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Cellulose

, Volume 26, Issue 9, pp 5497–5511 | Cite as

Underwater superoleophobic biomaterial based on waste potato peels for simultaneous separation of oil/water mixtures and dye adsorption

  • Arun K. Singh
  • Shruti Mishra
  • Jayant K. SinghEmail author
Original Research
  • 372 Downloads

Abstract

Underwater superoleophilicity involves interactions between a solid surface and two immiscible liquids, viz., water and oils, in which water remains in the completely wetted and oils in the non-wetted state. Materials with underwater superoleophilicity have drawn significant interest due to their superior performance in selective separation of oil and organic solvents from an aqueous phase. However, the development of such materials with special wettability for water and oils are hindered by (1) complex fabrication process (2) long processing duration with high cost, and (3) use of environmentally unfriendly and expensive fluorochemicals to lower the surface energy. Herein, we demonstrate the use of waste potato peels (WPP) to fabricate simple, economical and eco-friendly materials with superhydrophilic (water contact angle ~ 0°) and underwater superoleophobic (oil contact angle > 150°) properties. Initially, powder of WPP was prepared and accumulated into a layer via a simple cleaning, smashing, one step inexpensive chemical treatment and stacking procedures. The developed WPP layer was efficient for the gravity-driven separation of various oil/water mixtures (including hexane, toluene, dodecylbenzene, and kerosene) and water-in-oil emulsions, with high efficiency (> 98%) in single unit operation. During the oil/water separation process, the WPP layer was also found to serve as an adsorbent material for efficient removal of various water-soluble dyes (methylene blue and rhodamine B, 50 mg L−1) contaminants, simultaneously. Thus, the developed WPP layer is not only a good biomaterial for water remediation by the oil/water separation and dye adsorption simultaneously, but can also contribute in reducing environmental pollution and wastage.

Graphical abstract

Keywords

Waste potato peel powder Underwater superoleophobicity Oil/water separation Water-in-oil emulsion separation Water soluble dyes adsorption 

Notes

Acknowledgments

This work is supported by Science and Engineering research board (SERB) and Department of Science and Technology (DST), Government of India. Arun K. Singh gratefully acknowledge Science and Engineering Research Board (SERB) for awarding the SERB-National Post-Doctoral Fellowship (PDF/2016/002638) to him.

Supplementary material

Supplementary material 1 (AVI 5386 kb)

Supplementary material 2 (AVI 5126 kb)

