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Journal of Solid State Electrochemistry

, Volume 23, Issue 2, pp 529–541 | Cite as

Copper-deposited aluminum anode for aluminum-air battery

  • Rasiha Nefise MutluEmail author
  • Birgül Yazıcı
Original Paper
  • 64 Downloads

Abstract

For Al-air batteries, it is important to develop efficient and economical anodes. In this study, the effect of aluminum anodes treated with copper by chemical and electrochemical process to battery performance is investigated. The surface characterization of this electrode is performed with a scanning electron microscope. Electrochemical impedance spectroscopy and anodic polarization techniques are used. The hydrogen gas evolution and corrosion rate tests, the constant-voltage discharge tests, and the galvanostatic anodic dissolution tests are carried out. The anode utilizations are calculated. It is seen that the copper improves the anode efficiency by promoting the dissolution of aluminum according to battery reaction. However, it protects the aluminum from corrosion reaction by forming a barrier film without any restriction of battery reaction. It is understood from this work that the most efficient, economical, and practical method for copper deposition to electrode is the electrochemical deposition of copper. Furthermore, the 7075 alloy (Alloy/Cu) is more stable for both the electrochemical and chemical deposition process.

Keywords

Al-air battery Hydrogen gas evolution Copper Aluminum alloy Corrosion 

Notes

Acknowledgements

The authors are greatly thankful to Cukurova University Research fund. I also have the Prime Ministerial Scholarship that gives me financial support during my studies. I am also grateful for that.

Funding information

This study has been financially supported by Cukurova University research fund (Project no. FDK-2015-5386).

