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Journal of Solid State Electrochemistry

, Volume 23, Issue 2, pp 503–512 | Cite as

One-pot synthesis of copper nanoparticles on glass: applications for non-enzymatic glucose detection and catalytic reduction of 4-nitrophenol

  • Hemraj Mahipati Yadav
  • Jae-Joon LeeEmail author
Original Paper

Abstract

Thin film of metallic Cu nanoparticles was synthesized by a one-pot chemical reduction method at ambient temperature. Cu(II) acetate monohydrate and hydrazine monohydrate were used as precursor and reducing agent without additional surfactants to form uniform layer of Cu nanoparticle layer on a glass substrate (Cu/G). The XRD and the effectiveness of the electrocatalytic and catalytic properties of the Cu/G have been applied for an amperometric detection of glucose and for the chemical reduction of 4-nitrophenol. The former exhibited the detection limit as low as 2.47 μM with a linear range of 0.01–0.2 mM, while the latter showed the efficient catalytic activity with a high rate constant of 0.503/min. The current method suggested in this work might be useful for the fabrication of glass-based Cu nanoparticles electrodes for industrial and biomedical applications.

Keywords

Copper nanoparticles Electrochemical sensor Hydrogenation reaction Glucose 4-Nitrophenol 

Notes

Funding information

This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (NRF-2015M1A2A2054996, NRF-2016R1A2B2012061). It was also supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF), funded by the Ministry of Science, ICT & Future Planning (NRF-2016M1A2A2940912). This work was also supported by the Dongguk University Research Fund of 2016.

