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Cellulose

, Volume 26, Issue 6, pp 3777–3786 | Cite as

Preparation of all-cellulose composites with optical transparency using the banana pseudostem as a raw material

  • L. Chávez-GuerreroEmail author
  • S. Vazquez-Rodriguez
  • J. A. Salinas-Montelongo
  • L. E. Roman-Quirino
  • N. A. García-Gómez
Original Research
  • 108 Downloads

Abstract

Biopolymers are intended to substitute the petroleum-based polymers and all-cellulose composite has emerged as a green alternative, especially if it can be prepared through a method consuming less energy and fewer chemicals. Here, a novel approach to obtain a nanocomposite film made of cellulose fibrils imbibed into a nanocellulose matrix is described. Banana pseudostem was used as raw material and characterized along with the resulting materials using scanning electron microscopy, optical microscopy and Raman spectroscopy, while the cellulose/nanocellulose film was studied through X-ray diffraction, UV–Vis-NIR spectroscopy and laser scanning microscopy. Results indicate that cellulose (fibrils) and nanocellulose (platelets), extracted from banana pseudostem were successfully purified using hydrolysis at a relatively low amount of chemicals. Transparent films made of a fibrils/nanoplatelets blend were prepared by the solution casting method, exhibiting a transmittance of ≈ 83–88% and a crystallinity index of ≈ 70, hence demonstrating the feasibility of this novel method to obtain cellulose/nanocellulose free-standing films.

Graphical abstract

Keywords

Cellulose/nanocellulose films Agricultural waste Cellulose nanoplatelets Inner pseudostem Nanocomposites 

Abbreviations

BI-Ctrl

Control sample

BI-Alk

Sample under alkaline pretreatment

BI-Hyd

Sample under acidic pretreatment

BP

Sample under basic pretreatment

CNP

Cellulose nanoplatelets

CrI

Crystallinity index

XRD

X-ray diffraction

OM

Optic microscopy

SEM

Scanning electron microscopy

LSM

Laser scanning microscopy

Notes

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Facultad de Ingeniería Mecánica y EléctricaUniversidad Autónoma de Nuevo LeónSan Nicolás de los GarzaMéxico
  2. 2.Centro de Innovación, Investigación y Desarrollo en IngenieríaUniversidad Autónoma de Nuevo León UANLSan Nicolás de los GarzaMexico
  3. 3.Universidad Politécnica de ApodacaApodacaMéxico
  4. 4.Facultad de Ciencias QuímicasUniversidad Autónoma de Nuevo LeónSan Nicolás de los GarzaMexico
  5. 5.Centro de Investigación en Biotecnología y Nanotecnología (CIByN). Facultad de Ciencias QuímicasUniversidad Autónoma de Nuevo León (UANL). Parque de Investigación e Innovación TecnológicaApodacaMéxico

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