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Electrochemical noise of Li-ion battery: measurement with load-interrupt technique

  • E. A. AstafevEmail author
Original Paper
  • 29 Downloads

Abstract

The electrochemical noise of a commercially produced Li-ion battery was measured during discharge by means of a constant value resistor using two approaches: continuous discharge and discharge with interruptions. Power spectral density and standard deviation calculation techniques were applied to analyse the electrochemical noise behaviour for different states of charge values. It was shown that electrochemical noise does not disappear immediately following load removal. Noise decreases in amplitude for several hours, reaching the thermal noise level afterwards. Unfortunately, it is not likely that the described electrochemical noise measurement and analysis method can be used for practical state-of-charge estimation of the batteries of investigated type due to the majority of changes in electrochemical noise behaviour taking place at the very end of the discharge process regardless of discharge technique. Nevertheless, the novel load-interrupt realisation of electrochemical noise measurement provided some new interesting insights into the electrochemical noise-generating processes in rechargeable batteries. It was shown that the electrochemical noise measurement technique can be used as a means of detecting over-discharge for Li-ion batteries. The same load-interrupted measurement result was also obtained in continuous discharge mode.

Keywords

Electrochemical noise Li-ion battery Power spectral density Over-discharge detection 

Notes

Funding information

This work was supported by the State Task of the Russian Federation (State Registration No. 01201361853).

