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Catalysis Letters

, Volume 149, Issue 1, pp 292–302 | Cite as

A New Lewis Acidic Zr Catalyst for the Synthesis of Furanic Diesel Precursor from Biomass Derived Furfural and 2-Methylfuran

  • Yu-Jia Luo
  • Yi-Han Zhou
  • Yao-Bing HuangEmail author
Article
  • 83 Downloads

Abstract

Herein, we reported the first time to use Lewis type acidic Zr/SBA-15 catalyst for the hydroxyalkylation/alkylation (HAA) reaction of biomass derived furfural and 2-methylfuran (2-MF) to produce diesel precursors. Characterizations such as XRD, XPS, SEM and TEM, were used to provide detailed structure features of mesoporous catalysts of varied Si/Zr ratios. Among the catalysts, Zr/SBA-15(20) (Si/Zr ratio(mol:mol) = 20:1) possessed the highest catalytic activity in the HAA reaction, providing 93.9% yield of the target product at 140 °C under neat condition. Lewis acid was revealed as the dominant active sites for the HAA reaction. Reaction parameters including reaction temperature, catalyst loading and furfural/2-MF ratio were investigated and found to affect the reaction efficiency and product yields. Besides, the optimal Zr/SBA-15(20) catalyst maintained outstanding recyclability in the recycling test, offering almost comparable reaction yields as freshly prepared catalyst. This work not only opens up a new concept by using Lewis catalyst for HAA reaction to synthesize diesel precursors from biomass, but also enriches the catalyst inventory of HAA reaction by providing a pH-neutral, recyclable and stable catalyst.

Graphical Abstract

Keywords

Zr/SBA-15 Hydroxyalkylation/alkylation Diesel precursor 2-Methylfuran Furfural 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (NSFC 21502095), Natural Science Foundation of Jiangsu Province (BK20150872), Qing Lan Project of Jiangsu Province and Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP PPZY2015C221) and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Supplementary material

10562_2018_2599_MOESM1_ESM.docx (446 kb)
Supplementary material 1 (DOCX 446 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, College of Chemical EngineeringNanjing Forestry UniversityNanjingChina
  2. 2.Department of Chemical and Biomolecular EngineeringUniversity of California–BerkeleyBerkeleyUSA

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