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Mesoporous Silica Doped with Dysprosium and Modified with Nickel: A Highly Efficient and Heterogeneous Catalyst for the Hydrogenation of Benzene, Ethylbenzene and Xylenes

  • R. V. Shafigulin
  • E. O. Filippova
  • A. A. Shmelev
  • A. V. BulanovaEmail author
Article
  • 16 Downloads

Abstract

The catalytic activity of synthesized by the template method mesoporous silica doped with dysprosium and modified with nickel (Dy-Ni/MPS) in the hydrogenation of benzene, ethylbenzene and xylenes has been studied. The catalyst is characterized by various techniques such as TEM, SEM, BET, XRD, ICP, XRF analyses. It is shown that the presence of dysprosium in the MPS structure increases the activity of the catalyst. The catalytic activity of the catalyst (Dy-Ni/MPS) has been explored in hydrogenation reaction of benzene derivatives with excellent conversion (96–100%) at low pressure.

Graphical Abstract

Keywords

Heterogeneous catalyst Dy-Ni/MPS Hydrogenation of benzene derivatives 

Notes

Acknowledgements

The work is supported by Russian Foundation for Basic Research (project 17-43-630358 r_a).

References

  1. 1.
    Xiao-Na, Li et al (2017) Metal-mediated catalysis in the gas phase: a review. Chin J Catal 38:1515–1527CrossRefGoogle Scholar
  2. 2.
    Mallikarjuna K, Kim H (2017) Synthesis and characterization of highly active Cu/Pd bimetallic nanostructures. Colloids Surf A 535:194–200CrossRefGoogle Scholar
  3. 3.
    Peyrovi MH, Parsafard N, Mohammadian Z (2017) Benzene selective hydrogenation over supported Ni (nano-) particles catalysts: catalytic and kinetics studies. Chin J Chem Eng 26:521–528CrossRefGoogle Scholar
  4. 4.
    Ma X, Li J, Liu H, Tang J (2018) CeHIO6•4H2O: A novel, highly efficient catalyst for degrading organic dyes without light illumination at room temperature. J Phys Chem Solids 118:150–157CrossRefGoogle Scholar
  5. 5.
    Chiu W, Horng R, Chou H (2013) Hydrogen production from an ethanol reformer with energy saving approaches over various catalysts. Int J Hydrogen Energy 38:2760–2769CrossRefGoogle Scholar
  6. 6.
    Sakita AMP, Valles E, Della Noce R, Benedetti A (2018) Novel NiFe/NiFe-LDH composites as competitive catalysts for clean energy purposes. Appl Surf Sci 447:107–116CrossRefGoogle Scholar
  7. 7.
    Kumar Roy S, Dutta D, Talukdar A (2018) Highly effective methylated Ti MCM-41 catalyst for cyclohexene oxidation. Mater Res Bull 103:38–46CrossRefGoogle Scholar
  8. 8.
    Veisi H, Vafajoo S, Bahrami K, Mozafari B (2018) Preparation of polydopamine sulfamic acid- functionalized silica gel as heterogeneous and recyclable nanocatalyst for acetylation of alcohols and amines under solvent-free conditions. Catal Lett 148:2734–2745CrossRefGoogle Scholar
  9. 9.
    Abrokwah RY, Deshmane VG, Kuila D (2016) Comparative performance of M-MCM-41 (M: Cu, Co, Ni, Pd, Zn and Sn) catalysts for steam reforming of methanol. J Mol Catal 425:10–20CrossRefGoogle Scholar
  10. 10.
    Takamasa K, Fukue N, Shinichi K, Katsuya K (2018) Optimization of carboxyl-functionalized mesoporous silica for the selective adsorption of dysprosium. J Environ Chem Eng 5:5590–5998Google Scholar
  11. 11.
    Kumar S, Malik MM, Purohit R (2018) Synthesis of high surface area mesoporous silica materials using soft templating approach. Mater Today Proc 5: 4128–4133CrossRefGoogle Scholar
