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Improved cycling performances of binder-free macroporous silicon Li-ion negative electrodes using room temperature ionic liquid electrolyte

  • Erwann Luais
  • Fouad GhamoussEmail author
  • Joe Sakai
  • Thomas Defforge
  • Gaël Gautier
  • François Tran-Van
Original Paper
  • 63 Downloads

Abstract

The present article describes the innovative combination of freestanding macroporous silicon layers on copper foil collectors and room temperature ionic, liquid 1-propyl-1-methylpyrrolidinium bis(trifluosulfonyl)imide (Pyr13 FSI)-containing electrolyte (Pyr13 FSI mixed with 1 M LiTFSI) to produce highly stable negative electrodes for Li-ion batteries. A 20-μm-thick macroporous silicon layer was synthesized by anodization in hydrofluoric acid (HF)-based electrolyte followed by the deposition of a thick and mechanically stable copper layer acting as current collector. After peeling-off the parent substrate, the freestanding macroporous silicon layer was characterized as a negative electrode in a half-cell configuration. The electrode performances were determined under constant charge conditions (500, 750, and 1000 mA h g−1) and exhibited significantly higher stability for over 1800 charge and discharge cycles in 1 M LiTFSI dissolved in Pyr13 FSI.

Keywords

Electrochemical etching Freestanding macroporous silicon layers Negative electrode Lithium-ion batteries Room temperature ionic liquids 

Notes

Funding information

This study was supported by the Region Centre through the consecutive “BLaDES” and “μBaGS” projects.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Erwann Luais
    • 1
    • 2
  • Fouad Ghamouss
    • 2
    Email author
  • Joe Sakai
    • 1
  • Thomas Defforge
    • 1
  • Gaël Gautier
    • 1
  • François Tran-Van
    • 2
  1. 1.GREMAN UMR-CNRS 7347, INSA Centre Val de LoireUniversité de ToursToursFrance
  2. 2.Laboratoire de Physico-Chimie des Matériaux et des Electrolytes pour l’Energie (PCM2E)Université de ToursToursFrance

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