References

  1. 1.
    Li Z, Huang J, Liaw BY, Zhang J (2017) On state-of-charge determination for lithium-ion batteries. J Power Sources 348:281–301CrossRefGoogle Scholar
  2. 2.
    Hu X, Cao D, Egardt B (2018) Condition monitoring in advanced battery management systems: moving horizon estimation using a reduced electrochemical model. IEEE ASME T Mech 23(1):167–178CrossRefGoogle Scholar
  3. 3.
    Huhman BM, Heinzel JM, Mili L, Love CT, Wetz DA (2017) Investigation into state-of-health impedance diagnostic for 26650 4P1S battery packs. J Electrochem Soc 164(1):A6401–A6411CrossRefGoogle Scholar
  4. 4.
    Hoshi Y, Narita Y, Honda K, Ohtaki T, Shitanda I, Itagaki M (2015) Optimisation of reference electrode position in a three-electrode cell for impedance measurements in lithium-ion rechargeable battery by finite element method. J Power Sources 288:168–175CrossRefGoogle Scholar
  5. 5.
    Abdel-Monem M, Trad K, Omar N, Hegazy O, Van den Bossche P, Van Mierlo J (2017) Influence analysis of static and dynamic fast-charging current profiles on ageing performance of commercial lithium-ion batteries. Energy 120:179–191CrossRefGoogle Scholar
  6. 6.
    Mingant R, Bernard J, Sauvant-Moynot V (2016) Novel state-of-health diagnostic method for Li-ion battery in service. Appl Energy 183:390–398CrossRefGoogle Scholar
  7. 7.
    Bertocci U, Huet F (1995) Noise analysis applied to electrochemical systems. Corrosion 51(2):131–144CrossRefGoogle Scholar
  8. 8.
    Cottis RA (2001) Interpretation of electrochemical noise data. Corrosion 57(3):265–285CrossRefGoogle Scholar
  9. 9.
    Singh PS, Lemay SG (2016) Stochastic processes in electrochemistry. Anal Chem 88(10):5017–5027CrossRefGoogle Scholar
  10. 10.
    Martinet S, Durand R, Ozil P, Leblanc P, Blanchard P (1999) Application of electrochemical noise analysis to the study of batteries: state-of-charge determination and overcharge detection. J Power Sources 83(1-2):93–99CrossRefGoogle Scholar
  11. 11.
    Martemianov S, Adiutantov V, Evdokimov YK, Madier L, Maillard F, Thomas A (2015) New methodology of electrochemical noise analysis and applications for commercial Li-ion batteries. J Solid State Electrochem 19(9):2803–2810CrossRefGoogle Scholar
  12. 12.
    Astafev EA, Ukshe AE, Dobrovolsky YA (2018) Measurement of electrochemical noise of a Li/MnO2 primary lithium battery. J Solid State Electrochem 22(11):3597–3606CrossRefGoogle Scholar
  13. 13.
    Astafev EA (2018) Electrochemical noise measurement of a Li/SOCl2 primary battery. J Solid State Electrochem 22(11):3569–3577CrossRefGoogle Scholar
  14. 14.
    Astafev EA, Ukshe AE, Gerasimova EV, Dobrovolsky YA, Manzhos RA (2018) Electrochemical noise of a hydrogen-air polymer electrolyte fuel cell operating at different loads. J Solid State Electrochem 22(6):1839–1849CrossRefGoogle Scholar
  15. 15.
    Astafev EA, Ukshe AE, Manzhos RA, Dobrovolsky YA, Lakeev SG, Timashev SF (2017) Flicker noise spectroscopy in the analysis of electrochemical noise of hydrogen-air PEM fuel cell during its degradation. Int J Electrochem Sci 12:1742–1754CrossRefGoogle Scholar
  16. 16.
    Grafov BM, Dobrovolskii YA, Klyuev AL, Ukshe AE, Davydov AD, Astaf’ev EA (2017) Median Chebyshev spectroscopy of electrochemical noise. J Solid State Electrochem 21(3):915–918CrossRefGoogle Scholar
  17. 17.
    Astafev EA, Ukshe AE, Dobrovolsky YA (2018) The model of electrochemical noise of a hydrogen-air fuel cell. J Electrochem Soc 165(9):F604–F612CrossRefGoogle Scholar
  18. 18.
    Astafev EA (2018) Frequency characteristics of hydrogen-air fuel cell electrochemical noise. Fuel Cells 18(6):755–762CrossRefGoogle Scholar
  19. 19.
    Astafev EA (2019) Wide frequency band electrochemical noise measurement and analysis of a Li/SOCl2 primary battery. J Solid State Electrochem 23(2):389–396CrossRefGoogle Scholar
  20. 20.
    Baert DHJ, Vervaet AAK (2003) Small bandwidth measurement of the noise voltage of batteries. J Power Sources 114(2):357–365CrossRefGoogle Scholar
  21. 21.
    Martemianov S, Maillard F, Thomas A, Lagonotte P, Madier L (2016) Noise diagnosis of commercial Li-ion batteries using high-order moments. Russ J Electrochem 52(12):1122–1130CrossRefGoogle Scholar
  22. 22.
    Kanevskii LS (2009) Special features of discharge characteristics of different types of lithium-thionyl chloride cells and the problem of their diagnostics. Russ J Electrochem 45(8):835–846CrossRefGoogle Scholar
  23. 23.
    Maizia R, Dib A, Thomas A, Martemianov S (2017) Proton exchange membrane fuel cell diagnosis by spectral characterisation of the electrochemical noise. J Power Sources 342:553–561CrossRefGoogle Scholar
  24. 24.
    Astafev EA (2019) Electrochemical noise measurement methodologies of chemical power sources. Instrum Sci Technol 47:233–247.  https://doi.org/10.1080/10739149.2018.1521423 Google Scholar
  25. 25.
    Astafev EA (2018) Software and instrumentation methods of resolution enhancement in electrochemical noise measurement. Russ J Electrochem 54(11):1031–1044CrossRefGoogle Scholar
  26. 26.
    Schindler S, Bauer M, Petzl M, Danzer MA (2016) Voltage relaxation and impedance spectroscopy as in-operando methods for the detection of lithium plating on graphitic anodes in commercial lithium-ion cells. J Power Sources 304:170–180CrossRefGoogle Scholar
  27. 27.
    Kindermann FM, Noel A, Erhard SV, Jossen A (2015) Long-term equalisation effects in Li-ion batteries due to local state of charge inhomogeneities and their impact on impedance measurements. Electrochim Acta 185:107–116CrossRefGoogle Scholar
  28. 28.
    Astafev EA (2019) Electrochemical noise of a Li-ion battery: measurement and spectral analysis. J Solid State Electrochem.  https://doi.org/10.1007/s10008-019-04209-5
  29. 29.
    Astafev EA (2019) The instrument for electrochemical noise measurement of chemical power sources. Rev Sci Instrum 90(2):025104.  https://doi.org/10.1063/1.5079613 CrossRefGoogle Scholar
  30. 30.
    Astafev EA, Ukshe AE (2019) Peculiarities of hardware for electrochemical noise measurement in chemical power sources. IEEE Instrum Meas:1–7.  https://doi.org/10.1109/TIM.2018.2889232
  31. 31.
    Smulko J, Lentka L (2019) Methods of trend removal in electrochemical noise data-overview. Measurement. 131:569–581CrossRefGoogle Scholar
  32. 32.
    Bertocci U, Huet F, Nogueira RP, Rousseau P (2002) Drift removal procedures in the analysis of electrochemical noise. Corrosion 58(4):337–347CrossRefGoogle Scholar
  33. 33.
    Xia D-H, Behnamian Y (2015) Electrochemical noise: a review of experimental setup, instrumentation and DC removal. Russ J Electrochem 51(7):593–601CrossRefGoogle Scholar
  34. 34.
    Astafev EA, Ukshe AE, Leonova LS, Manzhos RA, Dobrovolsky YA (2018) Detrending and other features of data processing in the measurements of electrochemical noise. Russ J Electrochem 54(12):1117–1125CrossRefGoogle Scholar
  35. 35.
    Nyquist H (1928) Thermal agitation of electric charge in conductors. Phys Rev 32(1):110–113CrossRefGoogle Scholar
  36. 36.
    He H, Liu Y, Liu Q, Li Z, Xu F, Dun C, Ren Y, Wang M, Xie J (2013) Failure investigation of LiFePO4 cells in over-discharge conditions. J Electrochem Soc 160(6):A793–A804CrossRefGoogle Scholar
  37. 37.
    Chao W, Chunbo Z, Jinlei S, Jianhu J (2017) Fault mechanism study on Li-ion battery at over-discharge and its diagnosis approach. Electrical Sys Transp 7(1):48–54CrossRefGoogle Scholar
  38. 38.
    Astafev EA (2018) Comparison of the method and hardware for electrochemical impedance with the method of electrochemical noise measurement and analysis. Russ J Electrochem 54(11):1022–1030CrossRefGoogle Scholar
  39. 39.
    Galeotti M, Cin L, Giammanco C, Cordiner S, Di Carlo A (2015) Performance analysis and SOH (state of health) evaluation of lithium polymer batteries through electrochemical impedance spectroscopy. Energy 89:678–686CrossRefGoogle Scholar
  40. 40.
    Astaf’ev EA (2018) Electrochemical noise measurement of polymer membrane fuel cell under load. Russ J Electrochem 54(6):554–560CrossRefGoogle Scholar
  41. 41.
    Costard J, Ender M, Weiss M, Ivers-Tiff E (2017) Three-electrode setups for lithium-ion batteries II. Experimental study of different reference electrode designs and their implications for half-cell impedance spectra. J Electrochem Soc 164(2):A80–A87CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Institute of Problems of Chemical PhysicsRASChernogolovkaRussia

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