg L, Kotov NA, Söderberg LD (2018) Multiscale control of nanocellulose assembly: transferring remarkable nanoscale fibril mechanics to macroscale fibers. ACS Nano 12:6378–6388CrossRefGoogle Scholar
  15. Peng Y, Gardner DJ, Han Y (2012) Drying cellulose nanofibrils: in search of a suitable method. Cellulose 19:91–102CrossRefGoogle Scholar
  16. Pullawan T, Wilkinson AN, Eichhorn SJ (2012) Influence of magnetic field alignment of cellulose whiskers on the mechanics of all-cellulose nanocomposites. Biomacromol 13:2528–2536CrossRefGoogle Scholar
  17. Saito T, Kuramae R, Wohlert J, Berglund LA, Isogai A (2012) An ultrastrong nanofibrillar biomaterial: the strength of single cellulose nanofibrils revealed via sonication-induced fragmentation. Biomacromol 14:248–253CrossRefGoogle Scholar
  18. Sinko R, Mishra S, Ruiz L, Brandis N, Keten S (2013) Dimensions of biological cellulose nanocrystals maximize fracture strength. ACS Macro Lett 3:64–69CrossRefGoogle Scholar
  19. Tanaka T, Fujita M, Takeuchi A, Suzuki Y, Uesugi K, Ito K, Iwata T (2006) Formation of highly ordered structure in poly [(R)-3-hydroxybutyrate-co-(R)-3-hydroxyvalerate] high-strength fibers. Macromolecules 39:2940–2946CrossRefGoogle Scholar
  20. Thielke MW, Secker C, Schlaad H, Theato P (2016) Electrospinning of crystallizable polypeptoid fibers. Macromol Rapid Commun 37:100–104CrossRefGoogle Scholar
  21. Torres-Rendon JG, Schacher FH, Ifuku S, Walther A (2014) Mechanical performance of macrofibers of cellulose and chitin nanofibrils aligned by wet-stretching: a critical comparison. Biomacromol 15:2709–2717CrossRefGoogle Scholar
  22. Xu S, Liu D, Zhang Q, Fu Q (2018) Electric field-induced alignment of nanofibrillated cellulose in thermoplastic polyurethane matrix. Compos Sci Technol 156:117–126CrossRefGoogle Scholar
  23. Zhai L, Kim HC, Kim JW, Kang J, Kim J (2018) Elastic moduli of cellulose nanofibers isolated from various cellulose resources by using aqueous counter collision. Cellulose 25:4261–4268CrossRefGoogle Scholar
  24. Zhao HP, Feng XQ (2007) Ultrasonic technique for extracting nanofibers from nature materials. Appl Phys Lett 90:073112CrossRefGoogle Scholar
  25. Zhu H, Zhu S, Zia Z, Parvinian S, Li Y, Vaaland O, Hu L, Li T (2015) Anomalous scaling law of strength and toughness of cellulose nanopaper. PNAS 112:8971–8976CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Creative Research Center for Nanocellulose Future CompositesInha UniversityIncheonKorea

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