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Chinese Journal of Polymer Science

, Volume 37, Issue 10, pp 981–989 | Cite as

Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization

  • Wei-Qiang Fu
  • Gui-Nan Zhu
  • Jian-Bing ShiEmail author
  • Bin Tong
  • Zheng-Xu Cai
  • Yu-Ping DongEmail author
Article
  • 21 Downloads

Abstract

A series of new photodegradable poly(furan-amine)s (PFAs) were synthesized by a one-pot, catalyst-free, multicomponent cyclopolymerization between diisocyanides, dialkylacetylene dicarboxylates, and aromatic dialdehydes. All polymerizations were conducted in toluene at 100 °C for 6 h without inert gas protection and furnished polymers with a satisfactory molecular weight (Mw up to 32200) and yield. The PFA structure was confirmed by spectroscopic techniques, such as GPC, FTIR, and NMR, as well as by comparison with a model compound. The polymers exhibited good solubility in common organic solvents and thermal stability. All the PFAs had high refractive indices in the visible light region (400 nm to 800 nm). Moreover, the PFAs were substantially degraded by UV irradiation due to the presence of furan rings. The film thickness reduction rate could be over 90%.

Keywords

Photodegradation Multicomponent reaction Catalyst-free polymerization 

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Notes

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 21490574, 21875019, 51673024, and 51803009) and Beijing Institute of Technology Research Fund Program for Young Scholars.

Supplementary material

10118_2019_2281_MOESM1_ESM.pdf (1.2 mb)
Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization

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Copyright information

© Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, School of Materials Science and EngineeringBeijing Institute of TechnologyBeijingChina

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