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Mineralogy and Petrology

, Volume 113, Issue 5, pp 563–581 | Cite as

Paragenesis and composition of xenotime-(Y) and florencite-(Ce) from unconformity-related heavy rare earth element mineralization of northern Western Australia

  • Teimoor Nazari-Dehkordi
  • Carl SpandlerEmail author
Original Paper
  • 80 Downloads

Abstract

This study investigates the paragenesis and ore mineral composition of xenotime [(Y,HREE)PO4] and florencite [LREEAl3(PO4)2(OH)6] from heavy rare earth element (HREE) deposits/prospects of the Tanami and Hall Creek regions of Western Australia. Two stages of xenotime-(Y) formation are recognized: (1) early xenotime-(Y) in breccias (breccia-hosted) and in quartz-xenotime-(Y) veins (vein-type); and (2) late xenotime-(Y) that occurs largely as dipyramidal-shaped overgrowths on the pre-existing early xenotime-(Y). Similarly, florencite-(Ce) formed in two stages including: (1) early florencite-(Ce) that coexists with and is enclosed by early xenotime-(Y) within mineralized veins; and (2) late florencite-(Ce) that replaces early xenotime-(Y), or appears as narrow rims on early florencite-(Ce). All xenotime-(Y) types from a number of examined HREE deposits/prospects are characterized by elevated U contents and marked negative Eu anomalies that we interpret to be inherited from the metasedimentary rocks from which REE and P required for the phosphate ore mineralization, were sourced. Compared to the early xenotime-(Y), the late xenotime-(Y) is richer in HREE and depleted in P, owing to the formation of the coexisting late florencite-(Ce). Moreover, early florencite-(Ce) has a near end-member florencite (s.s.) composition similar to those associated with unconformity-related U deposits, whereas late florencite-(Ce) sits on the florencite-svanbergite compositional spectrum. The high U content of xenotime-(Y) and composition of early florencite-(Ce) potentially support a genetic association between the HREE mineralization and the coeval unconformity-related U deposits of northern Australia. Nevertheless, we also urge for caution in using xenotime-(Y) composition in isolation as an indicator of geological setting.

Keywords

Xenotime Florencite Aluminum-phosphate-sulfate minerals Hydrothermal Unconformity Tanami region 

Notes

Acknowledgements

Special thanks to Robin Wilson for helping with field work and sample collection, and to Nicholas Oliver for numerous discussions on structural and geological evolution of the Browns Range. We also acknowledge Lutz Nasdala for editorial handling, and Ray Macdonald, Sam Broom-Fendley and Zdeněk Losos for their insightful comments. This work was financially and logistically supported by Northern Minerals Ltd., and by an ARC Future Fellowship (FT 120100198) to CS.

Supplementary material

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ESM 1 (DOCX 15 kb)
710_2019_676_MOESM2_ESM.docx (95 kb)
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References

