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Deactivation of Co-Al2O3/SiO2 Fischer–Trospch Synthesis Catalyst in Industrially Relevant Conditions

  • Alexander P. Savost’yanov
  • Oleg L. EliseevEmail author
  • Roman E. Yakovenko
  • Grigoriy B. Narochniy
  • Konstantin I. Maslakov
  • Ivan Zubkov
  • Vitaliy N. Soromotin
  • Alexey T. Kozakov
  • Anatolii V. Nicolskii
  • Serge A. Mitchenko
Article
  • 68 Downloads

Abstract

The deactivation rate of Co-Al2O3/SiO2 Fischer–Tropsch synthesis catalyst have been experimentally assessed at industrially relevant conditions (T 198–237 °C, P = 60 bar, H2/CO = 1.85, GHSV 2000–7000 h–1). The fresh and spent catalyst was characterized by XRD, XPS, BET, TEM, and SEM–EDX techniques. Decreasing active surface area due to cobalt oxidation by product water and sintering of cobalt crystallites were found to be minor factors for the deactivation. The principal reason of activity loss seems is diffusion limitations arising due to catalyst pores plugging by product wax. The linear dependence between gas flow rate and estimated catalyst lifetime was revealed. High GHSV of fresh synthesis gas and/or high circulation ratio of product gas should be employed to prevent rapid loss of catalyst activity.

Graphic Abstract

Keywords

Heterogeneous catalysis Fischer–Tropsch Deactivation Cobalt Wax 

Notes

Acknowledgements

This work was supported by the Ministry of Education and Science of the Russian Federation (state task no. 10.2980.2017/4.6). XPS spectra analysis was supported by the project no 3.6105.2017/8.9.

Compliance with Ethical Standards

Conflict of interest

The authors declare no conflict of interest.

