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A Novel and Green In Situ Strategy for the Synthesis of Metallophthalocyanines on Chitosan and Investigation Their Catalytic Activity in the CO2 Fixation

  • Mahmoud Borjian Boroujeni
  • Mohammad Sadegh Laeini
  • Mohammad Taghi Nazeri
  • Ahmad ShaabaniEmail author
Article
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Abstract

In this work, a novel and green strategy for the in situ synthesis of metallophthalocyanines on chitosan (MPcs@CS; M=Cu, Ni, Co) in deep eutectic solvents (DESs) at 120 °C has been reported. The chemical and structural properties of the MPcs@CS were determined by scanning electron microscopy (SEM), energy-dispersive X-ray(EDS), X-ray powder diffraction (XRD), Fourier transformation infrared spectroscopy(FT-IR), thermogravimetric analysis(TGA) and flame atomic absorption spectroscopies(FAAS). This new MPcs@CS is a highly efficient, active and reusable catalyst for the synthesis of cyclic carbonates from promoting the reaction of CO2 with epoxides under mild reaction conditions (at 80 °C and 1 atm CO2 pressure) with good to excellent yield of products. The order of catalytic activity is CuPc@CS, CoPc@CS and NiPc@CS from the conversion, temperature and time point of view, respectively.

Graphical Abstract

Keywords

Chitosan Metallophthalocyanine CO2 fixation Heterogeneous catalyst Deep eutectic solvent Cyclic carbonate 

Notes

Acknowledgements

We gratefully acknowledge financial support from the Catalyst Center of Excellence (CCE) of Shahid Beheshti University and from the Iran National Science Foundation (INSF).

Compliance with Ethical Standards

Conflict of interest

The authors declare no conflict of interest.

Supplementary material

10562_2019_2740_MOESM1_ESM.docx (3.8 mb)
Supplementary material 1 (DOCX 3912 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Faculty of ChemistryShahid Beheshti University, G. CTehranIran

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