References

  1. 1.
    Wang D, Zhang D, Lee K, Gao L (2015) Performance of AA5052 alloy anode in alkaline ethylene glycol electrolyte with dicarboxylic acids additives for aluminium-air batteries. J Power Sources 297:464–471CrossRefGoogle Scholar
  2. 2.
    Fan L, Lu H, Leng J (2015) Performance of fine structured aluminum anodes in neutral and alkaline electrolytes for Al-air batteries. Electrochim Acta 165:22–28CrossRefGoogle Scholar
  3. 3.
    Chu F, Zuo C, Tian Z, Ma C, Zhao C, Wang Y, Dong W, Long J, Wen Z, Yuan X, Cao Y (2018) Solution combustion synthesis of mixed-phase Mn-based oxides nanoparticles and their electrocatalytic performances for Al-air batteries. J Alloys Compd 748:375–381CrossRefGoogle Scholar
  4. 4.
    Egan D, De León CP, Wood R, Jones R, Stokes K, Walsh F (2013) Developments in electrode materials and electrolytes for aluminium–air batteries. J Power Sources 236:293–310CrossRefGoogle Scholar
  5. 5.
    Holland A, McKerracher RD, Cruden A, Wills RGA (2018) An aluminium battery operating with an aqueous electrolyte. J Appl Electrochem 48:243–250CrossRefGoogle Scholar
  6. 6.
    Wang L, Wang W, Yang G, Liu D, Xuan J, Wang H, Leung MKH, Liu F (2013) A hybrid aluminum/hydrogen/air cell system. Int J Hydrog Energy 38(34):14801–14809CrossRefGoogle Scholar
  7. 7.
    Wang D, Li H, Liu J, Zhang D, Gao L, Tong L (2015) Evaluation of AA5052 alloy anode in alkaline electrolyte with organic rare-earth complex additives for aluminium-air batteries. J Power Sources 293:484–491CrossRefGoogle Scholar
  8. 8.
    Zhang X, Yang SH, Knickle H (2004) Novel operation and control of an electric vehicle aluminum/air battery system. J Power Sources 128(2):331–342CrossRefGoogle Scholar
  9. 9.
    Ilyukhina AV, Kleymenov BV, Zhuk AZ (2017) Development and study of aluminum-air electrochemical generator and its main components. J Power Sources 342:741–749CrossRefGoogle Scholar
  10. 10.
    Yang S, Knickle H (2002) Design and analysis of aluminum/air battery system for electric vehicles. J Power Sources 112(1):162–173CrossRefGoogle Scholar
  11. 11.
    Cho Y-J, Park I-J, Lee H-J, Kim J-G (2015) Aluminum anode for aluminum–air battery – part I: influence of aluminum purity. J Power Sources 277:370–378CrossRefGoogle Scholar
  12. 12.
    Fan L, Lu H (2015) The effect of grain size on aluminum anodes for Al–air batteries in alkaline electrolytes. J Power Sources 284:409–415CrossRefGoogle Scholar
  13. 13.
    Jingling M, Jiuba W, Hongxi Z, Quanan L (2015) Electrochemical performances of Al–0.5Mg–0.1Sn–0.02In alloy in different solutions for Al–air battery. J Power Sources 293:592–598CrossRefGoogle Scholar
  14. 14.
    Nestoridi M, Pletcher D, Wood RJK, Wang S, Jones RL, Stokes KR, Wilcock I (2008) The study of aluminium anodes for high power density Al/air batteries with brine electrolytes. J Power Sources 178(1):445–455CrossRefGoogle Scholar
  15. 15.
    Bai L, Conway B (1992) Role of indium in promoting anodic dissolution of Al-In alloys in non-aqueous electrolyte. J Appl Electrochem 22(2):131–139CrossRefGoogle Scholar
  16. 16.
    El Abedin SZ, Saleh A (2004) Characterization of some aluminium alloys for application as anodes in alkaline batteries. J Appl Electrochem 34:331–335CrossRefGoogle Scholar
  17. 17.
    Smoljko I, Gudić S, Kuzmanić N, Kliškić M (2012) Electrochemical properties of aluminium anodes for Al/air batteries with aqueous sodium chloride electrolyte. J Appl Electrochem 42(11):969–977CrossRefGoogle Scholar
  18. 18.
    Mutlu RN, Ateş S, Yazıcı B (2017) Al-6013-T6 and Al-7075-T7351 alloy anodes for aluminium-air battery. Int J Hydrog Energy 42(36):23315–23325CrossRefGoogle Scholar
  19. 19.
    Pino M, Cuadrado C, Chacón J, Rodríguez P, Fatás E, Ocón P (2014) The electrochemical characteristics of commercial aluminium alloy electrodes for Al/air batteries. J Appl Electrochem 44(12):1371–1380CrossRefGoogle Scholar
  20. 20.
    Ma J, Wen J, Gao J, Li Q (2014) Performance of Al−1Mg−1Zn−0.1Ga−0.1Sn as anode for Al-air battery. Electrochim Acta 129:69–75CrossRefGoogle Scholar
  21. 21.
    Chaubey N, Yadav DK, Singh VK, Quraishi MA (2015) A comparative study of leaves extracts for corrosion inhibition effect on aluminium alloy in alkaline medium. Ain Shams Eng J 8:673–682CrossRefGoogle Scholar
  22. 22.
    Fan L, Lu H, Leng J, Sun Z, Chen C (2015) The effect of crystal orientation on the aluminum anodes of the aluminum–air batteries in alkaline electrolytes. J Power Sources 299:66–69CrossRefGoogle Scholar
  23. 23.
    Pino M, Chacón J, Fatás E, Ocón P (2015) Performance of commercial aluminium alloys as anodes in gelled electrolyte aluminium-air batteries. J Power Sources 299:195–201CrossRefGoogle Scholar
  24. 24.
    Tang Y, Lu L, Roesky HW, Wang L, Huang B (2004) The effect of zinc on the aluminum anode of the aluminum–air battery. J Power Sources 138(1-2):313–318CrossRefGoogle Scholar
  25. 25.
