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Journal of Solid State Electrochemistry

, Volume 22, Issue 11, pp 3363–3373 | Cite as

Flexible, high-wettability and thermostable separator based on fluorinated polyimide for lithium-ion battery

  • Jinyan Tan
  • Lingyi Kong
  • Zhiming Qiu
  • Yurong Yan
Original Paper
  • 272 Downloads

Abstract

To meet the booming demands for lithium-ion battery (LIB), it is practically significant to promote its electrochemical performance and safety. In our work, a novel kind of flexible membrane as separator for LIB is prepared via phase inversion method with soluble polyimide (SPI) containing trifluoromethyl substituent, which is synthesized from 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene (6FAPB) and 4,4′-oxydiphthalic anhydride (ODPA). The SPI separator shows 5% weight loss temperature (Td5%) of 535 °C and maintains intrinsic dimension even after heating at 200 °C. The SPI membrane depicts a sponge-like structure with abundant interconnected pores and delivers a dominant porosity (67%). The SPI membrane displays desired electrolyte wettability, validated by contact angle tests (16.2° and 46.8° for SPI membrane and PE separator, respectively) and electrolyte uptake tests (420 and 132% for SPI membrane and PE separator, respectively). The LIB with SPI membrane as separator exhibits nice ionic conductivity (0.92 mS cm−1) than that with PE separator (0.30 mS cm−1), and therefore affords better electrochemical performance, such as cycling stability and rate capability.

Keywords

Separator Polyimide Phase inversion Lithium-ion battery 

Notes

Funding

This work was financially supported by the National Natural Science Foundation of China (51003033) and the Fundamental Research Funds for the Central Universities, SCUT (Grant Number 2015ZM100).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringSouth China University of TechnologyGuangzhouPeople’s Republic of China

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