  1. Adlakha EE, Hattori K (2015) Compositional variation and timing of aluminum phosphate-sulfate minerals in the basement rocks along the P2 fault and in association with the McArthur River uranium deposit, Athabasca Basin, Saskatchewan, Canada. Am Mineral 100:1386–1399CrossRefGoogle Scholar
  2. Aleinikoff JN, Lund K, Fanning CM (2015) SHRIMP U-Pb and REE data pertaining to the origins of xenotime in Belt Supergroup rocks: evidence for ages of deposition, hydrothermal alteration, and metamorphism. Can J Earth Sci 52:722–745CrossRefGoogle Scholar
  3. Andreoli MAG, Smith CB, Watkeys M, Moore JM, Ashwal LD, Hart RJ (1994) The geology of the Steenkampskraal monazite deposit, South Africa: implications for REE-Th-Cu mineralization in charnockite-granulite terrains. Econ Geol 89:994–1016CrossRefGoogle Scholar
  4. Aubert D, Stille P, Probst A (2001) REE fractionation during granite weathering and removal by waters and suspended loads: Sr and Nd isotopic evidence. Geochim Cosmochim Acta 65:387–406CrossRefGoogle Scholar
  5. Bagas L, Bierlein FP, English L, Anderson J, Maidment D, Huston DL (2008) An example of a Palaeoproteozoic back-arc basin: petrology and geochemistry of the ca. 1864 Ma Stubbins Formation as an aid towards an improved understanding of the Granites-Tanami Orogen, Western Australia. Precambrian Res 166:168–184CrossRefGoogle Scholar
  6. Bau M (1991) Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium. Chem Geol 93:219–230CrossRefGoogle Scholar
  7. Bau M, Moller P (1992) Rare earth element fractionation in metamorphogenic hydrothermal calcite, magnesite and siderite. Miner Petrol 45:231–246CrossRefGoogle Scholar
  8. Bayliss P, Kolitsch U, Nickel EH, Pring A (2010) Alunite supergroup: recommended nomenclature. Mineral Mag 74:919–927CrossRefGoogle Scholar
  9. Bea F (1996) Residence of REE, Y, Th and U in granites and crustal protoliths: implications for the chemistry of crustal melts. J Petrol 37:521–552CrossRefGoogle Scholar
  10. Beaufort D, Patrier P, Laverret E, Bruneton P, Mondy J (2005) Clay alteration associated with Proterozoic unconformity-type deposits in the East Alligator River Uranium Field, Northern Territory, Australia. Econ Geol 100:515–536CrossRefGoogle Scholar
  11. Blake DH, Tyler IM, Page RW (2000) Regional geology of the Halls Creek Orogen. In: Hoatson DM, Blake DH (eds) Geology and economic potential of the Palaeoproterozoic layered mafic/ultramafic intrusions in the East Kimberley, Western Australia. Aust Geol Surv Org Bull 246:35–62Google Scholar
  12. Broom-Fendley S, Brady AE, Wall F, Gunn G, Dawes W (2017) REE minerals at the Songwe Hill carbonatite, Malawi: HREE-enrichment in late-stage apatite. Ore Geol Rev 81:23–41CrossRefGoogle Scholar
  13. Chu M, Wang K, Griffin W, Chung S, OReilly S, Pearson N, Iizuka I (2009) Apatite composition: tracing petrogenetic processes in Transhimalayan granitoids. J Petrol 50:1829–1855CrossRefGoogle Scholar
  14. Cook NJ, Ciobanu CL, O'Rielly D, Wilson R, Das K, Wade B (2013) Mineral chemistry of Rare Earth Element (REE) mineralization, Browns Ranges, Western Australia. Lithos 172-173:192–213CrossRefGoogle Scholar
  15. Čopjaková R, Novák M, Franců E (2011) Formation of authigenic monazite-(Ce) to monazite-(Nd) from Upper Carboniferous graywackes of the Drahany Upland: roles of the chemical composition of host rock and burial temperature. Lithos 127:373–385CrossRefGoogle Scholar
  16. Crispe AJ, Vandenberg LC, Scrimgeour I (2007) Geological framework of the Archaean and Palaeoproterozoic Tanami Region, Northern Territory. Miner Deposita 42:1–26CrossRefGoogle Scholar
