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Study of Ethanol/Acetaldehyde to 1,3-Butadiene Over MgO–SiO2 Catalyst: Comparative Investigation of Deactivation Behaviour Due to Carbon Deposition

  • Minhua Zhang
  • Yu’nan Qin
  • Xuechao Tan
  • Lingtao Wang
  • Yingzhe Yu
  • Haoxi JiangEmail author
Article
  • 25 Downloads

Abstract

In this paper, the MgO–SiO2 catalyst was prepared with the deposition–precipitation method, which was used to catalyse the conversion of ethanol to 1,3-butadiene through a two-step process. The carbon deposition deactivation of the catalyst was mainly caused by that the carbon species occupied the acid-basic active sites on the catalyst surface. The carbon deposition mainly includes chain alkanes and aromatic compounds from outer to inner layers, and its site was mainly MgSiO3, followed by MgO, while SiO2 showed weak carbon deposition ability.

Graphic Abstract

Keywords

1,3-Butadiene Carbon decomposition Ethanol MgO–SiO2 catalyst 

Notes

Acknowledgements

This work was supported by the National Scientific Foundation of China (Grant Nos. 21808157 and 21978211).

Compliance with Ethical Standards

Conflict of interest

All authors declare that they have no conflict of interest.

Supplementary material

10562_2019_3049_MOESM1_ESM.docx (1 mb)
Supplementary material 1 (DOCX 1059 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Key Laboratory for Green Chemical Technology of Ministry of EducationR&D Center for Petrochemical Technology, Tianjin UniversityTianjinChina
  2. 2.Research and Development Center for Petrochemical Technology, Tianjin UniversityTianjinChina

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