  12. 12.
    Lehmann T, Wolff T, Hamel C, Veit P, Garke B, Seidel-Morgenstern A (2012) Physico-chemical characterization of Ni/MCM-41 synthesized by a template ion exchange approach. Microporous Mesoporous Mater 151:113–125CrossRefGoogle Scholar
  13. 13.
    Hosseinzadeh R, Aghili N, Tajbakhsh M (2016) Synthesis, characterization and catalytic application of MCM 41 supported phenanthrolinium dibromide catalyst for aza-michael addition reaction in aqueous medium. Catal Lett 146:1194–1203CrossRefGoogle Scholar
  14. 14.
    Ambursa MM, Sudarsanam P, Voon LH, Abd Hamid SB, Bhargava SK (2017) Bimetallic Cu-Ni catalysts supported on MCM-41 and Ti-MCM-41 porous materials for hydrodeoxygenation of lignin model compound into transportation fuels. Fuel Process Technol 162:87–97CrossRefGoogle Scholar
  15. 15.
    Abd Hamid SB, Ambursa MM, Sudarsanam P, Voon LH, Bhargava SK (2017) Effect of Ti loading on structure-activity properties of Cu-Ni/Ti-MCM-41 catalysts in hydrodeoxygenation of guaiacol. Catal Commun 94:18–22CrossRefGoogle Scholar
  16. 16.
    Luo N, Cao Y, Li J, Guo W, Zhao Z (2016) Preparation pf Ni2P/Zr-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil. J Fuel Chem Technol 44:76–83CrossRefGoogle Scholar
  17. 17.
    Khorshidi A (2016) Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation. Chin J Catal 37:153–158CrossRefGoogle Scholar
  18. 18.
    Kowalczyk A, Borcuch A, Michalik M, Rutkowska M, Gil B, Sojka Z (2017) MCM-41 modified with transition metals by template ion-exchange method as catalysts for selective catalytic oxidation of ammonia to dinitrogen. L Chmielarz 240:9–21Google Scholar
  19. 19.
    Mamontov GV, Gorbunova A, Vyshegorodtseva E, Zaikovskii V, Vodyankina O (2018) Selective oxidation of CO in the presence of propylene over Ag/MCM-41. Catalysis Today. In press, accepted manuscriptGoogle Scholar
  20. 20.
    Hajjami M, Cheraghi M (2016) Synthesis of Pd-complex supported on MCM-41 and its catalytic activity for the C–C coupling reactions. Catal Lett 146:1099–1106CrossRefGoogle Scholar
  21. 21.
    Deng F, Li N, Tang S, Liu C, Yue H, Liang B (2018) Evolution of active sites and catalytic consequences of mesoporous MCM-41 supported copper catalysts for the hydrogenation of ethylene carbonate. Chem Eng J 334:1943–1953CrossRefGoogle Scholar
  22. 22.
    Romero A, Nieto-Marquez A, Alonso E (2017) Bimetallic Ru:Ni/MCM-48 catalysts for the effective hydrogenation of D-glucose into sorbitol. Appl Catal A 529:49–59CrossRefGoogle Scholar
  23. 23.
    Jibril BY, Ahmed S (2006) Oxidative dehydrogenation of propane over Co, Ni and Mo mixed oxides/MCM-41 catalysts: effects of intra- and extra-framework locations of metals on product distributions. Catal Commun 7:990–996CrossRefGoogle Scholar
  24. 24.
    Taghavinezhad P, Haghighi M, Alizadeh R (2018) Sonosynthesis of VOx/MCM-41 nanocatalyst enhanced by various metal oxides (Mg, Al, Zr) for CO2-oxidative dehydrogenation of ethane to ethylene. Microporous Mesoporous Mater 261:63–78CrossRefGoogle Scholar
  25. 25.
    Deshmane VG, Abrokwah RY, Kuila D (2015) Synthesis of stable Cu-MCM-41 nanocatalysts for H2 production with high selectivity via steam reforming of methanol. Int J Hydrogen Energy 40:1–14CrossRefGoogle Scholar
  26. 26.
    Appaturi JM, Selvaraj M, Abdul Hamid B S (2018) Synthesis of 3-(2-furylmethylene)-2,4-penttanedione using dl-Alanine functionalized MCM-41 catalyst via Knoevangel condensation reaction. Microporous Mesoporous Mater 260:260–269CrossRefGoogle Scholar