    Liu J, Wang D, Zhang D, Gao L, Lin T (2016) Synergistic effects of carboxymethyl cellulose and ZnO as alkaline electrolyte additives for aluminium anodes with a view towards Al-air batteries. J Power Sources 335:1–11CrossRefGoogle Scholar
  26. 26.
    Park I-J, Choi S-R, Kim J-G (2017) Aluminum anode for aluminum-air battery – part II: influence of in addition on the electrochemical characteristics of Al-Zn alloy in alkaline solution. J Power Sources 357:47–55CrossRefGoogle Scholar
  27. 27.
    Macdonald DD, English C (1990) Development of anodes for aluminium/air batteries—solution phase inhibition of corrosion. J Appl Electrochem 20(3):405–417CrossRefGoogle Scholar
  28. 28.
    Paramasivam M, Iyer SV (2001) Influence of alloying additives on corrosion and hydrogen permeation through commercial aluminium in alkaline solution. J Appl Electrochem 31(1):115–119CrossRefGoogle Scholar
  29. 29.
    Paramasivam M, Jayachandran M, Iyer SV (2003) Influence of alloying additives on the performance of commercial grade aluminium as galvanic anode in alkaline zincate solution for use in primary alkaline batteries. J Appl Electrochem 33(3/4):303–309CrossRefGoogle Scholar
  30. 30.
    Nath P, Sahu DK, Mallik A (2016) Physicochemical and corrosion properties of sono-electrodeposited Cu-Ni thin films. Surf Coat Technol 307:772–780CrossRefGoogle Scholar
  31. 31.
    Alper M, Kockar H, Safak M, Baykul MC (2008) Comparison of Ni–cu alloy films electrodeposited at low and high pH levels. J Alloys Compd 453(1-2):15–19CrossRefGoogle Scholar
  32. 32.
    Sharma T, Shaver P, Brown DA, Brüning R, Peldzinski V, Ferro A (2016) Time evolution of stress and microstructure in electroplated copper films. Electrochim Acta 196:479–486CrossRefGoogle Scholar
  33. 33.
    Wang Y-H, He J-B (2012) Corrosion inhibition of copper by sodium phytate in NaOH solution: cyclic voltabsorptometry for in situ monitoring of soluble corrosion products. Electrochim Acta 66:45–51CrossRefGoogle Scholar
  34. 34.
    Zhou X, Thompson GE, Skeldon P, Shimizu K, Habazaki H, Wood GC (2005) The valence state of copper in anodic films formed on Al–1at.% Cu alloy. Corros Sci 47(5):1299–1306CrossRefGoogle Scholar
  35. 35.
    Hashimoto T, Zhou X, Skeldon P, Thompson GE (2015) Structure of the copper–enriched layer introduced by anodic oxidation of copper-containing aluminium alloy. Electrochim Acta 179:394–401CrossRefGoogle Scholar
  36. 36.
    Cao C, Zhang D, Wang X, Ma Q, Zhuang L, Zhang J (2016) Effects of Cu addition on the precipitation hardening response and intergranular corrosion of Al-5.2Mg-2.0Zn (wt.%) alloy. Mater Charact 122:177–182CrossRefGoogle Scholar
  37. 37.
    Mert BD, Solmaz R, Kardaş G, Yazıcı B (2011) Copper/polypyrrole multilayer coating for 7075 aluminum alloy protection. Prog Org Coat 72(4):748–754CrossRefGoogle Scholar
  38. 38.
    Mukherjee S, Ghosh AK (2011) Friction stir processing of direct metal deposited copper–nickel. Mater Sci Eng A 528(9):3289–3294CrossRefGoogle Scholar
  39. 39.
    Strehblow HH, Doherty C (1978) Examination of aluminum copper films during anodic oxidation I. Corrosion Studies. J Electrochem Soc 125(1):30–33CrossRefGoogle Scholar
  40. 40.
    Arthanari S, Jang JC, Shin KS (2018) Corrosion studies of high pressure die-cast Al-Si-Ni and Al-Si-Ni-Cu alloys. J Alloys Compd 749:146–154CrossRefGoogle Scholar
  41. 41.
    Li Y-J, Luo X-T, Rashid H, Li C-J (2018) A new approach to prepare fully dense Cu with high conductivities and anti-corrosion performance by cold spray. J Alloys Compd 740:406–413CrossRefGoogle Scholar
  42. 42.
    Alfantazi AM, Ahmed TM, Tromans D (2009) Corrosion behavior of copper alloys in chloride media. Mater Des 30(7):2425–2430CrossRefGoogle Scholar
  43. 43.
    Lin X, Ni Y, Kokot S (2014) Electrochemical mechanism of eugenol at a cu doped gold nanoparticles modified glassy carbon electrode and its analytical application in food samples. Electrochim Acta 133:484–491CrossRefGoogle Scholar
  44. 44.
    Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutionsGoogle Scholar
  45. 45.
    Beverskog B, Puigdomenech I (1995) Revised Pourbaix diagrams for copper at 5-150 C. SKiGoogle Scholar
  46. 46.
    Hunt L (1934) The mechanism of electrodeposition. Trans Electrochem Soc 65(1):413–427CrossRefGoogle Scholar
  47. 47.
    Xiong H, Yu K, Yin X, Dai Y, Yan Y, Zhu H (2017) Effects of microstructure on the electrochemical discharge behavior of Mg-6wt%Al-1wt%Sn alloy as anode for Mg-air primary battery. J Alloys Compd 708:652–661CrossRefGoogle Scholar
  48. 48.
    Wang N, Wang R, Peng C, Peng B, Feng Y, Hu C (2014) Discharge behaviour of Mg-Al-Pb and Mg-Al-Pb-in alloys as anodes for Mg-air battery. Electrochim Acta 149:193–205CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Science and Letters Faculty, Chemistry DepartmentÇukurova UniversityAdanaTurkey

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