  17. Cross A, Crispe A (2007) SHRIMP U-Pb analyses of detrital zircon: a window to understanding the Paleoproterozoic development of the Tanami Region, northern Australia. Miner Deposita 42:27–50CrossRefGoogle Scholar
  18. Dill HG (2001) The geology of aluminium phosphates and sulfates of the alunite group minerals: a review. Earth Sci Rev 53:35–93CrossRefGoogle Scholar
  19. Doroshkevich AG, Viladkar SG, Ripp GS, Burtseva MV (2009) Hydrothermal REE mineralization in the Amba Dongar carbonatite complex, Gujarat, India. Can Mineral 47:1105–1116CrossRefGoogle Scholar
  20. Ehlers TA, Farley KA (2003) Apatite (U-Th)/He thermochronometry: methods and applications to problems in tectonic and surface processes. Earth Planet Sci Lett 206:1–14CrossRefGoogle Scholar
  21. Engi M (2017) Petrochronology based on REE-minerals: monazite, allanite, xenotime, apatite. In: Kohn M, Engi MJ, Lanari P (eds) Petrochronology: methods and applications. Rev Mineral Geochem, vol 83. Miner Soc Am, Chantilly, pp 365–418Google Scholar
  22. Forster HJ (1998) The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany. Part II: Xenotime. Am Mineral 83:1302–1315CrossRefGoogle Scholar
  23. Franz G, Andrehs G, Rhede D (1996) Crystal chemistry of monazite and xenotime from Saxothuringian-Moldanubian metapelites, NE Bavaria, Germany. Eur J Mineral 8:1097–1118CrossRefGoogle Scholar
  24. Fricker MB, Kutscher D, Aeschlimann B, Frommer J, Dietiker R, Bettmer J, Günther D (2011) High spatial resolution trace element analysis by LA-ICP-MS using a novel ablation cell for multiple or large samples. Int J Mass Spectrom 307:39–45CrossRefGoogle Scholar
  25. Gaboreau S, Beaufort D, Vieillard P, Patrier P, Bruneton P (2005) Aluminum phosphate-sulphate minerals associated with Proterozoic unconformity-type uranium deposits in the East Alligator River Uranium Field, Northern Territories, Australia. Can Mineral 43:813–827CrossRefGoogle Scholar
  26. Gaboreau S, Cuney M, Quirt D, Beaufort D, Patrier P, Mathieu R (2007) Significance of aluminium phosphate-sulfate minerals associated with U unconformity-type deposits: the Athabasca basin, Canada. Am Mineral 92:267–280CrossRefGoogle Scholar
  27. Georgieva S, Velinova N (2014) Florencite-(Ce, La, Nd) and crandallite from the advanced argillic alteration in the Chelopech high-sulphidation epithermal Cu-Au deposit, Bulgaria. C R Acad Bulg Sci 67:1669–1678Google Scholar
  28. Griffin TJ, Page RW, Sheppard S, Tyler IM (2000) Tectonic implications of Palaeoproterozoic post-collisional, high-K felsic igneous rocks from the Kimberley Region of Northwestern Australia. Precambrian Res 101:1–23CrossRefGoogle Scholar
  29. Harlov DE, Andersson UB, Forster HJ, Nystrom JO, Dulski P, Broman C (2002) Apatite-monazite relations in the kiirunavaara magnetite-apatite ore, northern Sweden. Chem Geol 191:47–72CrossRefGoogle Scholar
  30. Harlov DE, Wirth R, Hetherington CJ (2011) Fluid-mediated partial alteration in monazite: the role of coupled dissolution-reprecipitation in element redistribution and mass transfer. Contrib Mineral Petrol 162:329–348CrossRefGoogle Scholar
  31. Hendrickx MA, Slater K, Crispe AJ, Dean AA, Vandenberg LC, Smith JB (2000) Paleoproterozoic stratigraphy of the Tanami Region: regional correlations realisation preliminary results. Northern Territory Geol Surv Bull, DarwinGoogle Scholar
  32. Hetherington CJ, Jercinovic MJ, Williams ML, Mahan K (2008) Understanding geologic processes with xenotime: composition, chronology, and a protocol for electron probe microanalysis. Chem Geol 254:133–147CrossRefGoogle Scholar
