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The Synthesis of Ni–Cu Alloy Nanofibers via Vacuum Thermal Co-reduction Toward Hydrogen Generation from Hydrazine Decomposition

  • Hefang Wang
  • Qinglong Fu
  • Guanyan Zhang
  • Yangyang Sun
Article
  • 86 Downloads

Abstract

A safe and reductant-free method based on co-reduction of nickel and copper oxides via vacuum thermal treatment has been developed for the synthesis of Ni–Cu alloy nanofibers, which includes electrospinning of a nickel acetate/copper acetate/polyvinylpolypyrrolidone (NiAc/CuAc/PVP) precursor solution, followed by vacuum thermal reduction. On account of the synergistic effect between Cu and Ni, the Ni–Cu alloy nanofibers catalyst with an optimal composition exhibits good catalytic performance for the decomposition of hydrous hydrazine in NaOH solution.

Graphical Abstract

Ni–Cu alloy nanofibers have been prepared by a vacuum thermal co-reduction method, and further used as catalysts for hydrous hydrazine decomposition.

Keywords

Ni–Cu alloy Nanofibers Catalysis Hydrogen production 

Notes

Acknowledgements

This work is financially supported by National Natural Science Foundation of China (No. 21776058) and Natural Sciences Foundation of Hebei province (No. B2017202226).

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10562_2018_2575_MOESM1_ESM.docx (4.1 mb)
Supplementary material 1 (DOCX 4150 KB)

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Chemical Engineering and TechnologyHebei University of TechnologyTianjinChina

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