References

  1. 1.
    Maduraiveeran G, Jin W (2017) Nanomaterials based electrochemical sensor and biosensor platforms for environmental applications. Trends Environ Anal Chem 13:10–23CrossRefGoogle Scholar
  2. 2.
    Dong C, Cai H, Zhang X, Cao C (2014) Synthesis and characterization of monodisperse copper nanoparticles using gum acacia. Physica E 57:12–20Google Scholar
  3. 3.
    Chen S, Yuan R, Chai Y, Hu F (2013) Electrochemical sensing of hydrogen peroxide using metal nanoparticles: a review. Microchim Acta 180(1-2):15–32CrossRefGoogle Scholar
  4. 4.
    Wu S-H, Chen D-H (2004) Synthesis of high-concentration Cu nanoparticles in aqueous CTAB solutions. J Colloid Interface Sci 273(1):165–169CrossRefGoogle Scholar
  5. 5.
    Dhas NA, Raj CP, Gedanken A (1998) Synthesis, characterization, and properties of metallic copper nanoparticles. Chem Mater 10(5):1446–1452CrossRefGoogle Scholar
  6. 6.
    Wang A-J, Feng J-J, Li Z-H, Liao QC, Wang ZZ, Chen JR (2012) Solvothermal synthesis of Cu/Cu2O hollow microspheres for non-enzymatic amperometric glucose sensing. CrystEngComm 14(4):1289–1295CrossRefGoogle Scholar
  7. 7.
    Khodashenas B, Ghorbani HR (2014) Synthesis of copper nanoparticles: an overview of the various methods. Korean J Chem Eng 31(7):1105–1109CrossRefGoogle Scholar
  8. 8.
    Zhou D-L, Feng J-J, Cai L-Y, Fang QX, Chen JR, Wang AJ (2014) Facile synthesis of monodisperse porous Cu2O nanospheres on reduced graphene oxide for non-enzymatic amperometric glucose sensing. Electrochim Acta 115:103–108CrossRefGoogle Scholar
  9. 9.
    Mei L-P, Song P, Feng J-J, Shen JH, Wang W, Wang AJ, Weng X (2015) Nonenzymatic amperometric sensing of glucose using a glassy carbon electrode modified with a nanocomposite consisting of reduced graphene oxide decorated with Cu2O nanoclusters. Microchim Acta 182(9-10):1701–1708CrossRefGoogle Scholar
  10. 10.
    Yang J, Yang S, Okamoto T, Bessho T, Satake S, Ichino R, Okido M (2006) Synthesis of copper monolayer and particles at aqueous–organic interface. Surf Sci 600(24):L318–L320CrossRefGoogle Scholar
  11. 11.
    Qiu R, Cha HG, Noh HB, Shim YB, Zhang XL, Qiao R, Zhang D, Kim YI, Pal U, Kang YS (2009) Preparation of dendritic copper nanostructures and their characterization for electroreduction. J Phys Chem C 113(36):15891–15896CrossRefGoogle Scholar
  12. 12.
    Li J, Li J, Feng H, Zhang Y, Jiang J, Feng Y, Chen M, Qian D (2015) A facile one-step in situ synthesis of copper nanostructures/graphene oxide as an efficient electrocatalyst for 2-naphthol sensing application. Electrochim Acta 153:352–360CrossRefGoogle Scholar
  13. 13.
    Alzahrani E, Ahmed RA (2016) Synthesis of copper nanoparticles with various sizes and shapes: application as a superior non-enzymatic sensor and antibacterial agent. Int J Electrochem Sci 11:4712–4723CrossRefGoogle Scholar
  14. 14.
    Li Z, Chen Y, Xin Y, Zhang Z (2015) Sensitive electrochemical nonenzymatic glucose sensing based on anodized CuO nanowires on three-dimensional porous copper foam. Sci Rep 5(1):16115CrossRefGoogle Scholar
  15. 15.
    Wang L, Lu X, Wen C, Xie Y, Miao L, Chen S, Li H, Li P, Song Y (2015) One-step synthesis of Pt–NiO nanoplate array/reduced graphene oxide nanocomposites for nonenzymatic glucose sensing. J Mater Chem A 3(2):608–616CrossRefGoogle Scholar
  16. 16.
    Devaraj M, Saravanan R, Deivasigamani R, Gupta VK, Gracia F, Jayadevan S (2016) Fabrication of novel shape Cu and Cu/Cu2O nanoparticles modified electrode for the determination of dopamine and paracetamol. J Mol Liq 221:930–941CrossRefGoogle Scholar
  17. 17.
    Li H, Guo C-Y, Xu C-L (2015) A highly sensitive non-enzymatic glucose sensor based on bimetallic Cu–Ag superstructures. Biosens Bioelectron 63:339–346CrossRefGoogle Scholar
  18. 18.
    Wang Q, Wang Q, Li M, Szunerits S, Boukherroub R (2015) Preparation of reduced graphene oxide/Cu nanoparticle composites through electrophoretic deposition: application for nonenzymatic glucose sensing. RSC Adv 5(21):15861–15869CrossRefGoogle Scholar
  19. 19.