  33. Hikov A, Lerouge C, Velinova N (2010) Geochemistry of alunite group minerals in hydrothermally altered rocks from the Asarel porphyry copper deposit, Central Srednogorie. Rev Bulg Geol Soc 71:133–148Google Scholar
  34. Jambor JL (1999) Nomenclature of the alunite supergroup. Can Mineral 37:1323–1341Google Scholar
  35. Kister P, Laverret E, Quirt D, Cuney M, Patrier P, Beaufort D, Bruneton P (2006) Mineralogy and geochemistry of the host-rock alterations associated to the Shea Creek unconformity-type uranium deposits (Saskatchewan, Canada), part 2. Spatial distribution of the Athabasca Group sandstone matrix minerals. Clay Clay Miner 54:295–313CrossRefGoogle Scholar
  36. Kister P, Vieillard P, Cuney M, Quirt D, Laverret E (2005) Thermodynamic constraints on the mineralogical and fluid composition evolution in a clastic sedimentary basin: the Athabasca basin (Saskatchewan, Canada). Eur J Mineral 17:325–342CrossRefGoogle Scholar
  37. Komninou A, Sverjensky DA (1996) Geochemical modeling of the formation of an unconformity-type uranium deposit. Econ Geol 91:590–606CrossRefGoogle Scholar
  38. Kositcin N, McNaughton NJ, Griffin BJ, Fletcher IR, Groves DI, Rasmussen B (2003) Textural and geochemical discrimination between xenotime of different origin in the Archaean Witwatersrand Basin, South Africa. Geochim Cosmochim Acta 67:709–731CrossRefGoogle Scholar
  39. Krenn E, Ustaszewski K, Finger F (2008) Detrital and newly formed metamorphic monazite in amphibolite-facies metapelites from the Motajica Massif, Bosnia. Chem Geol 254:164–174CrossRefGoogle Scholar
  40. Lan ZW, Chen ZQ, Li XH, Li B, Adams D (2013) Hydrothermal origin of the Paleoproterozoic xenotime from the King Leopold Sandstone of the Kimberley Group, Kimberley, NW Australia: implications for a ca 1.7 Ga far-field hydrothermal event. Aust J Earth Sci 60:497–508CrossRefGoogle Scholar
  41. Liu Y, Hu Z, Gao S, Günther D, Xu J, Gao C, Chen H (2008) In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chem Geol 257:34–43CrossRefGoogle Scholar
  42. Lorilleux G, Cuney M, Jebrak M, Rippert JC, Portella P (2003) Chemical brecciation processes in the sue unconformity-type uranium deposits, eastern Athabasca Basin (Canada). J Geochem Explor 80:241–258CrossRefGoogle Scholar
  43. Marfil R, La Iglesia A, Estupiñan J (2013) Origin and nature of the aluminium phosphate-sulfate minerals (APS) associated with uranium mineralization in triassic red-beds (Iberian Range, Spain). Estud Geol 69:21–23CrossRefGoogle Scholar
  44. McDonough WF, Sun SS (1995) Composition of the Earth. Chem Geol 120:223–253CrossRefGoogle Scholar
  45. McNaughton NJ, Rasmussen B (2017) Geochemical characterisation of xenotime formation environments using U-Th. Chem Geol 484:109–119CrossRefGoogle Scholar
  46. Moralev GV, Borisov AV, Surenkov SV, Nagaeva SP, Tarbaev MB, Kuznetsov SK, Onishchenko SA, Efanova LI, Soboleva AA (2005) Distribution and modes of occurrence of REE at the Chudnoe and Nesterovskoe occurrences of Au–Pd–REE ore mineralization in the Maldynyrd Range, nether-polar Urals. Geochem Int 43:1078–1097Google Scholar
  47. Mordberg LE (2004) Thorium in crandallite-group minerals: an example from a Devonian bauxite deposit, Timan, Russia. Russian Research Geological Institute (VSEGEI), St. Petersburg, Russia. Mineral Mag 68:489–497CrossRefGoogle Scholar
