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Chinese Journal of Polymer Science

, Volume 37, Issue 3, pp 243–252 | Cite as

Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

  • Pei XuEmail author
  • Zhao-Pei Cui
  • Gang Ruan
  • Yun-Sheng DingEmail author
Article
  • 21 Downloads

Abstract

To investigate the performance of graphene (Gra) modified with ethoxycarbonyl ionic liquid (IL), chain mobility and crystallization kinetics of poly(L-lactic acid) (PLLA), a series of PLLA nanocomposites have been prepared using solution-cast method. IL can improve the dispersion of Gra in PLLA matrix and the samples containing IL have higher growth rate of PLLA spherulite than neat PLLA does. PLLA/IL/Gra and PLLA/2Gra exhibit the same relaxation strength and time of αN relaxation that corresponds to the longest normal mode motion at 110−140 °C. PLLA/IL/Gra shows a faster crystallization rate than PLLA/2Gra does, which might be attributed to the Gra-imidazolium cation interaction in IL modified Gra, the significant dispersion effect of IL at Gra surface, and the increase of nuclei density of PLLA/IL/Gra.

Keywords

Ionic liquid Graphene PLLA Crystallization Dielectric behavior 

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Notes

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 51603060) and the Fundamental Research Funds for the Central Universities (No. JZ2017YYPY0250).

Supplementary material

10118_2019_2192_MOESM1_ESM.pdf (173 kb)
Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

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Copyright information

© Chinese Chemical Society, Institute of Chemistry (CAS) and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Functional Materials and DevicesHefei University of TechnologyHefeiChina

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