References

  1. Arampatzidou AC, Deliyanni EA (2016) Comparison of activation media and pyrolysis temperature for activated carbons development by pyrolysis of potato peels for effective adsorption of endocrine disruptor bisphenol-A. J Colloid Interface Sci 466:101–112CrossRefPubMedGoogle Scholar
  2. Baig U, Matin A, Gondal MA, Zubair SM (2018) Facile fabrication of superhydrophobic, superoleophilic photocatalytic membrane for efficient oil-water separation and removal of hazardous organic pollutants. J Clean Prod.  https://doi.org/10.1016/j.jclepro.2018.10.079 CrossRefGoogle Scholar
  3. Camire ME, Violette D, Dougherty MP, McLaughlin MA (1997) Potato peel dietary fiber composition: effects of peeling and extrusion cooking processes. J Agric Food Chem 45:1404–1408CrossRefGoogle Scholar
  4. Cao Y, Liu N, Zhang W, Feng L, Wei Y (2016) One-step coating toward multifunctional applications: oil/water mixtures and emulsions separation and contaminants adsorption. ACS Appl Mater Interfaces 8:3333–3339CrossRefPubMedGoogle Scholar
  5. Cheng Q, Ye DD, Chang C, Zhang L (2017) Facile fabrication of superhydrophilic membranes consisted of fibrous tunicate cellulose nanocrystals for highly efficient oil/water separation. J Membr Sci 525:1–8CrossRefGoogle Scholar
  6. Das S, Kumar S, Samal SK, Mohanty S, Nayak SK (2018) A review on superhydrophobic polymer nanocoatings: recent development and applications. Ind Eng Chem Res 57:2727–2745CrossRefGoogle Scholar
  7. Feng Y, Wang Y, Wang Y, Yao J (2017) Furfuryl alcohol modified melamine sponge for highly efficient oil spill clean-up and recovery. J Mater Chem A 5:21893–21897CrossRefGoogle Scholar
  8. Fu S, Zhou H, Wang H, Niu H, Yang W, Shaoa H, Lin T (2018) Amphibious superamphiphilic fabrics with self-healing underwater superoleophilicity. Mater Horiz.  https://doi.org/10.1039/c8mh00898a CrossRefPubMedPubMedCentralGoogle Scholar
  9. Gao X, Jiang L (2004) Water-repellent legs of water striders. Nature 432:36CrossRefGoogle Scholar
  10. Guechi E-K, Hamdaoui O (2016) Biosorption of methylene blue from aqueous solution by potato (Solanum tuberosum) peel: equilibrium modelling, kinetic, and thermodynamic studies. Desalin Water Treat 57:10270–10285CrossRefGoogle Scholar
  11. Guo F, Wen Q, Guo Z (2017) Low cost and non-fluoride flowerlike superhydrophobic particles fabricated for both emulsions separation and dyes adsorption. J Colloid Interface Sci 507:421–428CrossRefPubMedGoogle Scholar
  12. Khosravi M, Azizian S (2017) Preparation of superhydrophobic and superoleophilic nanostructured layer on steel mesh for oil–water separation. Sep Purif Technol 172:366–373CrossRefGoogle Scholar
  13. Li J, Li D, Yang Y, Li J, Zha F, Lei Z (2016) A prewetting induced underwater superoleophobic or underoil (super) hydrophobic waste potato residue-coated mesh for selective efficient oil/water separation. Green Chem 18:541–549CrossRefGoogle Scholar
  14. Li J, Zhao Z, Li D, Tang X, Feng H, Qi W, Wang Q (2017a) Multifunctional walnut shell layer used for oil/water mixtures separation and dyes adsorption. Appl Surf Sci 419:869–874CrossRefGoogle Scholar
  15. Li Y, Zhang Z, Ge B, Men X, Xue Q (2017b) A versatile and efficient approach to separate both surfactant-stabilized water-in-oil and oil-in-water emulsions. Sep Purif Technol 176:1–7CrossRefGoogle Scholar
  16. Li C, Lai H, Cheng Z, Yan J, An M (2018a) Designing robust underwater superoleophobic microstructures on copper substrates. Nanoscale 10:20435–20442CrossRefPubMedGoogle Scholar
  17. Li J, Xu C, Zhang Y, Tang X, Qi W, Wang Q (2018b) Gravity-directed separation of both immiscible and emulsified oil/water mixtures utilizing coconut shell layer. J Colloid Interface Sci 511:233–242CrossRefPubMedGoogle Scholar
  18. Li J, Xu C, Guo C, Tian H, Zha F, Guo L (2018c) Underoil superhydrophilic desert sand layer for efficient gravity-directed water-in-oil emulsions separation with high flux. J Mater Chem A 6:223–230CrossRefGoogle Scholar
  19. Lin X, Heo J, Jeong H, Choi M, Chang M, Hong J (2016) Robust superhydrophobic carbon nanofiber network inlay-gated mesh for water-in-oil emulsion separation with high flux. J Mater Chem A 4:17970–17980CrossRefGoogle Scholar
  20. Linag S, McDonald AG (2014) Chemical and thermal characterization of potato peel waste and its fermentation residue as potential resources for biofuel and bioproducts production. J Agric Food Chem 62:8421–8429CrossRefGoogle Scholar
  21. Liu BM, Wang S, Wei Z, Song Y, Jiang L (2009) Bioinspired design of a superoleophobic and low adhesive water/solid interface. Adv Mater 21:665–669CrossRefGoogle Scholar
  22. Liu X, Zhou J, Xue Z, Gao J, Meng J, Wang S, Jiang L (2012) Clam’s shell inspired high-energy inorganic coatings with underwater low adhesive superoleophobicity. Adv Mater 24:3401–3405CrossRefPubMedGoogle Scholar
  23. Marmur A (2012) Hydro-hygro-oleo-omni-phobic? Terminology of wettability classification. Soft Matter 8:6867–6870CrossRefGoogle Scholar
  24. Nguyen T-B, Park S, Lim H (2018) Effects of morphology parameters on anti-icing performance in superhydrophobic surfaces. Appl Surf Sci 435:585–591CrossRefGoogle Scholar