  48. Morin-Ka S, Beardsmore TJ, Hancock EA, Rasmussen B, Dunkley D, Muhling J, Zi J, Wilson R, Champion J (2016) Alteration and age of the browns range rare earth element deposits. Western Australian Department of Mines and Petroleum, PerthGoogle Scholar
  49. Müller A, Wiedenbeck M, Flem B, Schiellerup H (2008) Refinement of phosphorus determination in quartz by LA-ICP-MS through defining new reference material values. Geostand Geoanal Res 32:361–376CrossRefGoogle Scholar
  50. Nagy G, Draganits E, Demeny A, Panto G, Arkai P (2002) Genesis and transformations of monazite, florencite, and rhabdophane during medium grade metamorphism: examples from the Sopron Hills, Eastern Alps. Chem Geol 191:25–46CrossRefGoogle Scholar
  51. Nazari-Dehkordi T, Spandler C, Oliver NHS, Wilson R (2018) Unconformity–related rare earth element deposits: a regional-scale hydrothermal mineralization type of northern Australia. Econ Geol 113:1297–1305CrossRefGoogle Scholar
  52. Nazari-Dehkordi T, Spandler C, Oliver NHS, Wilson R (2019) Age, geological setting and paragenesis of heavy rare earth element mineralization of the Tanami Region, Western Australia. Miner Deposita  https://doi.org/10.1007/s00126-019-00878-4
  53. Nazari-Dehkordi T, Spandler C, Oliver NHS, Chapman J, Wilson R (2017) Provenance, tectonic setting and source of Archean metasedimentary rocks of the Browns Range Metamorphics, Tanami Region, Western Australia. Aust J Earth Sci 64:723–741CrossRefGoogle Scholar
  54. Ondrejka M, Uher P, Prsek J, Ozdin D (2007) Arsenian monazite-(Ce) and xenotime-(Y), REE arsenates and carbonates from the Tisovec-Rejkovo rhyolite, Western Carpathians, Slovakia: composition and substitutions in the (REE,Y)XO4 system (X = P, As, Si, Nb, S). Lithos 95:116–129CrossRefGoogle Scholar
  55. Page R, Sun SS, Blake D, Edgecombe D, Pearcey D (1995) Geochronology of an exposed late Archean basement terrane in the Granites-Tanami region. Aust Geol Surv Org 22:21–22Google Scholar
  56. Page RW, Griffin TJ, Tyler IM, Sheppard S (2001) Geochronological constraints on tectonic models for Australian Palaeoproterozoic high-K granites. J Geol Soc Lond 158:535–545CrossRefGoogle Scholar
  57. Patino Douce AE, Roden MF, Chaumba J, Fleisher C, Yogodzinski G (2011) Compositional variability of terrestrial mantle apatites, thermodynamic modeling of apatite volatile contents, and the halogen and water budgets of planetary mantles. Chem Geol 288:14–31CrossRefGoogle Scholar
  58. Pettke T, Oberli F, Audetat A, Guillong M, Simon AC, Hanley JJ, Klemm LM (2012) Recent developments in element concentration and isotope ratio analysis of individual fluid inclusions by laser ablation single and multiple collector ICP-MS. Ore Geol Rev 44:1023CrossRefGoogle Scholar
  59. Quirt D, Kotzer T, Kyser TK (1991) Tourmaline, phosphate minerals, zircon and pitchblende in the Athabasca group: Maw Zone and McArthur Rivers areas, Saskatchewan. In summary of investigations, Saskatchewan Geological Survey, Saskatchewan Energy and Mines 4:181–191Google Scholar
  60. Rasmussen B (1996) Early-diagenetic REE-phosphate minerals (florencite, gorceixite, crandallite, and xenotime) in marine sandstones; a major sink for oceanic phosphorus. Am J Sci 296:601–632CrossRefGoogle Scholar
  61. Rasmussen B, Muhling JR (2009) Reactions destroying detrital monazite in greenschist-facies sandstones from the Witwatersrand basin, South Africa. Chem Geol 264:311–327CrossRefGoogle Scholar
  62. Repina SA, Khiller VV, Makagonov EP (2014) Microheterogeneity of crystal growth zones as a result of REE fractionation. Geochem Int 52:1057–1071CrossRefGoogle Scholar
