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A Bimetallic Pure Inorganic Framework for Highly Efficient and Selective Photocatalytic Oxidation of Cyclohexene to 2-Cyclohexen-1-ol

  • Xiaoyun Shi
  • Zhuolin Shi
  • Guiqin Niu
  • Chen Si
  • Qiuxia HanEmail author
  • Jingjing Zhang
Article
  • 13 Downloads

Abstract

The highly efficient and selective photocatalytic oxidation of cyclohexene with molecular oxygen under mild conditions is an important objective in chemical synthesis. In this work, a pure inorganic framework CoMo was self-assembly prepared under solvothermal conditions by incorporating simple MoO42−, cobalt (II) ion. The catalyst CoMo was well characterized by infrared spectroscopy (FTIR), nitrogen adsorption–desorption, powder X-ray diffraction (XRD), scanning electron spectroscopy (SEM), and X-ray photoelectron spectroscopy (XPS) methods. It displayed high efficiency and selectivity in the photocatalytic oxidation of cyclohexene to 2-cyclohexen-1-ol in O2 atmosphere. The influence of solvents, oxidants, pressure of oxygen, reaction temperature, light source and time on the reaction was investigated. More interestingly, the selectivity of the reaction in 4-ethyltoluene was much higher than that in other solvents.

Graphic Abstract

A pure inorganic framework CoMo with open mesoporous channels displayed high efficiency and selectivity for photocatalytic oxidation of cyclohexene with molecular oxygen under mild conditions.

Keywords

Inorganic framework Cyclohexene Photocatalysis Selective oxidation 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21601048), the China Postdoctoral Science Foundation (2015M580626), the Natural Science Foundation Project of Henan province (162300410012).

Compliance with Ethical Standards

Conflict of interest

The authors declare no conflict of interest.

Supplementary material

10562_2019_2847_MOESM1_ESM.doc (11.7 mb)
Supplementary material 1 (DOC 12023 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Xiaoyun Shi
    • 1
  • Zhuolin Shi
    • 1
  • Guiqin Niu
    • 1
  • Chen Si
    • 1
  • Qiuxia Han
    • 1
    Email author
  • Jingjing Zhang
    • 1
  1. 1.Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical EngineeringHenan UniversityKaifengChina

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