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Kinetics of Thiocyanate Formation by Reaction of Cyanide and Its Iron Complexes with Thiosulfate

  • Irina Kurashova
  • Alexey KamyshnyJr.Email author
Original Article
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Abstract

Reactions between cyanide and compounds, which contain S–S bonds, in aqueous media result in formation of thiocyanate. In this work, we studied the kinetics of reactions of thiosulfate with free cyanide and its complexes under environmental conditions. Rates of reactions between cyanide species and thiosulfate decrease in the following order: CN > HCN > [Fe(CN)6]3− > [Fe(CN)6]4−. However, at neutral and slightly acidic pH range, reaction of thiosulfate with iron-cyanide complexes outcompetes its reaction with free cyanide, which exists in equilibrium with complexed cyanide. At environmentally relevant conditions, the characteristic time of reaction between free cyanide and thiosulfate was found to be tens of thousands of years, while for iron-cyanide complexes it was found to be hundreds to millions of years. Examples of application of kinetic parameters for calculation of rates of cyanide consumption in industrial (coke oven wastewater) and non-polluted natural aquatic system (Delaware Great Marsh) are provided.

Keywords

Thiocyanate Sulfide oxidation intermediates Cyanide Thiosulfate Hexacyanoferrate(II) Hexacyanoferrate(III) 

Notes

Acknowledgements

This work was supported by the Marie Curie Actions CIG PCIG10-GA-2011-303740 (ThioCyAnOx) Grant. We are grateful to Ido Ben Laish for help with establishing experimental protocols for analyses of cyanide and sulfur species. The authors would like to thank Valeria Boyko for assistance with experiments.

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.The Department of Geological and Environmental SciencesBen-Gurion University of the NegevBeer ShevaIsrael

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