  27. 27.
    Pirouzmand M, Gharehbaba A, Ghasemi Z, Khaaje S (2017) [CTA]Fe/MCM-41: An efficient and reusable catalyst for green synthesis of xanthene derivatives. Arab J Chem 10:1070–1076CrossRefGoogle Scholar
  28. 28.
    Teimouri A, Mahmoudsalehi M, Salavati H (2018) Catalytic oxidative desulfurization of dibenzothiophene utilizing molybdenium and vanadium oxides supported on MCM-41. Int J Hydrogen Energy 43:14816–14833CrossRefGoogle Scholar
  29. 29.
    Hammer B, Norskov JK (1995) Electronic factors determining the reactivity of metals. Surf Sci 343:211–220CrossRefGoogle Scholar
  30. 30.
    Pallassana V, Neurock M (2000) Electronic factors governing ethylene hydrogenation and dehydrogenation activity of pseudomorphic PdML/Re, PdML/Ru, Pd, and PdML/Au surfaces. J Catal 191:301–317CrossRefGoogle Scholar
  31. 31.
    Boudjahem A-G, Redjel A, Mokrane T (2012) Preparation, characterization and performance of Pd/SiO2 catalyst for benzene catalytic hydrogenation. J Ind Eng Chem Vol 18:303–308CrossRefGoogle Scholar
  32. 32.
    Rahaman M, Vasiur AM, Vannice (1991) The hydrogenation of toluene and o-, m-, and p-xylene over palladium: I. kinetic behavior and o-xylene isornerization. J Catal 127:251–266CrossRefGoogle Scholar
  33. 33.
    Neyestanaki AK, Malki-Arvela P, Backman H, Karhu H, Salmi T, Valyrynen J, Murzin DY (2003) Gas-phase hydrogenation of o-xylene over Pt/knitted silica-fiber catalysts. Ind Eng Chem Res 42: 3230–3236CrossRefGoogle Scholar
  34. 34.
    Boudjahema A-G, Bettahar MM (2017) Effect of oxidative pre-treatment on hydrogen spillover for a Ni/SiO2 catalyst. J Mol Catal A Chem 426:190–197CrossRefGoogle Scholar
  35. 35.
    Wang X, Chen J (2017) Effects of indium on Ni/SiO2 catalytic performance in hydrodeoxygenation of anisole as model bio-oil compound: Suppression of benzene ring hydrogenation and C–C bond hydrogenolysis. Chin J Catal 38:1818–1830CrossRefGoogle Scholar
  36. 36.
    Feng X, Dong C, Ping D, Geng J, Hang J, Dong X (2018) Zr-Modified SBA-15 supported Ni catalysts with excellent catalytic performance of CO selective methanation in H2-rich fuels. Catal Lett 148:2967–2973CrossRefGoogle Scholar
  37. 37.
    Shafigulin RV, Filimonov NS, Filippova EO, Shmelev AA, Bulanova AV (2017) Kinetic and thermodynamic specific features of hydrogenation of Hexene-1, Heptene-1, and Cyclohexene on catalyst containing copper nanoparticles. Russ J Appl Chem 10:1648–1654CrossRefGoogle Scholar
  38. 38.
    Shubina EG, Filimonov NS, Shafigulin RV et al (2017) Effect of size of nickel nanoparticles on hydrogenation of benzene. Petroleum Chem 57:410–414CrossRefGoogle Scholar
  39. 39.
    Restrepo-Garcia JR, Ramírez GE, Baldovino-Medrano VG (2018) Hydroprocessing of phenanthrene over sulfided Fe-W supported on modified SBA-15. Catal Lett 148:621–641CrossRefGoogle Scholar
  40. 40.
    Nakamura K, Mizuta R, Suganuma S et al (2017) Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids. Catal Commun 102:103–107CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • R. V. Shafigulin
    • 1
  • E. O. Filippova
    • 1
  • A. A. Shmelev
    • 1
  • A. V. Bulanova
    • 1
    Email author
  1. 1.Department of ChemistrySamara UniversitySamaraRussia

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