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Journal of Solid State Electrochemistry

, Volume 23, Issue 12, pp 3449–3458 | Cite as

Nickel iron carbonate hydroxide hydrate decorated with CeOx for highly efficient oxygen evolution reaction

  • Jinhua Cai
  • Jiangen Huang
  • Shichen Xu
  • Ling Yuan
  • Xueren Huang
  • Zhipeng HuangEmail author
  • Chi Zhang
Original Paper
  • 39 Downloads

Abstract

Highly active, durable, and inexpensive nanostructured catalysts are crucial for achieving efficiently and economically electrochemical water splitting. In recent years, the introduction of cerium (Ce) into electrocatalysts is an effective way to improve the performance of oxygen evolution reaction (OER). Herein, we report a cerium oxide deposited nickel iron carbonate hydroxide hydrate (NiFeCH(Ce)) on the carbon fiber paper through two-step hydrothermal/electrodeposition approach. The NiFeCH(Ce) not only exhibits a remarkably improved OER performance with an overpotential of 252 mV at a current density of 100 mA cm−2, but also possesses a small Tafel slope of 59 mV dec−1, the both values superior to the most non-noblemetal-based OER electrocatalysts reported. X-ray photoelectron spectroscopy analysis shows that the super OER electrocatalysis performance of the NiFeCH(Ce) was related intensely with the introduction of Ce ions, which not only richer surface defects and higher oxygen adsorption capacity, but also provide more effective charge and mass transfer between intermediates and catalysts, making a great contribution to the OER enhancement.

Keywords

Nickel iron carbonate hydroxide hydrate Oxygen evolution reaction Cerium oxide Overall water splitting Interfacial effect 

Notes

Acknowledgements

This research was financially supported by the National Natural Science Foundation of China (51772214, 51432006 and 21561017), the Ministry of Science and Technology of China (2011DFG52970), the Ministry of Education of China (IRT14R23), 111 Project (B13025), Jiangsu Province (2011-XCL-019 and 2013-479), the Innovation Program of Shanghai Municipal Education Commission, the Natural Science Foundation of Guangxi Province (2018JJA160004) and the Education Department Foundation of the Jiangxi Province (GJJ160730).

Compliance with ethical standards

Conflict of interest

There are no conflicts to declare.

Supplementary material

10008_2019_4445_MOESM1_ESM.docx (19.9 mb)
ESM 1 (DOCX 20399 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Jinhua Cai
    • 1
  • Jiangen Huang
    • 1
  • Shichen Xu
    • 2
  • Ling Yuan
    • 2
  • Xueren Huang
    • 3
  • Zhipeng Huang
    • 2
    Email author
  • Chi Zhang
    • 2
  1. 1.College of Chemistry & Chemical EngineeringJinggangshan UniversityJianPeople’s Republic of China
  2. 2.School of Chemical Science and EngineeringTongji UniversityShanghaiPeople’s Republic of China
  3. 3.College of Petroleum and Chemical EngineeringBeibuwan UniversityQinzhouPeople’s Republic of China

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