    Mani V, Devasenathipathy R, Chen S-M, Wang SF, Devi P, Tai Y (2015) Electrodeposition of copper nanoparticles using pectin scaffold at graphene nanosheets for electrochemical sensing of glucose and hydrogen peroxide. Electrochim Acta 176:804–810CrossRefGoogle Scholar
  20. 20.
    Xu Q, Zhao Y, Xu JZ, Zhu JJ (2006) Preparation of functionalized copper nanoparticles and fabrication of a glucose sensor. Sensors Actuators B Chem 114(1):379–386CrossRefGoogle Scholar
  21. 21.
    Hassan HH, Badr IHA, Abdel-Fatah HTM et al (2015) Low cost chemical oxygen demand sensor based on electrodeposited nano-copper film. Arab J Chem 11:171–180CrossRefGoogle Scholar
  22. 22.
    Lu LM, Zhang L, Qu FL, Lu HX, Zhang XB, Wu ZS, Huan SY, Wang QA, Shen GL, Yu RQ (2009) A nano-Ni based ultrasensitive nonenzymatic electrochemical sensor for glucose: enhancing sensitivity through a nanowire array strategy. Biosens Bioelectron 25(1):218–223CrossRefGoogle Scholar
  23. 23.
    Jiang D, Liu Q, Wang K, Qian J, Dong X, Yang Z, du X, Qiu B (2014) Enhanced non-enzymatic glucose sensing based on copper nanoparticles decorated nitrogen-doped graphene. Biosens Bioelectron 54:273–278CrossRefGoogle Scholar
  24. 24.
    Shabnam L, Faisal SN, Roy AK, Haque E, Minett AI, Gomes VG (2017) Doped graphene/Cu nanocomposite: a high sensitivity non-enzymatic glucose sensor for food. Food Chem 221:751–759CrossRefGoogle Scholar
  25. 25.
    Ensafi AA, Abarghoui MM, Rezaei B (2014) Electrochemical determination of hydrogen peroxide using copper/porous silicon based non-enzymatic sensor. Sensors Actuators B Chem 196:398–405CrossRefGoogle Scholar
  26. 26.
    Dayakar T, Rao KV, Bikshalu K, Rajendar V, Park SH (2017) Novel synthesis and characterization of pristine cu nanoparticles for the non-enzymatic glucose biosensor. J Mater Sci Mater Med 28(7):109CrossRefGoogle Scholar
  27. 27.
    Yang T, Xu J, Lu L, Zhu X, Gao Y, Xing H, Yu Y, Ding W, Liu Z (2016) Copper nanoparticle/graphene oxide/single wall carbon nanotube hybrid materials as electrochemical sensing platform for nonenzymatic glucose detection. J Electroanal Chem 761:118–124CrossRefGoogle Scholar
  28. 28.
    Wu C-H, Onno E, Lin C-Y (2017) CuO nanoparticles decorated nano-dendrite-structured CuBi 2 O 4 for highly sensitive and selective electrochemical detection of glucose. Electrochim Acta 229:129–140CrossRefGoogle Scholar
  29. 29.
    Meng Z, Sheng Q, Zheng J (2012) A sensitive non-enzymatic glucose sensor in alkaline media based on Cu/MnO2-modified glassy carbon electrode. J Iran Chem Soc 9(6):1007–1014CrossRefGoogle Scholar
  30. 30.
    Zhang J, Xiao X, He Q, Huang L, Li S, Wang F (2014) A nonenzymatic glucose sensor based on a copper nanoparticle–zinc oxide nanorod array. Anal Lett 47(7):1147–1161CrossRefGoogle Scholar
  31. 31.
    Liu L, Chen Y, Lv H, Wang G, Hu X, Wang C (2015) Construction of a non-enzymatic glucose sensor based on copper nanoparticles/poly(o-phenylenediamine) nanocomposites. J Solid State Electrochem 19(3):731–738CrossRefGoogle Scholar
  32. 32.
    Liu S, Ma Y, Zhang R, Luo X (2016) Three-dimensional nanoporous conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) decorated with copper nanoparticles: electrochemical preparation and enhanced nonenzymatic glucose sensing. ChemElectroChem 3(11):1799–1804CrossRefGoogle Scholar
  33. 33.
    Guo C, Wang L, Li M (2014) Functionalization of carbon nanotubes with copper for nonenzymatic electrochemical detection of glucose. Nanosci Nanotechnol Lett 6(6):481–487CrossRefGoogle Scholar
  34. 34.
    Luo J, Zhang H, Jiang S, Jiang J, Liu X (2012) Facile one-step electrochemical fabrication of a non-enzymatic glucose-selective glassy carbon electrode modified with copper nanoparticles and graphene. Microchim Acta 177(3-4):485–490CrossRefGoogle Scholar
  35. 35.
    Luo J, Jiang S, Zhang H, Jiang J, Liu X (2012) A novel non-enzymatic glucose sensor based on Cu nanoparticle modified graphene sheets electrode. Anal Chim Acta 709:47–53CrossRefGoogle Scholar
  36. 36.
    Zhao Y, He Z, Yan Z et al (2013) Copper@carbon coaxial nanowires synthesized by hydrothermal carbonization process from electroplating wastewater and their use as an enzyme-free glucose sensor. Analyst 138(2):559–568CrossRefGoogle Scholar
