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Journal of Solid State Electrochemistry

, Volume 22, Issue 12, pp 3873–3881 | Cite as

Influence of synthesis temperature on cobalt metal-organic framework (Co-MOF) formation and its electrochemical performance towards supercapacitor electrodes

  • Wenlu Xuan
  • Rajendran Ramachandran
  • Changhui Zhao
  • Fei Wang
Original Paper
  • 204 Downloads

Abstract

We have synthesized cobalt metal-organic framework (Co-MOF) at different temperatures through solvothermal route as metal-organic frameworks which can be used for supercapacitors. The effect of synthesizing temperature on Co-MOF’s structure and porous behavior were analyzed with various characterization techniques like X-ray diffraction, Brunauer-Emmett-Teller surface analyzer, scanning electron microscope, and transmission electron microscope. The charge storage performance of the as-prepared Co-MOF’s was carried out in 3 M KOH. The results proved the excellent redox behavior of Co-MOFs, and a maximum specific capacitance of 952.5 F g−1 was obtained for Co-MOF/150 (synthesized at 150 °C) at a current density of 0.25 A g−1. The higher specific surface area and micropore of Co-MOF/150 significantly heightened the electrolyte ion transport during the electrochemical performance.

Graphical abstract

Keywords

Metal-organic framework Specific capacitance Temperature Specific surface area 

Notes

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Project No. 51505209). We also acknowledge the support from Shenzhen Science and Technology Innovation Committee (Project No. JCYJ20170412154426330 and KQTD2015071710313656). Fei Wang is also supported by Guangdong Natural Science Funds for Distinguished Young Scholar (Project No. 2016A030306042).

Supplementary material

10008_2018_4096_MOESM1_ESM.doc (8.7 mb)
ESM 1 (DOC 8953 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Electrical and Electronic EngineeringSouthern University of Science and Technology (SUSTech)ShenzhenChina
  2. 2.Shenzhen Key Laboratory of 3rd Generation Semiconductor DevicesShenzhenChina
  3. 3.SUSTech Academy for Advanced Interdisciplinary StudiesShenzhenChina
  4. 4.State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghaiChina

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