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Journal of Solid State Electrochemistry

, Volume 23, Issue 3, pp 735–748 | Cite as

Morphological and structural evolution of Si-Cu nanocomposites by an instantaneous vapor-liquid-solid growth and the electrochemical lithiation/delithiation performances

  • Jingshuang Liang
  • Yulin Yang
  • Jian Gao
  • Lei Zhou
  • Ming Gao
  • Zhongyuan Zhang
  • Wenfei Yang
  • Muhammad Javid
  • Youngguan Jung
  • Xinglong DongEmail author
  • Guozhong Cao
Original Paper
  • 81 Downloads

Abstract

Polymorphic Si-Cu nanocomposites of Si@Cu3Si nanowires, Si@Cu3Si nanorods, and Si@Cu3Si(Cu) nanocapsules are synthesized via the high-energy arc-discharge plasma. Electrochemical performances of these materials as anodes for lithium-ion batteries are also investigated. It is found that the morphologies and structures of above Si-Cu nanocomposites are alterable by the composition of the raw target and synthetic conditions. Optical emission spectroscopy is adopted to reveal the energetic states of excited atoms in plasma; thus, the temperature of working plasma as well as the evaporation rate of each element can be evaluated, in which both favor to control the composition of Si-Cu nanopowder product and the aborative nanostructures. Formation of multifarious Si-Cu nanostructures is understood from the in situ nucleation and anisotropic growth processes, induced by an instantaneous vapor-liquid-solid mechanism within the robust plasma. The optimal composition and microstructure of Si@Cu3Si nanorods are found for the excellent electrochemical behaviors, typically a stable discharge capacity of 783 mAh g−1 with the coulombic efficiency of 98.51% at 100 mA g−1 after 100 cycles. Good performances are attributed to one-dimensional Si-Cu nanostructure, which favors to promote Li+ ion diffusion. Metallic Cu component released from Cu3Si precursor enhances the conductivity, buffers the volume change, and facilitates the stabilization in cycling.

Keywords

Polymorphic Si-Cu nanocomposite Arc-discharge plasma Anode Lithium-ion battery 

Notes

Funding information

This work was supported by the National Natural Science Foundations of China (Nos. 51331006 and 51271044).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Jingshuang Liang
    • 1
  • Yulin Yang
    • 1
  • Jian Gao
    • 1
  • Lei Zhou
    • 1
  • Ming Gao
    • 1
  • Zhongyuan Zhang
    • 1
  • Wenfei Yang
    • 1
  • Muhammad Javid
    • 1
  • Youngguan Jung
    • 2
  • Xinglong Dong
    • 1
    Email author
  • Guozhong Cao
    • 3
  1. 1.Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Materials Science and EngineeringDalian University of TechnologyDalianPeople’s Republic of China
  2. 2.Department of Mechanical EngineeringKumoh National Institute of TechnologyGumiSouth Korea
  3. 3.Department of Materials Science and EngineeringUniversity of WashingtonSeattleUSA

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