  25. Qu M, Ma L, Zhou Y, Zhao Y, Wang J, Zhang Y, Zhu X, Liu X, He J (2018) Durable and recyclable superhydrophilic-superoleophobic materials for efficient oil/water separation and water-soluble dyes removal. ACS Appl Nano Mater 1:5197–5209CrossRefGoogle Scholar
  26. Schlaich C, Camacho LC, Yu L, Achazi K, Wei Q, Haag R (2016) Surface-independent hierarchical coatings with superamphiphobic properties. ACS Appl Mater Interfaces 8:29117–29127CrossRefPubMedGoogle Scholar
  27. Si Y, Dong Z, Jiang L (2018) Bioinspired designs of superhydrophobic and superhydrophilic materials. ACS Cent Sci 4:1102–1112CrossRefPubMedPubMedCentralGoogle Scholar
  28. Singh JK, Muller-Plathe F (2014) On the characterization of crystallization and ice adhesion on smooth and rough surfaces using molecular dynamics. Appl Phys Lett 104:021603CrossRefGoogle Scholar
  29. Singh AK, Singh JK (2016) Fabrication of zirconia based durable superhydrophobic–superoleophilic fabrics using non fluorinated materials for oil–water separation and water purification. RSC Adv 6:103632–103640CrossRefGoogle Scholar
  30. Singh AK, Singh JK (2017a) Fabrication of durable superhydrophobic coatings on cotton fabrics with photocatalytic activity by fluorine-free chemical modification for dual-functional water purification. New J Chem 41:4618–4628CrossRefGoogle Scholar
  31. Singh AK, Singh JK (2017b) Fabrication of durable super-repellent surfaces on cotton fabric with liquids of varying surface tension: low surface energy and high roughness. Appl Surf Sci 416:639–648CrossRefGoogle Scholar
  32. Singh AK, Singh JK (2019) An efficient use of waste PE for hydrophobic surface coatings and its application on cotton fibers for oil–water separator. Prog Org Coat 131:301–310CrossRefGoogle Scholar
  33. Singh AK, Ketan K, Singh JK (2017) Simple and green fabrication of recyclable magnetic highly hydrophobic sorbents derived from waste orange peels for removal of oil and organic solvents from water surface. J Environ Chem Eng 5:5250–5259CrossRefGoogle Scholar
  34. Song J, Wang D, Hu L, Huang X, Chen Y (2018) Superhydrophobic surface fabricated by nanosecond laser and perhydropolysilazane. Appl Surf Sci 455:771–779CrossRefGoogle Scholar
  35. Sukamanchi R, Mathew D, Kumar KSS (2017) Durable superhydrophobic particles mimicking leafhopper surface: superoleophilicity and very low surface energy. ACS Sustain Chem Eng 5:252–260CrossRefGoogle Scholar
  36. Ueda E, Levkin PA (2013) Emerging applications of superhydrophilic-superhydrophobic micropatterns. Adv Mater 25:1234–1247CrossRefPubMedGoogle Scholar
  37. Wang J, Wang H (2018) Easily enlarged and coating-free underwater superoleophobic fabric for oil/water and emulsion separation via a facile NaClO2 treatment. Sep Purif Technol 195:358–366CrossRefGoogle Scholar
  38. Wen X, Liu H, Zhang L, Zhang J, Fu C, Shi X, Chen X, Mijowska E, Ming-Jun Chen M-J, Wang D-Y (2019) Large-scale converting waste coffee grounds into functional carbon materials as high-efficient adsorbent for organic dyes. Bioresour Technol 272:92–98CrossRefPubMedGoogle Scholar
  39. Yimina D, Jiaqi Z, Danyang L, Lanli N, Liling Z, Yi Z, Xiaohong Z (2018) Preparation of Congo red functionalized Fe3O4@SiO2 nanoparticle and its application for the removal of methylene blue. Colloids Surf A 550:90–98CrossRefGoogle Scholar
  40. Yong J, Chen F, Huo J, Fang Y, Yang Q, Bian H, Li W, Wei Y, Dai Y, Hou X (2018) Green, biodegradable, underwater superoleophobic wood sheet for efficient oil/water separation. ACS Omega 3:1395–1402CrossRefPubMedPubMedCentralGoogle Scholar
  41. You Q, Ran G, Wang C, Zhao Y, Song Q (2018) A novel superhydrophilic–underwater superoleophobic Zn–ZnO electrodeposited copper mesh for efficient oil/water separation. Sep Purif Technol 193:21–28CrossRefGoogle Scholar
  42. Zhan H, Zuo T, Tao R, Chang C (2018a) Robust tunicate cellulose nanocrystal/palygorskite nanorod membranes for multifunctional oil/water emulsion separation. ACS Sustain Chem Eng 6:10833–10840CrossRefGoogle Scholar
  43. Zhan H, Peng N, Lei X, Huang Y, Li D, Tao R, Chang C (2018b) UV-induced self-cleanable TiO2/nanocellulose membrane for selective separation of oil/water emulsion. Carbohydr Polym 201(2018):464–470CrossRefPubMedGoogle Scholar
  44. Zhang Z, Luo X, Liu Y, Zhou P, Ma G, Lei Z, Lei L (2015) A low cost and highly efficient adsorbent (activated carbon) prepared from waste potato residue. J Taiwan Inst Chem Eng 49:206–211CrossRefGoogle Scholar
  45. Zhou H, Zhao Y, Wang H, Lin T (2016) Recent development in durable super-liquid-repellent fabrics. Adv Mater Interfaces 3:1600402CrossRefGoogle Scholar
  46. Zhou C, Feng J, Cheng J, Zhang H, Lin J, Zeng X, Pi P (2018) Opposite superwetting nickel meshes for on-demand and continuous oil/water separation. Ind Eng Chem Res 57:1059–1070CrossRefGoogle Scholar
  47. Zhu H, Chen D, Li N, Xu Q, Li H, He J, Lu J (2017) Dual-layer copper mesh for integrated oil–water separation and water purification. Appl Catal B Environ 200:594–600CrossRefGoogle Scholar
  48. Zhu H, Guo P, Shang Z, Yu X, Zhang Y (2018) Fabrication of underwater superoleophobic metallic fiber felts for oil–water separation. Appl Surf Sci 447:72–77CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Chemical EngineeringIndian Institute of Technology KanpurKanpurIndia

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