Journal of Solid State Electrochemistry

, Volume 23, Issue 1, pp 1–7 | Cite as

Design of porous Co3O4 nanosheets via one-step synthesis as high-performance anode materials for lithium-ion batteries

  • Shihang Guo
  • Yi Feng
  • Weiqiang Ding
  • Xiaodan LiEmail author
  • Lvye Yang
  • Jianfeng YaoEmail author
Original Paper


The morphology of Co-based zeolitic imidazolate framework is affected by the molar ratio of 2-methylimidazole and Co2+ used during the synthesis. In this study, we found that by further controlling the molar ratio of 2-methylimidazole and Co2+, hexagonal Co(OH)2 nanosheets can by formed. By calcination of such Co(OH)2 nanosheets, the original two-dimensional morphology was maintained and hierarchical pores were formed with 2-methylimidazole as the porogen. Such porous Co3O4 nanosheets exhibited good electrochemical performance and delivered a high specific capacity of 850 mAh g−1 at current density of 300 mA g−1 after 100 cycles when used as anode of lithium-ion batteries.

Graphical Abstract

Porous Co3O4 nanosheets as high-performance anode materials were prepared from hexagonal Co(OH)2 nanosheets


Porous Co3O4 Nanosheets One-step synthesis Li-ion battery 


Funding information

This study is financially supported by Natural Science Key Project of the Jiangsu Higher Education Institutions (15KJA220001), Jiangsu Province Six Talent Peaks Project (2016-XCL-043), the Youth Fund of Natural Science Foundation of Jiangsu Province (BK20170919), the National Science Foundation for Young Scientists of China (21808112), and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).


