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Chinese Journal of Polymer Science

, Volume 37, Issue 2, pp 189–196 | Cite as

Improving the Thermal Conductivity and Mechanical Properties of Two-component Room Temperature Vulcanized Silicone Rubber by Filling with Hydrophobically Modified SiO2-Graphene Nanohybrids

  • Bo Yang
  • Shuang-Hong Zhang
  • Yi-Feng Zou
  • Wen-Shi Ma
  • Guo-Jia Huang
  • Mao-Dong Li
Article
  • 27 Downloads

Abstract

The SiO2 nanoparticles were coated on the surface of graphene oxide (GO) by sol-gel method to get the SiO2-G compound. The SiO2-G was restored and oleophylically modified to prepare hydrophobic modified SiO2-G (HM-SiO2-G) which was subsequently added to silicone rubber matrix to prepare two-component room temperature vulcanized (RTV-2) thermal conductive silicone rubber. The morphology, chemical structure and dispersity of the modified graphene were characterized with SEM, FTIR, Raman, and XPS methods. In addition, the heat-resistance behavior, mechanical properties, thermal conductivity, and electrical conductivity of the RTV-2 silicone rubber were also studied systematically. The results showed that the SiO2 nanoparticles were coated on graphene oxide successfully, and HM-SiO2-G was uniformly dispersed in RTV-2 silicone rubber. The addition of HM-SiO2-G could effectively improve the thermal stability, mechanical properties and thermal conductivity of RTV-2 silicone rubber and had no great influence on the electrical insulation performance.

Keywords

Graphene Modification Two components Room temperature vulcanized silicone rubber Thermal conductivity 

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Notes

Acknowledgements

The authors would like to thank the Guangdong Province Science and Technology projects (Grant No. 2017A040402005) and Guangdong Bureau of Quality and Technical Supervision Science and Technology projects (Grant No. 2017CT30) for financial support of this work.

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Copyright information

© Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Bo Yang
    • 1
  • Shuang-Hong Zhang
    • 1
  • Yi-Feng Zou
    • 2
  • Wen-Shi Ma
    • 2
  • Guo-Jia Huang
    • 1
  • Mao-Dong Li
    • 1
  1. 1.Guangzhou Special Pressure Equipment Inspection and Research InstituteGuangzhouChina
  2. 2.School of Materials Science and TechnologySouth China University of TechnologyGuangzhouChina

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