References

  1. 1.
    Steynberg AP, Dry M (2004) Stud Surf Sci Catal 152:1CrossRefGoogle Scholar
  2. 2.
    Dry ME (2004) Appl Catal A 276:1CrossRefGoogle Scholar
  3. 3.
    Khodakov AY, Chu W, Fongarland P (2007) Chem Rev 107:1692CrossRefGoogle Scholar
  4. 4.
    Zhang Q, Kang J, Wang Y (2010) ChemCatChem 2:1030CrossRefGoogle Scholar
  5. 5.
    Rytter E, Tsakoumis NE, Holmen A (2016) Catal. Today 261:3CrossRefGoogle Scholar
  6. 6.
    Freund M (1982) Developments in petroleum science, Vol. 14, In: Freund M, Mózes GY (eds) Elsevier Scientific Publishing Company: AmsterdamGoogle Scholar
  7. 7.
    Bekker M, Louw NR, Van Rensburg VJJ, Potgiete J (2013) Int J Cosmet Sci 35:99CrossRefGoogle Scholar
  8. 8.
    Dobratz BM, Crawford PC (1985) LLNL explosive handbook: properties of chemical explosives and explosive simplants. Livermore, CaliforniaGoogle Scholar
  9. 9.
    Van Berge PJ, Everson RC (1997) Stud Surf Sci Catal 107:207CrossRefGoogle Scholar
  10. 10.
    Sparks DE, Jacobs G, Gnanamani MK, Pendyala VRR, Ma W, Kang J, Shafer WD, Keogh RA, Graham UM, Gao P, Davis BH (2013) Catal Today 215:67CrossRefGoogle Scholar
  11. 11.
    Saib AM, Moodley DJ, Ciobîcă IM, Hauman MM, Sigwebela BH, Weststrate CJ, Niemantsverdriet JW, van de Loosdrecht J (2010) Catal Today 154:271CrossRefGoogle Scholar
  12. 12.
    Espinoza RL, Steynberg AP, Jager B, Vosloo AC (1999) Appl Catal A 186:13CrossRefGoogle Scholar
  13. 13.
    Van Berge PJ, van de Loosdrecht J, Barradas S, van der Kraan AM (2000) Catal Today 58:321CrossRefGoogle Scholar
  14. 14.
    Saib AM, Borgna A, van de Loosdrecht J, van Berge PJ, Geus JW, Niemantsverdriet JW (2006) J Catal 239:326CrossRefGoogle Scholar
  15. 15.
    Hilmen AM, Schanke D, Hanssen KF, Holmen A (1999) Appl Catal A 186:169CrossRefGoogle Scholar
  16. 16.
    Bian GZ, Fujishita N, Mochizuki T, Ning WS, Yamada M (2003) Appl Catal A 252:251CrossRefGoogle Scholar
  17. 17.
    Kiss G, Kliewer CE, DeMartin GJ, Culross CC, Baumgartner JE (2003) J Catal 217:127Google Scholar
  18. 18.
    Overett MJ, Breedt B, du Plessis E, Erasmus W, van de Loosdrecht J (2008) Prepr Pap-Am Chem Soc Div Pet Chem 53:126Google Scholar
  19. 19.
    Jacobs G, Patterson PM, Zhang Y, Das T, Li J, Bavis BH (2002) Appl Catal A 233:215CrossRefGoogle Scholar
  20. 20.
    Li JL, Zhan XD, Zhang YQ (2002) Appl Catal A 228:203CrossRefGoogle Scholar
  21. 21.
    Pennline HW, Gormley RJ, Schehl RR (1984) Ind Eng Chem Prod Res Dev 23:388CrossRefGoogle Scholar
  22. 22.
    Pennline HW, Pollack SS (1986) Ind Eng Chem Prod Res Dev 23:11CrossRefGoogle Scholar
  23. 23.
    Niemela MK, Krause AOI (1996) Catal Lett 42:161CrossRefGoogle Scholar
  24. 24.
    Van Steen E, Claeys M, Dry ME, van de Loosdrecht J, Viljoen EL, Visagie JL (2005) J Phys Chem B 109:3577Google Scholar
  25. 25.
    Li JL, Davis BH (2004) Stud Surf Sci Catal 147:307CrossRefGoogle Scholar
  26. 26.
    Krishnamoorthy S, Tu M, Ojeda MP, Pinna D, Iglesia E (2002) J Catal 211:422CrossRefGoogle Scholar
  27. 27.
    Bartholomew CH (2001) Appl Catal A 212:17CrossRefGoogle Scholar
  28. 28.
    Das TK, Jacobs G, Patterson PM, Conner WA, Li J, Davis BH (2003) Fuel 82:805CrossRefGoogle Scholar
  29. 29.
    Jacobs G, Patterson PM, Das TK, Luo M, Davis BH (2004) Appl Catal A 270:65CrossRefGoogle Scholar
  30. 30.
    Jahangiri H, Bennett J, Mahjoubi P, Wilson K, Gu S (2014) Catal Sci Technol 4:2210CrossRefGoogle Scholar
  31. 31.
    Moodley DJ, van de Loosdrecht J, Saib AM, Overett MJ, Datye AK, Niemantsverdriet JW (2009) Appl Catal A 354:102CrossRefGoogle Scholar
  32. 32.
    Narochnyi GB, Yakovenko RE, Savost’yanov AP, Bakun VG (2016) Catal Ind 8:139CrossRefGoogle Scholar
  33. 33.
    Savost’yanov AP, Yakovenko RE, Sulima SI, Bakun VG, Narochnyi GB, Chernyshev VM, Mitchenko SA (2017) Catal Today 279:107CrossRefGoogle Scholar
  34. 34.
    Savost’yanov AP, Narochnyi GB, Yakovenko RE, Mitchenko SA, Zubkov IN (2018) Pet Chem 58:76CrossRefGoogle Scholar
  35. 35.
    Savost’yanov AP, Yakovenko RE, Narochnyi GB, Sulima SI, Bakun VG, Soromotin VN, Mitchenko SA (2017) Catal Commun 99:25CrossRefGoogle Scholar
  36. 36.
    International Centre for Diffraction Data (ICDD), PDF-2 Release 2012 https://www.icdd.com/index.php/pdf-2/
  37. 37.
    Kashin AS, Ananikov VP (2011) Russ Chem Bull 60:2602CrossRefGoogle Scholar
  38. 38.
    Kachala K, Khemchyan LL, Kashin AS, Orlov NV, Grachev AA, Zalesskiy SS, Ananikov VP (2013) Russ Chem Rev 82:648CrossRefGoogle Scholar
  39. 39.
    Biesinger MC, Payne BP, Grosvenor AP, Lau LW, Gerson AR, Smart RSC (2011) Appl Surf Sci 257:2717CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2020

Authors and Affiliations

  • Alexander P. Savost’yanov
    • 1
  • Oleg L. Eliseev
    • 2
    Email author
  • Roman E. Yakovenko
    • 1
  • Grigoriy B. Narochniy
    • 1
  • Konstantin I. Maslakov
    • 3
  • Ivan Zubkov
    • 1
  • Vitaliy N. Soromotin
    • 1
  • Alexey T. Kozakov
    • 4
  • Anatolii V. Nicolskii
    • 4
  • Serge A. Mitchenko
    • 1
  1. 1.Platov South-Russian State Polytechnic University (NPI)NovocherkasskRussia
  2. 2.N.D. Zelinsky Institute of Organic ChemistryMoscowRussia
  3. 3.Department of ChemistryLomonosov Moscow State UniversityMoscowRussia
  4. 4.Scientific Research Institute of Physics At SouthernFederal UniversityRostov-on-DonRussia

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