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Electrochemical behavior of Inhcf in alkali metal electrolytes

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Abstract

The paper characterizes electrochemical properties of indium hexacyanoferrates (Inhcf). The cyclic voltammetric response in the presence of different metal alkali cations of divalent cations and of hydronium has been investigated. The Inhcf can exchange reversibly with all of these cations. This feature makes the Inhcf a good candidate for many electrochemical applications where a source or sink of metal cations is needed, e.g., electrochromic and energy storage devices. A prototype electrochromic system based on an Inhcf and Cohcf couple has been assembled and tested.

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References

  1. Miscellanea Berolinensia ad IncrementiumScientiarium (1710) 377–378

  2. Brown D (1724) J Philos Trans 33:17–24

    Google Scholar 

  3. De Tacconi NR, Rajeshwar K, Lezna RO (2003) Chem Mater 15:3046–3062

    Article  Google Scholar 

  4. Berrettoni M, Giorgetti M, Zamponi S, Conti P, Ranganathan D, Zanotto A, Saladino ML, Caponetti E (2010) J Phys Chem C 114:6401–6407

    Article  CAS  Google Scholar 

  5. Guadagnini L, Tonelli D, Giorgetti M (2010) Electrochim Acta 55:5036–5039

    Article  CAS  Google Scholar 

  6. Zamponi S, Berrettoni M, Kulesza PJ, Miecznikowski K, Malik MA, Makowski O, Marassi R (2003) Electrochim Acta 48:4261–4269

    Article  CAS  Google Scholar 

  7. Kulesza PJ, Faszynska M (1988) J Electroanal Chem 252:461–466

    Article  CAS  Google Scholar 

  8. Malik MA, Horanyi G, Kulesza PJ, Inzelt G, Kertesz V, Schmidt R, Czirok E (1998) J Electroanal Chem 452:57–62

    Article  CAS  Google Scholar 

  9. Kurdakova VV, Kondrat’ev VV, Levin OV, Malev VV (2002) Russ J Electrochem 38:1192–1199

    Article  CAS  Google Scholar 

  10. Chen LC, Tseng KS, Ho KC (2002) J Solid State Electrochem 7:1–5

    Article  CAS  Google Scholar 

  11. Tseng KS, Chen LC, Ho KC (2006) Electroanalysis 18:1306–1312

    Article  CAS  Google Scholar 

  12. Chen SM (1996) J Electroanal Chem 417:145–153

    Article  CAS  Google Scholar 

  13. Malev V, Kurdakova V, Kondratiev V, Zigel V (2004) Solid State Ionics 169:95–104

    Article  CAS  Google Scholar 

  14. Chen SM (2002) J Electroanal Chem 521:29–52

    Article  CAS  Google Scholar 

  15. Czirk E, Bcskai J, Kulesza PJ, Inzelt G, Wolkiewicz A, Miecznikowski K, Malik MA (1996) J Electroanal Chem 405:205–209

    Article  Google Scholar 

  16. Wang JY, Yu CM, Hwang SC, Ho KC, Chen LC (2008) Sol Energy Mater Sol Cells 92:112–119

    Article  CAS  Google Scholar 

  17. Jin Z, Dong S (1990) Electrochim Acta 35:1057–1060

    Article  CAS  Google Scholar 

  18. Kulesza PJ, Malik MA, Miecznikowski K, Wolkiewicz A (1996) J Electrochem Soc 143:L10–L12

    Article  CAS  Google Scholar 

  19. Zhang S, Sun W, Zhang W, Qi W, Jin L, Yamamoto K, Tao S, Jin J (1999) Analytica Chimica Acta 386:21–30

    Article  CAS  Google Scholar 

  20. Chen SM, Chan CM (2003) J Electroanal Chem 543:161–173

    Article  CAS  Google Scholar 

  21. Rutkowska IA, Stroka J, Galus Z (2008) Electrochim Acta 53:3870–3878

    Article  CAS  Google Scholar 

  22. Barcena-Soto M, Scholz F (2002) J Electroanal Chem 521:183–189

    Article  CAS  Google Scholar 

  23. Dostal A, Hermes M, Scholz F (1996) J Electroanal Chem 415:133–141

    Article  CAS  Google Scholar 

  24. Kulesza PJ, Zamponi S, Malik MA, Berrettoni M, Wolkiewicz A, Marassi R (1998) Electrochim Acta 43:919–923

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Dipartimento di Chimica Fisica e Inorganica, Università di Bologna, Viale Risorgimento 4, 40136, Bologna, Italy

    Michela Ciabocco & Mario Berrettoni

  2. INSTM, UdR Bologna, Università di Bologna, Bologna, Italy

    Mario Berrettoni

  3. Scuola di Scienze e Tecnologie, Università di Camerino, Via S. Agostino 1, 62032, Camerino, Italy

    Silvia Zamponi

  4. Department of Chemistry and Biochemistry, Miami University, Oxford, OH, 45056, USA

    James A. Cox

  5. CSGI and Department of Engineering, University of Bergamo, 24044, Dalmine, Italy

    Stefania Marini

Authors
  1. Michela Ciabocco
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  2. Mario Berrettoni
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  3. Silvia Zamponi
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  4. James A. Cox
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  5. Stefania Marini
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Corresponding author

Correspondence to Mario Berrettoni.

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Ciabocco, M., Berrettoni, M., Zamponi, S. et al. Electrochemical behavior of Inhcf in alkali metal electrolytes. J Solid State Electrochem 17, 2445–2452 (2013). https://doi.org/10.1007/s10008-013-2123-2

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  • DOI: https://doi.org/10.1007/s10008-013-2123-2

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