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Molecular Oxygen Activation on Suspended Doped Cerium(IV) Oxide Particles in Molten Chloride Salts

  • Behzad Tangeysh
  • Horia Metiu
  • Michael J. Gordon
  • Eric W. McFarlandEmail author
Article
  • 29 Downloads

Abstract

Suspensions of cerium(IV) oxide (CeO2) particles in molten chloride salts were found to be active for molecular oxygen activation when doped with the larger Lanthanides, gadolinium (Gd), praseodymium, (Pr), and samarium, (Sm). The activity for O2 oxidation of gas phase CO on suspended doped ceria in molten mixtures of LiCl–LiBr–KBr and NaCl–KCl is significantly higher than undoped ceria or the salt mixtures alone in the temperature ranges of 350–600 °C, and 700–800 °C, respectively. Surface tension measurements show that the solid doped ceria particles suspended in the melt are contacting the gas–liquid interface of the bubbles. The activity for O2 oxidation of liquid phase MgCl2 in molten MgCl2–KCl to produce Cl2 and solid MgO was also observed to be significantly increased on suspended CeO2 doped with 5 wt% or 10 wt% Gd. The rates of oxidation were observed to increase with catalyst loading.

Graphic Abstract

Keywords

Molten chloride salts Doped ceria catalyst Oxygen activation CO oxidation Cl2 production 

Notes

Acknowledgements

This work was supported by BASF through the California Research Alliance Program (CARA). The authors are grateful for the indispensable technical assistance of Mr. Richard Bock of the UCSB Chemistry Department who prepared all the quartz reactor components and their modifications. The authors also acknowledge the technical assistance of Mr. Steven Bustillos and Mr. Joshua Rodriguez.

Supplementary material

10562_2019_2942_MOESM1_ESM.docx (420 kb)
Supplementary material 1 (DOCX 420 kb) Additional figures of control studies and thermodynamic plots of the reactions. This material is available free of charge via the Internet

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Behzad Tangeysh
    • 1
  • Horia Metiu
    • 2
  • Michael J. Gordon
    • 1
  • Eric W. McFarland
    • 1
    Email author
  1. 1.Department of Chemical EngineeringUniversity of CaliforniaSanta BarbaraUSA
  2. 2.Department of Chemistry and BiochemistryUniversity of CaliforniaSanta BarbaraUSA

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