Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

One-Step Encapsulation of Bimetallic Pd–Co Nanoparticles Within UiO-66 for Selective Conversion of Furfural to Cyclopentanone

Abstract

The design of efficient catalysts is of important significance for the transformation of biomass into chemicals. In this work, bimetallic Pd–Co nanoparticles were encapsulated within UiO-66 to form a core–shell Pd–Co@UiO-66 catalyst via a facile one-step strategy. The as-synthesized Pd–Co@UiO-66 catalysts were characterized and applied to the selective hydrogenation of furfural (FUR) to cyclopentanone (CPO). Compared with the monometallic Pd@UiO-66, the Pd–Co@UiO-66 could demonstrate excellent performance with 96% CPO selectivity and 99% FUR conversion at 120 °C under 3 MPa H2 pressure for 12 h. It was found that trace Co had synergetic and promoting effects on the catalytic performance. The core–shell catalysts showed more outstanding recyclability than the supported catalysts, which could maintain high CPO yield after 5th runs.

Graphic Abstract

This is a preview of subscription content, log in to check access.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. 1.

    Klass DL (1998) Biomass for renewable energy, fuels, and chemicals. Elsevier, London

  2. 2.

    Demirbaş A (2001) Energ Convers Manage 42:1357

  3. 3.

    Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411

  4. 4.

    Lange JP, Van Der Heide E, Van Buijtenen J, Price R (2012) Chemsuschem 5:150

  5. 5.

    Li JQ (2001) Chem Eng J 1:338

  6. 6.

    Yan K, Wu G, Lafleur T, Jarvis C (2014) Renew Sust Energ Rev 38:663

  7. 7.

    Li X, Jia P, Wang T (2016) ACS Catal 6:7621

  8. 8.

    Pushkarev VV, Musselwhite N, An K, Alayoglu S, Somorjai GA (2012) Nano Lett 12:5196

  9. 9.

    Biradar NS, Hengne AM, Birajdar SN, Niphadkar PS, Joshi PN, Rode CV (2012) ACS Sustain Chem Eng 2:272

  10. 10.

    Taber DF (1977) J Am Chem Soc 99:3513

  11. 11.

    Tiziana G, Emanuela E, Emanuela M, Rosanna DP, Carmelo M, Rosaria M, Placido B, Salvatore C (2008) Shock 30:142

  12. 12.

    Nagashima O, Sato S, Takahashi R, Sodesawa T, Akashi T (2006) Appl Catal A: Gen 312:175

  13. 13.

    Zhan BZ, Thompson A (2004) Tetrahedron 13:2917

  14. 14.

    Takehira K, Hayakawa T, Orita H, Shimizu M (1989) J Mol Catal 53:15

  15. 15.

    Hronec M, Fulajtarová K (2012) Catal Commun 24:100

  16. 16.

    Zhang GS, Zhu MM, Zhang Q, Liu YM, He HY, Gao Y (2016) Green Chem 18:2155

  17. 17.

    Liu X, Zhang B, Fei B, Chen X, Zhang J, Mu X (2017) Faraday Discuss 202:79

  18. 18.

    Yang Y, Du Z, Huang Y, Lu F, Wang F, Gao J, Xu J (2013) Green Chem 15:1932

  19. 19.

    Guo J, Xu G, Han Z, Zhang Y, Fu Y, Guo Q (2014) ACS Sustain Chem Eng 2:2259

  20. 20.

    Zhu H, Zhou M, Zeng Z, Xiao G, Xiao R (2014) Korean J Chem Eng 31:593

  21. 21.

    Wang Y, Sang S, Zhu W, Gao L, Xiao G (2016) Chem Eng J 299:104

  22. 22.

    Liu CY, Wei RP, Geng GL, Zhou MH, Gao LJ, Xiao GM (2016) Fuel Process Technol 134:168

  23. 23.

    Chang L, Li Y (2017) Mol Catal 433:77

  24. 24.

    Hronec M, Fulajtárová K, Vávra I, Soták T, Dobročka E, Mičušík M (2016) Appl Catal B: Environ 181:210

  25. 25.

    Li H, Eddaoudi M, O'Keeffe M, Yaghi OM (1999) Nature 402:276

  26. 26.

    Chae HK, Siberio Pérez DY, Kim J, Go Y, Eddaoudi M, Matzger AJ, Yaghi OM (2004) Nature 427:523

  27. 27.

    Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I (2005) Science 309:2040

  28. 28.

    Park KS, Ni Z, Côté AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, ÓKeeffe M, Yaghi OM (2006) P Natl Acad Sci USA 103:10186

  29. 29.

    Lin L, Liu H, Zhang X (2018) Appl Surf Sci 433:602

  30. 30.

    Fang R, Liu H, Luque R, Li Y (2015) Green Chem 17:4183

  31. 31.

    Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud K (2008) J Am Chem Soc 130:13850

  32. 32.

    Ramsahye NA, Gao J, Jobic H, Llewellyn PL, Yang Q, Wiersum AD, Koza MM, Guillerm V, Serre C, Zhong CL, Maurin G (2014) J Phys Chem C 118:27470

  33. 33.

    Bai Y, Dou Y, Xie L, Rutledge W, Li J, Zhou H (2016) Chem Soc Rev 45:2327

  34. 34.

    Chen L, Chen X, Liu H, Bai C, Li Y (2015) J Mater Chem A 3:15259

  35. 35.

    Pastoriza-Santos I, Liz-Marzán LM (2009) Adv Funct Mater 19:679

  36. 36.

    Wu F, Lin L, Liu H, Wang H, Qiu J, Zhang X (2017) J Membrane Sci 544:342

  37. 37.

    Zheng S, Yang P, Zhang F, Chen D, Zhu W (2017) Chem Eng J 328:977

  38. 38.

    Krawczyk M, Sobczak JW (2004) Appl Surf Sci 235:49

  39. 39.

    Li H, Zhu Z, Zhang F, Xie S, Li H, Li P, Zhou X (2011) ACS Catal 1:1604

  40. 40.

    Yin D, Ren H, Li C, Liu J, Liang C (2018) Chinese J Catal 39:319

  41. 41.

    Hronec M, Fulajtárova K, Mičušík M (2013) App Catal A: Gen 468:426

  42. 42.

    Yu W, Porosoff MD, Chen JG (2012) Chem Rev 112:5780

  43. 43.

    Chen L, Chen H, Luque R, Li Y (2014) Chem Sci 5:3708

  44. 44.

    Maheswari S, Karthikeyan S, Murugan P, Sridhar P, Pitchumani S (2012) Phys Chem Chem Phys 14:9683

  45. 45.

    Hronec M, Katarina F, Liptaj T (2012) Appl Catal A: Gen 437:104

Download references

Acknowledgements

This work was supported by the National Natural Science and China National Petroleum Corporation (CNPC) Joint Foundation (No. U1662101); National Natural Science Foundation (No: 21173030).

Author information

Correspondence to Xiongfu Zhang.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Wang, Y., Liu, C. & Zhang, X. One-Step Encapsulation of Bimetallic Pd–Co Nanoparticles Within UiO-66 for Selective Conversion of Furfural to Cyclopentanone. Catal Lett (2020). https://doi.org/10.1007/s10562-020-03133-y

Download citation

Keywords

  • Selective hydrogenation
  • Biomass conversion
  • Heterogeneous catalysis
  • Hydrothermal synthesis
  • Encapsulation
  • Nanoparticles