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Cellulose

, Volume 26, Issue 5, pp 3359–3373 | Cite as

A novel nanocomposite membrane containing modified cellulose nanocrystals for copper ion removal and dye adsorption from water

  • Fateme Rafieian
  • Mehdi JonoobiEmail author
  • Qingliang Yu
Original Research
  • 345 Downloads

Abstract

The aim of this study was developing novel membranes based on polyethersulfone (PES) as matrix and amine functionalized cellulose nanocrystals (CNC) as nanofiller for copper ion and direct red-16 removal from water. The surface modification of CNC was performed using (3-aminopropyl)triethoxysilane (APTES) and confirmed by Fourier transform infrared spectroscopy and energy dispersive X-ray spectroscopy. Then, PES membranes were prepared by embedding various concentrations (0, 0.1, 0.5, and 1 wt%) of modified CNC (MCNC). The results showed that the maximum adsorption capacity of copper ions was 90% for membranes containing 1 wt% MCNC. Dye removal percentage was 89% for neat PES and increased to 99% for 1 wt% MCNC loading. The outcomes of this study demonstrated that incorporating this type of modified CNC in PES membranes improved the efficacy of impurities removal from water and can be suggested as a simple technique for water filtration.

Graphical abstract

Keywords

Cellulose nanocrystal (3-Aminopropyl)triethoxysilane Nanocomposite membranes Water purification 

Notes

Acknowledgments

The authors wish to acknowledge to the Iranian National Science Foundation for the financial support of the Research Project (# 92043921) and also the University of Tehran.

References

  1. Abouzeid RE, Khiari R, El-Wakil N, Dufresne A (2018) Current state and new trends in the use of cellulose nanomaterials for wastewater treatment. Biomacromolecules.  https://doi.org/10.1021/acs.biomac.8b00839 CrossRefPubMedGoogle Scholar
  2. de Castro Silva F, da Silva MMF, Lima LCB, Osajima JA, da Silva Filho EC (2018) Modifying cellulose with metaphosphoric acid and its efficiency in removing brilliant green dye. Int J Biol Macromol 114:470–478CrossRefPubMedGoogle Scholar
  3. El Haddad M, Slimani R, Mamouni R, ElAntri S, Lazar S (2013) Removal of two textile dyes from aqueous solutions onto calcined bones. J Associ Arab Univ Basic Appl Sci 14:51–59Google Scholar
  4. Elimelech M, Phillip WA (2011) The future of seawater desalination: energy, technology, and the environment. Science 333:712–717CrossRefPubMedGoogle Scholar
  5. French AD, Santiago Cintrón MS (2013) Cellulose polymorphy, crystallite size, and the Segal crystallinity index. Cellulose 20:583–588CrossRefGoogle Scholar
  6. Gehrke I, Geiser A, Somborn-Schulz A (2015) Innovations in nanotechnology for water treatment. Nanotechnol Sci Appl 8:1–17CrossRefPubMedPubMedCentralGoogle Scholar
  7. Jain P, Varshney S, Srivastava S (2016) Synthetically modified nano-cellulose for the removal of chromium: a green nanotech perspective. IET Nanobiotechnol 11:45–51CrossRefGoogle Scholar
  8. Khanjanzadeh H, Behrooz R, Bahramifar N, Gindl-Altmutter W, Bacher M, Edler M, Griesser T (2018) Surface chemical functionalization of cellulose nanocrystals by 3-aminopropyltriethoxysilane. Int J Biol Macromol 106:1288–1296CrossRefPubMedGoogle Scholar
  9. Li B, Li M, Zhang J, Pan Y, Huang Z, Xiao H (2018) Adsorption of Hg(II) ions from aqueous solution by diethylenetriaminepentaacetic acid-modified cellulose. Int J Biol Macromol 122:149–156CrossRefPubMedGoogle Scholar
  10. Madivoli E et al (2016) Adsorption of selected heavy metals on modified nanocellulose. Int Res J Pure Appl Chem 12:1–9CrossRefGoogle Scholar
  11. Mautner A, Maples H, Kobkeatthawin T, Kokol V, Karim Z, Li K, Bismarck A (2016) Phosphorylated nanocellulose papers for copper adsorption from aqueous solutions. Int J Environ Sci Technol 13:1861–1872CrossRefGoogle Scholar
  12. Misra AK (2014) Climate change and challenges of water and food security. Int J Sustain Built Environ 3:153–165CrossRefGoogle Scholar
  13. Nam S, French AD, Condon BD, Concha M (2016) Segal crystallinity index revisited by the simulation of X-ray diffraction patterns of cotton cellulose Iβ and cellulose II. Carbohydr Polym 135:1–9CrossRefPubMedGoogle Scholar
  14. Pendergast MM, Hoek EM (2011) A review of water treatment membrane nanotechnologies. Energy Environ Sci 4:1946–1971CrossRefGoogle Scholar
  15. Rahimi M, Dadari S, Zeinaddini S, Mohamadian E (2017) Flux, antifouling and separation characteristics enhancement of nanocomposite polyethersulfone mixed-matrix membrane by embedding synthesized hydrophilic adipate ferroxane nanoparticles. Korean J Chem Eng 34:1444–1455CrossRefGoogle Scholar
  16. Rathoure AK (2015) Toxicity and waste management using bioremediation. IGI Global, HersheyGoogle Scholar
  17. Saraswathi MSSA, Rana D, Nagendran A, Alwarappan S (2018) Custom-made PEI/exfoliated-MoS2 nanocomposite ultrafiltration membranes for separation of bovine serum albumin and humic acid. Mater Sci Eng C 83:108–114CrossRefGoogle Scholar
  18. Segal LGJMA, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29(10):786–794CrossRefGoogle Scholar
  19. Sun N, Wen X, Yan C (2018) Adsorption of mercury ions from wastewater aqueous solution by amide functionalized cellulose from sugarcane bagasse. Int J Biol Macromol 108:1199–1206CrossRefPubMedGoogle Scholar
  20. Tahir U, Yasmin A, Khan UH (2016) Phytoremediation: potential flora for synthetic dyestuff metabolism. J King Saud Univ-Sci 28:119–130CrossRefGoogle Scholar
  21. Yin J, Deng B (2015) Polymer-matrix nanocomposite membranes for water treatment. J Membr Sci 479:256–275CrossRefGoogle Scholar
  22. Zhang D, Karkooti A, Liu L, Sadrzadeh M, Thundat T, Liu Y, Narain R (2018) Fabrication of antifouling and antibacterial polyethersulfone (PES)/cellulose nanocrystals (CNC) nanocomposite. J Membr Sci 549:350–356CrossRefGoogle Scholar
  23. Zhou Y, Jin Q, Hu X, Zhang Q, Ma T (2012) Heavy metal ions and organic dyes removal from water by cellulose modified with maleic anhydride. J Mater Sci 47:5019–5029CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Food Science and Technology, Agricultural CollegeUniversity of TehranKarajIran
  2. 2.Department of Wood and Paper Science and Technology, Faculty of Natural ResourcesUniversity of TehranKarajIran
  3. 3.Department of Built EnvironmentEindhoven University of TechnologyEindhovenThe Netherlands

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