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Grafted Polyethylene Glycol–Graphene Oxide as a Novel Triphase Catalyst for Carbenes and Nucleophilic Substitution Reactions

  • Xiaohai Yang
  • Jie Zhai
  • Tongchun Xu
  • Bing Xue
  • Jie Zhu
  • Yongxin LiEmail author
Article
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Abstract

Separation and reusability had been main problems for the using of polyethylene glycol (PEG) as phase transfer catalysts (PTCs). To solve these problems, PEG was firstly and successfully grafted on graphene oxide (GO) using BF3·C2H5OC2H5 as Lewis acid catalyst. The solid GO-PEG composites were systemically investigated by characterization techniques (TG, FT-IR, XPS, ICP-AES etc.) and then applied to some carbenes and nucleophilic substitution reactions as novel triphase catalysts. As the results, GO-PEG showed not only equally excellent catalytic activity (≥ 93% yield of 7,7-dichlorobicyclo[4.1.0]heptane and iodooctane) but also incomparable reusability (≥ 85% yield of iodooctane after using for four times) in comparison with traditional PTCs (PEG).

Graphic Abstract

Keywords

Polyethylene glycol Graphene oxide Triphase catalyst Carbenes reaction Nucleophilic substitution 

Notes

Acknowledgements

This research is supported by the National Natural Science Foundation of China (21673024).

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Xiaohai Yang
    • 1
  • Jie Zhai
    • 1
  • Tongchun Xu
    • 1
  • Bing Xue
    • 1
  • Jie Zhu
    • 1
  • Yongxin Li
    • 1
    Email author
  1. 1.Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical EngineeringChangzhou UniversityChangzhouChina

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