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Synthesis of nanosilica from fly ash and its utilization with lime sludge in concrete: an environmentally friendly and sustainable solution

  • Prabhat Vashistha
  • S. K. Singh
  • Dharm Dutt
  • Vivek KumarEmail author
Original Paper
  • 13 Downloads

Abstract

Solid waste generation and its disposal is becoming the cause of concern all over the world. Paper industry is not exceptional as lime sludge and fly ash need appropriate utilization to reduce the threat for the environment. Application of these materials in other industries could be the appropriate alternative. In this paper, fly ash is utilized for nanosilica synthesis, because of the presence of silica precursor in very high amount. Nanosilica was synthesized with the alkali treatment of ash and acid precipitation. The produced nanosilica was characterized for crystallinity, specific surface area, size and morphology. This synthesized nanosilica is used with lime sludge in cement-based concrete. Concrete blocks were evaluated for compressive strength after 7 and 28 days of curing. It is observed that the compressive strength of concrete blocks with only lime sludge decreased up to 50% with the replacement of cement by lime sludge from 10 to 40%. Concrete blocks produced with the addition of 0.3, 0.6 and 1.0% nanosilica and different proportions of lime sludge attained up to 30% more compressive strength in comparison with the blocks without nanosilica.

Graphic abstract

Keywords

Solid waste Lime sludge Fly ash Nanosilica Concrete 

Notes

Acknowledgements

The authors would like to thank the staff of Indian Institute of Technology (IIT) Roorkee and Central Building Research Institute (CBRI) Roorkee for the support in successful completion of the work.

Funding

This work was financially supported by Department of Science and Technology (Government of India) and Ruchira Paper Industry Kalaamb, Himachal Pradesh (India). The funding was provided under the scheme of Uchatar Aviskar Yojana (UAY) with award number UAY-1012 DPT.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