  1. 1.
    Armand M, Tarascon JM (2008) Building better batteries. Nature 451:652–657CrossRefGoogle Scholar
  2. 2.
    Kang B, Ceder G (2009) Battery materials for ultrafast charging and discharging. Nature 458:190–193CrossRefGoogle Scholar
  3. 3.
    Huang Q, Yan M, Jiang Z (2008) Thermal study of organic electrolytes with fully charged cathodic materials of lithium-ion batteries. J Solid State Electrochem 12:671–678CrossRefGoogle Scholar
  4. 4.
    Zhu J, Bai L, Sun Y, Zhang X, Li Q, Cao B, Yan W, Xie Y (2013) Topochemical transformation route to atomically thick Co3O4 nanosheets realizing enhanced lithium storage performance. Nanoscale 5:5241–5246CrossRefGoogle Scholar
  5. 5.
    Wang J, Yang N, Tang H, Dong Z, Jin Q, Yang M, Kisailus D, Zhao H, Tang Z, Wang D (2013) Accurate control of multishelled Co3O4 hollow microspheres as high-performance anode materials in lithium-ion batteries. Angew Chem Int Edit 52:6417–6420CrossRefGoogle Scholar
  6. 6.
    Wang Y, Zhang HJ, Wei J, Wong CC, Lin J, Borgna A (2011) Crystal-match guided formation of single-crystal tricobalt tetraoxygen nanomesh as superior anode for electrochemical energy storage. Energy Environ Sci 4:1845–1854CrossRefGoogle Scholar
  7. 7.
    Xiao K, Zhang L, Tang Q, Fan B, Hu A, Zhang S, Deng W, Chen X (2018) Facile synthesis of single-crystalline Co3O4 cubes as high-performance anode for lithium-ion batteries. J Solid State Electrochem 22:2321–2328CrossRefGoogle Scholar
  8. 8.
    Hu A, Cao W, Liu D, Tang Q, Deng W, Chen X (2018) Saqima-like Co3O4/CNTs secondary microstructures with ultrahigh initial coulombic efficiency as an anode for lithium ion batteries. J Solid State Electrochem 22:417–427CrossRefGoogle Scholar
  9. 9.
    Qiu K, Yan H, Zhang D, Lu Y, Cheng J, Lu M, Wang C, Zhang Y, Liu X, Luo Y (2015) Hierarchical 3D Co3O4@MnO2 core/shell nanoconch arrays on Ni foam for enhanced electrochemical performance. J Solid State Electrochem 19:391–401CrossRefGoogle Scholar
  10. 10.
    Choi W-S, Hwang S, Chang W, Shin H-C (2016) Degradation of Co3O4 anode in rechargeable lithium-ion battery: a semi-empirical approach to the effect of conducting material content. J Solid State Electrochem 20:345–352CrossRefGoogle Scholar
  11. 11.
    Han Y, Zhao M, Dong L, Feng J, Wang Y, Li D, Li X (2015) MOF-derived porous hollow Co3O4 parallelepipeds for building high-performance Li-ion batteries. J Mater Chem A 3:22542–22546CrossRefGoogle Scholar
  12. 12.
    Baji DS, Nair SV, Rai AK (2017) Highly porous disk-like shape of Co3O4 as an anode material for lithium ion batteries. J Solid State Electrochem 21:2869–2875CrossRefGoogle Scholar
  13. 13.
    Zhang Q, Wang Y, Seh ZW, Fu Z, Zhang R, Cui Y (2015) Understanding the anchoring effect of two-dimensional layered materials for lithium-sulfur batteries. Nano Lett 15:3780–3786CrossRefGoogle Scholar
  14. 14.
    Guo Y, Xu K, Wu C, Zhao J, Xie Y (2015) Surface chemical-modification for engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials. Chem Soc Rev 44:637–646CrossRefGoogle Scholar
  15. 15.
    Wu C, Lu X, Peng L, Xu K, Peng X, Huang J, Yu G, Xie Y (2013) Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors. Nat Commun 4:3431Google Scholar
  16. 16.
    Cheng FY, Liang J, Tao ZL, Chen J (2011) Functional materials for rechargeable batteries. Adv Mater 23:1695–1715CrossRefGoogle Scholar
  17. 17.
    Wang YG, Li HQ, He P, Hosono E, Zhou HS (2010) Nano active materials for lithium-ion batteries. Nanoscale 2:1294–1305CrossRefGoogle Scholar
  18. 18.
    Zhan F, Geng B, Guo Y (2009) Porous Co3O4 nanosheets with extraordinarily high discharge capacity for lithium batteries. Chem Eur J 15:6169–6174CrossRefGoogle Scholar
  19. 19.
    Chen D, Peng L, Yuan Y, Zhu Y, Fang Z, Yan C, Chen G, Shahbazian-Yassar R, Lu J, Amine K, Yu G (2017) Two-dimensional holey Co3O4 nanosheets for high-rate alkali-ion batteries: from rational synthesis to in situ probing. Nano Lett 17:3907–3913CrossRefGoogle Scholar
  20. 20.
    Zhao W, Zhou X, Kim IJ, Kim S (2017) Self-assembled Co3O4 hexagonal plates by solvent engineering and their dramatically enhanced electrochemical performance. Nanoscale 9:940–946CrossRefGoogle Scholar
  21. 21.
    Liang CC, Cheng DF, Ding SJ, Zhao PF, Zhao MS, Song XP, Wang F (2014) The structure dependent electrochemical performance of porous Co3O4 nanoplates as anode materials for lithium-ion batteries. J Power Sources 251:351–356CrossRefGoogle Scholar
  22. 22.
    Zhang JC, Zhang TC, Yu DB, Xiao KS, Hong Y (2015) Transition from ZIF-L-Co to ZIF-67: a new insight into the structural evolution of zeolitic imidazolate frameworks (ZIFs) in aqueous systems. Crystengcomm 17:8212–8215CrossRefGoogle Scholar
  23. 23.
    Chen R, Yao J, Gu Q, Smeets S, Baerlocher C, Gu H, Zhu D, Morris W, Yaghi OM, Wang H (2013) A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption. Chem Commun 49:9500–9502CrossRefGoogle Scholar
  24. 24.
    Fang G, Zhou J, Cai Y, Liu S, Tan X, Pan A, Liang S (2017) Metal-organic framework-templated two-dimensional hybrid bimetallic metal oxides with enhanced lithium/sodium storage capability. J Mater Chem A 5:13983–13993CrossRefGoogle Scholar
  25. 25.
    Kraytsberg A, Ein-Eli Y (2012) Higher, stronger, better ... a review of 5 Volt cathode materials for advanced lithium-ion batteries. Adv Energy Mater 2:922–939CrossRefGoogle Scholar
  26. 26.
    Xiao X, Liu X, Zhao H, Chen D, Liu F, Xiang J, Hu Z, Li Y (2012) Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Adv Mater 24:5762–5766CrossRefGoogle Scholar
  27. 27.
    Jin Y, Wang L, Shang Y, Gao J, Li J, He X (2015) Facile synthesis of monodisperse Co3O4 mesoporous microdisks as an anode material for lithium ion batteries. Electrochim Acta 151:109–117CrossRefGoogle Scholar
  28. 28.
    Du H, Yuan C, Huang K, Wang W, Zhang K, Geng B (2017) A novel gelatin-guided mesoporous bowknot-like Co3O4 anode material for high-performance lithium-ion batteries. J Mater Chem A 5:5342–5350CrossRefGoogle Scholar
  29. 29.
    Xu M, Wang F, Zhang Y, Yang S, Zhao M, Song X (2013) Co3O4-carbon nanotube heterostructures with bead-on-string architecture for enhanced lithium storage performance. Nanoscale 5:8067–8072CrossRefGoogle Scholar
  30. 30.
    Dou YH, Xu JT, Ruan BY, Liu QN, Pan YD, Sun ZQ, Dou SX (2016) Atomic layer-by-layer Co3O4/graphene composite for high performance lithium-ion batteries. Adv Energy Mater 6:1501835CrossRefGoogle Scholar
  31. 31.
    Sun HT, Xin GQ, Hu T, Yu MP, Shao DL, Sun X, Lian J (2014) High-rate lithiation-induced reactivation of mesoporous hollow spheres for long-lived lithium-ion batteries. Nat Commun 5:5526CrossRefGoogle Scholar
  32. 32.
    Shin J-Y, Samuelis D, Maier J (2011) Sustained lithium-storage performance of hierarchical, nanoporous anatase TiO2 at high rates: emphasis on interfacial storage phenomena. Adv Funct Mater 21:3464–3472CrossRefGoogle Scholar
  33. 33.
    Hou C, Hou Y, Fan Y, Zhai Y, Wang Y, Sun Z, Fan R, Dang F, Wang J (2018) Oxygen vacancy derived local build-in electric field in mesoporous hollow Co3O4 microspheres promotes high-performance li-ion batteries. J Mater Chem A 6:6967–6976CrossRefGoogle Scholar
  34. 34.
    Wang F, Lu C, Qin Y, Liang C, Zhao M, Yang S, Sun Z, Song X (2013) Solid state coalescence growth and electrochemical performance of plate-like Co3O4 mesocrystals as anode materials for lithium-ion batteries. J Power Sources 235:67–73CrossRefGoogle Scholar
  35. 35.
    Hao Q, Li M, Jia S, Zhao X, Xu C (2013) Controllable preparation of Co3O4 nanosheets and their electrochemical performance for Li-ion batteries. RSC Adv 3(21):7850–7854CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemical Engineering, Jiangsu Key Lab for the Chemistry & Utilization of Agricultural and Forest BiomassNanjing Forestry UniversityNanjingChina
  2. 2.School of Materials Science and EngineeringXiamen University of TechnologyXiamenChina

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