  37. 37.
    Lu XP, Ye YJ, Xie YZ, Song Y, Chen S, Li P, Chen L, Wang L (2014) Copper coralloid granule/polyaniline/reduced graphene oxide nanocomposites for nonenzymatic glucose detection. Anal Methods 6(13):4643–4651CrossRefGoogle Scholar
  38. 38.
    He Y, Wei G, Lin J, Sun M, Li Z (2017) Cu and Ni nanoparticles deposited on ITO electrode for nonenzymatic electrochemical carbohydrates sensor applications. Electroanalysis 29(4):965–974CrossRefGoogle Scholar
  39. 39.
    Park H, Reddy DA, Kim Y, Lee S, Ma R, Lim M, Kim TK (2017) Hydrogenation of 4-nitrophenol to 4-aminophenol at room temperature: boosting palladium nanocrystals efficiency by coupling with copper via liquid phase pulsed laser ablation. Appl Surf Sci 401:314–322CrossRefGoogle Scholar
  40. 40.
    Wróbel K, Wróbel K, Madai Colunga Urbina E, Muñoz Romero J (2000) The determination of 3-nitrophenol and some other aromatic impurities in 4-nitrophenol by reversed phase HPLC with peak suppression diode array detection. J Pharm Biomed Anal 22(2):295–300CrossRefGoogle Scholar
  41. 41.
    Narayanan KB, Sakthivel N (2011) Heterogeneous catalytic reduction of anthropogenic pollutant, 4-nitrophenol by silver-bionanocomposite using Cylindrocladium floridanum. Bioresour Technol 102(22):10737–10740CrossRefGoogle Scholar
  42. 42.
    Dhokale RK, Yadav HM, Achary SN, Delekar SD (2014) Anatase supported nickel nanoparticles for catalytic hydrogenation of 4-nitrophenol. Appl Surf Sci 303:168–174CrossRefGoogle Scholar
  43. 43.
    Deshmukh SP, Dhokale RK, Yadav HM, Achary SN, Delekar SD (2013) Titania-supported silver nanoparticles: an efficient and reusable catalyst for reduction of 4-nitrophenol. Appl Surf Sci 273:676–683CrossRefGoogle Scholar
  44. 44.
    Sasmal AK, Dutta S, Pal T (2016) A ternary Cu2O–Cu–CuO nanocomposite: a catalyst with intriguing activity. Dalton Trans 45(7):3139–3150CrossRefGoogle Scholar
  45. 45.
    Bhattacharjee A, Ahmaruzzaman M (2016) CuO nanostructures: facile synthesis and applications for enhanced photodegradation of organic compounds and reduction of p-nitrophenol from aqueous phase. RSC Adv 6(47):41348–41363CrossRefGoogle Scholar
  46. 46.
    Krishna R, Fernandes DM, Ventura J, Freire C (2016) Novel synthesis of highly catalytic active Cu@Ni/RGO nanocomposite for efficient hydrogenation of 4-nitrophenol organic pollutant. Int J Hydrog Energy 41(27):11608–11615CrossRefGoogle Scholar
  47. 47.
    Sun Y, Xu L, Yin Z, Song X (2013) Synthesis of copper submicro/nanoplates with high stability and their recyclable superior catalytic activity towards 4-nitrophenol reduction. J Mater Chem A 1(39):12361CrossRefGoogle Scholar
  48. 48.
    Zhang P, Sui Y, Xiao G, Wang Y, Wang C, Liu B, Zou G, Zou B (2013) Facile fabrication of faceted copper nanocrystals with high catalytic activity for p-nitrophenol reduction. J Mater Chem A 1(5):1632–1638CrossRefGoogle Scholar
  49. 49.
    Bendi R, Imae T (2013) Renewable catalyst with Cu nanoparticles embedded into cellulose nano-fiber film. RSC Adv 3(37):16279CrossRefGoogle Scholar
  50. 50.
    Ullah I, Khan K, Sohail M, Ullah K, Ullah A, Shaheen S (2017) Synthesis, structural characterization and catalytic application of citrate-stabilized monometallic and bimetallic palladium@copper nanoparticles in microbial anti-activities. Int J Nanomedicine 12:8735–8747CrossRefGoogle Scholar
  51. 51.
    Geng Y, Liu M, Ma H, Hao J, Liu HG (2013) Catalytic polymer/copper composite thin films formed at the liquid/liquid interface through self-assembly and hydrolysis process. Colloids Surf A Physicochem Eng Asp 431:161–170CrossRefGoogle Scholar
  52. 52.
    Wu W, Lei M, Yang S, Zhou L, Liu L, Xiao X, Jiang C, Roy VAL (2015) A one-pot route to the synthesis of alloyed Cu/Ag bimetallic nanoparticles with different mass ratios for catalytic reduction of 4-nitrophenol. J Mater Chem A 3(7):3450–3455CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Research Center for Photoenergy Harvesting & Conversion Technology (phct), Department of Energy and Materials EngineeringDongguk UniversitySeoulSouth Korea

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