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Cellulose

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Bio-inspired films based on chitosan, nanoclays and cellulose nanocrystals: structuring and properties improvement by using water-evaporation-induced self-assembly

  • Daniela EnescuEmail author
  • Christian Gardrat
  • Henri Cramail
  • Cédric Le Coz
  • Gilles SèbeEmail author
  • Véronique ComaEmail author
Original Research
  • 52 Downloads

Abstract

Herein, we report a novel approach for the preparation of chitosan films with improved mechanical and barrier properties, by incorporating a mixture of nanoclays (MMT) and cellulose nanocrystals (CNC), via a water-evaporation-induced self-assembly process. The improvements obtained were assigned to: (1) the slow evaporation of water, leading to nacre-like structures; (2) a synergistic effect created between MMT and CNC. The best mechanical properties were obtained with a weight ratio MMT/CNC 1:2, which led to a significant improvement in tensile strength (+ 230%) and tensile modulus (+ 448%). In addition, the thermal stability of the films was also improved, while the water vapor and oxygen transmission rates were reduced. The improved barrier properties were attributed to the nacre-like layered structure formed by the sodium cloisite platelets within the chitosan matrix, which slowed down the diffusion of water and oxygen.

Graphical abstract

Keywords

Chitosan Cellulose nanocrystals Nanoclays Biocomposites Bioinspired materials 

Notes

Acknowledgments

The authors express their gratitude towards PLACAMAT (France) for SEM analysis, towards Vincent Baylac (Université Paul Sabatier, Toulouse, France) for OTR measurements and towards Eric Lebraud (ICMCB, University of Bordeaux, France) for XRD analysis.

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.UMR 5629Université de BordeauxPessacFrance
  2. 2.UMR 5629CNRS, LCPOPessacFrance
  3. 3.Department Life Sciences, Research Unit: Nano for Food, Food ProcessingInternational Iberian Nanotechnology Laboratory (INL)BragaPortugal

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