References

  1. Abo-El-Enein SA, Heikal M, Amin MS, Negm HH (2013) Reactivity of dealuminated kaolin and burnt kaolin using cement kiln dust or hydrated lime as activators. Constr Build Mater 47:1451–1460.  https://doi.org/10.1016/j.conbuildmat.2013.06.078 CrossRefGoogle Scholar
  2. Abo-El-Enein SA, Hashem FS, Amin MS, Sayed DM (2016) Physico chemical characteristics of cementitious building materials derived from industrial solid wastes. Constr Build Mater 126:983–990.  https://doi.org/10.1016/j.conbuildmat.2016.09.112 CrossRefGoogle Scholar
  3. Adesanya E, Ohenoja K, Luukkonen T, Kinnunen P, Illikainen M (2018) One-part geopolymer cement from slag and pretreated paper sludge. J Clean Prod 185:168–175.  https://doi.org/10.1016/j.jclepro.2018.03.007 CrossRefGoogle Scholar
  4. Brás I, Almeida R, Silva PC, Marques L (2016) Industrial waste valorization to produce eco-materials for construction applications. IJESD 7:559CrossRefGoogle Scholar
  5. CARE rating on credit perspective, Indian paper industry: out of the woods paper industry (2016).https://www.careratings.com/upload/NewsFiles/SplAnalysis/Indian%20Paper%20Industry%20-%20Out%20of%20the%20woods.pdf .
  6. Chaidir D A, Kristianto H, Andreas A (2016) Synthesis of nanosilica originated from fly ash using sol-gel method with methanol as solvent. Seminar Nasional Teknik Kimia Kejuangan, p 15Google Scholar
  7. Chaudhary PK (2011) Planning commission government of India. https://planningcommission.nic.in/aboutus/committee/wrkgrp12/wg_paper.pdf . Accessed 14 Nov 2011
  8. Cordeiro GC, Toled FRD, Tavares LM, Fairbairn EMR (2008) Pozzolanic activity and filler effect of sugar cane bagasse ash in Portland cement and lime mortars. Cem Concr Comp 30:410–418.  https://doi.org/10.1016/j.cemconcomp.2008.01.001 CrossRefGoogle Scholar
  9. Hassan AF, Abdelghny AM, Elhadidy H, Youssef AM (2014) Synthesis and characterization of high surface area nanosilica from rice husk ash by surfactant-free sol-gel method. J Sol-Gel Sci Technol 69:465–472.  https://doi.org/10.1007/s10971-013-3245-9 CrossRefGoogle Scholar
  10. Indian standard concrete mix proportioning: guidelines (First revision) IS 10262:2009, Bureau of India Standard, New Delhi, India. https://civilcafe.weebly.com/uploads/2/8/9/8/28985467/is_code_for_concrete_mix_design.pdf
  11. Isabel R (2015) Silica nano particles synthesized from boiler spent ash: Value addition to an industrial waste. J Hazard Mater 286:252–260CrossRefGoogle Scholar
  12. Jo BW, Kim CH, Tae GH, Park JB (2007) Characteristics of cement mortar with nano-SiO2 particles. Const build Mater 21:1351–1355.  https://doi.org/10.1016/j.conbuildmat.2005.12.020 CrossRefGoogle Scholar
  13. Kamath SR, Proctor A (1998) Silica gel from rice hull ash: preparation and characterization. Cereal Chem 75:484–487.  https://doi.org/10.1094/CCHEM.1998.75.4.484 CrossRefGoogle Scholar
  14. Kumar KA, Rajasekhar K, Sashidhar C (2016) Experimental investigation on fly ash and lime sludge in cement mortar. IJLTEMAS 5:2278–2540Google Scholar
  15. Liou TH, Yang CC (2011) Synthesis and surface characteristics of nanosilica produced from alkali-extracted rice husk ash. Mater Sci Eng B 176:521–529.  https://doi.org/10.1016/j.mseb.2011.01.007 CrossRefGoogle Scholar
  16. Maheswaran S, Kumar VR, Bhuvaneshwari B, Palani GS, Iyer NR (2011) Studies on lime sludge for partial replacement of cement. AMM 71:1015–1019.  https://doi.org/10.4028/www.scientific.net/AMM.71-78.1015 CrossRefGoogle Scholar
  17. Malaiskiene J, Kizinievic O, Kizinievic V, Boris R (2018) The impact of primary sludge from paper industry on the properties of hardened cement paste and mortar. Constr Build Mater 172:553–561.  https://doi.org/10.1016/j.conbuildmat.2018.04.011 CrossRefGoogle Scholar
  18. Modolo RCE, Senff L, Labrincha JA, Ferreira VM, Tarelho LAC (2014) Lime mud from cellulose industry as raw material in cement mortars. Mater Constr 64:33.  https://doi.org/10.3989/mc.2014.00214 CrossRefGoogle Scholar
  19. Mollah MYA, Yu W, Schennach R, Cocke DL (2000) A Fourier transform infrared spectroscopic investigation of the early hydration of Portland cement and the influence of sodium lignosulfonate. Cement Concrete Res 30:267–273.  https://doi.org/10.1016/S0008-8846(99)00243-4 CrossRefGoogle Scholar
  20. Monte MC, Fuente E, Blanco A, Negro C (2009) Waste management from pulp and paper production in the European Union. Waste Manag 29:293–308.  https://doi.org/10.1016/j.wasman.2008.02.002 CrossRefGoogle Scholar
  21. Nakamoto K (2006) Infrared and Raman spectra of inorganic and coordination compounds. Handb Vib Spectrosc.  https://doi.org/10.1002/0470027320.s4104 Google Scholar
  22. Nataraja MC, Das L (2010) Concrete mix proportioning as per IS 10262: 2009–comparison with IS 10262: 1982 and ACI 211.1–91. The Indian Concr J 64–70.Google Scholar
  23. Parida S (2015) Effect of nano silica on the compressive strength of concrete. Dissertation, National Institute of Technology Rourkela.Google Scholar
  24. Sakka S, Kosuko H (2000) Handbook of sol-gel science and technology. Volume I: Solgel Processing.Google Scholar
  25. Shenoy J (2018) Indian paper industry poised touched 25 million in 2019–20. The times of India.https://timesofindia.indiatimes.com/articleshow/63096462.cms?utm_source=contentofinterest&utm_medium=text&utm_campaign=cppst. Accessed 17 February 2018.
  26. Sobolev K, Gutiérrez MF (2005) How nanotechnology can change the concrete world. Am Ceram Soc Bull 84:14Google Scholar
  27. Soni Y (2015) Lime sludge: an emerging alternate construction building material for the partial replacement of fine aggregate. AIChE Annual meeting Nov. 8–13 salt lake city U.S.A).Google Scholar
  28. Thuadaiji N, Nuntiya A (2008) Synthesis and characterization of nanosilica from rice husk ash prepared by precipitation method. J Nat Sci Spec Issue Nanotechnol 7:59–65Google Scholar
  29. Torabian IF, Redaelli E, Lollini F, Li W, Bertolini L (2016) Effects of nanosilica on compressive strength and durability properties of concrete with different water to binder ratios. Adv Mater Sci Eng.  https://doi.org/10.1155/2016/8453567 Google Scholar
  30. Yan S, Sagoe-Crentsil K, Shapiro G (2011) Reuse of de-inking sludge from wastepaper recycling in cement mortar products. J Environ Manag 92:2085–2090.  https://doi.org/10.1016/j.jenvman.2011.03.028 CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Prabhat Vashistha
    • 1
  • S. K. Singh
    • 2
  • Dharm Dutt
    • 1
  • Vivek Kumar
    • 3
    Email author
  1. 1.Indian Institute of TechnologyRoorkeeIndia
  2. 2.AcSIR, CSIR-Central Building Research InstituteRoorkeeIndia
  3. 3.Centre for Rural Development and TechnologyIndian Institute of Technology DelhiNew DelhiIndia

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