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Polyester-supported Chitosan-Poly(vinylidene fluoride)-Inorganic-Oxide-Nanoparticles Composites with Improved Flame Retardancy and Thermal Stability

  • Ahmed Abed
  • Nabil BouaziziEmail author
  • Stéphane Giraud
  • Ahmida El Achari
  • Christine Campagne
  • Olivier Thoumire
  • Reddad El Moznine
  • Omar Cherkaoui
  • Julien Vieillard
  • Abdelkrim Azzouz
Article
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Abstract

Polyester (PET) was pre-activated by atmospheric air plasma and coated by various inorganic oxide nanoparticles (MOx) such as titanium dioxide (TiO2), zinc oxide (ZnO), and silicon oxide (SiO2), using poly(vinylidene fluoride) (PVDF) and chitosan (CT) as binders. The resulting PET-PVDF-MOx-CT composites were thermally compressed and then characterized by scanning electron microscopy, Fourier infrared spectroscopy, thermal gravimetric analysis, and flame retardancy (FR) ability tests. PET modifications resulted in more thermally stable and less harmful composites with weaker hazardous gas release. This was explained in terms of structure compaction that blocks pyrolysis gas emissions. CT incorporation was found to reduce the material susceptibility to oxidation. This judicious procedure also allowed improving flame retardancy ability, by lengthening the combustion delay and slowing the flame propagation. Chitosan also turned out to contribute to a possible synergy with the other polymers present in the synthesized materials. These results provide valuable data that allow understanding the FR phenomena and envisaging low-cost high FR materials from biodegradable raw materials.

Keywords

Polyester nonwovens Composite PVDF Flame retardancy Material oxides Chitosan 

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Notes

Acknowledgments

This work was financially supported by the GEMTEX Laboratory-France. We are grateful to Christian Catel, from ENSAIT, Roubaix, France for support through plasma treatment.

Supplementary material

10118_2020_2336_MOESM1_ESM.pdf (451 kb)
Polyester-supported Chitosan-Poly(vinylidene fluoride)-Inorganic-Oxide-Nanoparticles Composites with Improved Flame Retardancy and Thermal Stability

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Copyright information

© Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Ahmed Abed
    • 1
    • 2
    • 3
  • Nabil Bouazizi
    • 1
    Email author
  • Stéphane Giraud
    • 1
  • Ahmida El Achari
    • 1
  • Christine Campagne
    • 1
  • Olivier Thoumire
    • 4
  • Reddad El Moznine
    • 2
  • Omar Cherkaoui
    • 3
  • Julien Vieillard
    • 5
  • Abdelkrim Azzouz
    • 6
  1. 1.ENSAIT, GEMTEX – Laboratoire de Génie et Matériaux TextilesLilleFrance
  2. 2.Laboratory LPMC, Faculty of Science El JadidaChouaib Doukkali UniversityEl JadidaMorocco
  3. 3.Laboratory REMTEXESITHCasablancaMorocco
  4. 4.Normandie Univ., UNIROUEN, CNRS, PBS (UMR 6270)EvreuxFrance
  5. 5.Normandie Univ., UNIROUEN, INSA Rouen, CNRS, COBRA (UMR 6014)EvreuxFrance
  6. 6.Nanoqam, Department of ChemistryUniversity of Quebec at MontrealMontrealCanada

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