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Synthesis of Fe–Co–Ce/Zeolite A-3 Catalysts and their Selectivity to Light Olefins for Fischer–Tropsch Synthesis in Fixed-Bed Reactor

  • Reza Nohtani
  • Ali Akbar MirzaeiEmail author
  • Amir Eshraghi
Article
  • 26 Downloads

Abstract

In the present work, Fe–Co–Ce/Zeolite A-3 catalysts were prepared, using the impregnation method and applied in Fischer–Tropsch Synthesis (FTS). The catalyst’s performance was investigated by changing the catalyst’s composition and process conditions. Increased pressure from 2 to 10 and H2/CO ratio from 1 to 4 were accompanied by decreased olefin to paraffin proportion and increased \({\text{C}}_{4}^{+}\) production. Decline in the GHSV led to decrease in methane and light olefin generation, and a significant increase in the number of carbon in the products. The catalysts were characterized by SEM, BET, STA and XRD. Catalyst composition was changed with different loading of support (Zeolite A-3) and metals (Fe, Co, Ce). Finally, 45%Fe–45%Co–10%Ce/60%Zeolite A-3 catalyst was judged to be the best composition to obtain the optimal operation conditions (high selectivity towards light olefins and low selectivity towards methane, simultaneously).

Graphical Abstract

Keywords

Catalyst composition Reaction conditions FT reaction Light olefins selectivity 

Notes

Acknowledgements

This work is financially and instrumentally supported by the University of Sistan and Baluchestan.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Reza Nohtani
    • 1
  • Ali Akbar Mirzaei
    • 1
  • Amir Eshraghi
    • 1
  1. 1.Department of Chemistry, Faculty of SciencesUniversity of Sistan and BaluchestanZahedanIran

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