  63. Roberts WL, Campbell TJ, Rapp GR (1990) Encyclopedia of minerals. Van Nostrand Reinhold, New YorkCrossRefGoogle Scholar
  64. Schmandt DS, Cook NJ, Ciobanu CL, Ehrig K, Wade BP, Gilbert S, Kamenetsky VS (2019) Rare earth element phosphate minerals from the Olympic Dam Cu-U-Au-Ag deposit, South Australia: recognizing temporal-spatial controls on REE mineralogy in an evolved IOCG system. Can Mineral 57:1–22CrossRefGoogle Scholar
  65. Schoneveld L, Spandler C, Hussey K (2015) Genesis of the central zone of the Nolans Bore rare earth element deposit, Northern Territory, Australia. Contrib Mineral Petrol 170:11CrossRefGoogle Scholar
  66. Scott KM (1987) Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, Northwest Queensland, Australia. Am Mineral 72:178–187Google Scholar
  67. Sheppard S, Tyler IM, Griffin TG, Taylor WR (1999) Paleoproterozoic subduction-related and passive margin basins in the Halls Creek Orogen, northwest Australia. Aust J Earth Sci 46:679–690CrossRefGoogle Scholar
  68. Slezak PR, Spandler C (2019) Carbonatites as recorders of mantle-derived magmatism and subsequent tectonic events: an example of the Gifford Creek Carbonatite Complex, Western Australia. Lithos 328-329:212–227CrossRefGoogle Scholar
  69. Slezak PR, Spandler C, Blake K (2018) Ghosts of apatite past: using hyperspectral CL and micro-geochemical data to reveal multi-generational apatite in the Gifford Creek Carbonatite Complex. Australia Can Mineral 56:1–25Google Scholar
  70. Smith JB (2001) Summary of results, joint NTGS-AGSO age determination program 1999-2001. Northern Territory Geol Surv, Darwin, AustraliaGoogle Scholar
  71. Spandler C, Pettke T, Rubatto D (2011) Internal and external fluid sources for eclogite-facies veins in the Monviso meta-ophiolite, Western Alps: implications for fluid flow in subduction zones. J Petrol 52:1207–1236CrossRefGoogle Scholar
  72. Spear FS, Pyle JM (2002) Apatite, monazite and xenotime in metamorphic rocks. In: Kohn MJ, Rakovan J, Hughes JM (eds) Phospates. Geochemical, geobiological and materials importance. Rev Mineral Geochem, vol 48. Miner Soc Am, Chantilly, pp 293–335Google Scholar
  73. Stepanov AS, Hermann J, Rubatto D, Rapp RP (2012) Experimental study of monazite/melt partitioning with implications for the REE, Th and U geochemistry of crustal rocks. Chem Geol 300:200–220CrossRefGoogle Scholar
  74. Švecová E, Čopjaková R, Losos Z, Škoda R, Nasdala L, Cícha J (2016) Multi-stage evolution of xenotime-(Y) from Písek pegmatites, Czech Republic: an electron probe micro-analysis and Raman spectroscopy study. Miner Petrol 110:747–765CrossRefGoogle Scholar
  75. Tyler IM, Griffin TJ, Page RW, Shaw RD (1995) Are there terranes within the Lamboo Complex of the Halls Creek Orogen? Geol Surv Western Australia 1993-94:37–46Google Scholar
  76. Vallini DA, Groves DI, McNaughton NJ, Fletcher IR (2007) Uraniferous diagenetic xenotime in northern Australia and its relationship to unconformity-associated uranium mineralisation. Miner Deposita 42:51–64CrossRefGoogle Scholar
  77. Van Achterbergh E, Ryan CG, Jackson SE, Griffin WL (2001) Data reduction software for LA-ICP-MS. in: Sylvester PJ (ed) laser ablation-ICP mass spectrometry in the earth sciences: principles and applications. Mineral Assoc Canada 29:239–243Google Scholar
  78. Van Emden B, Thornber MR, Graham J, Lincoln FJ (1997) The incorporation of actinides in monazite and xenotime from placer deposits in western Australia. Can Mineral 35:95–104Google Scholar
  79. Williams IS (2001) Response of detrital zircon and monazite, and their U-Pb isotopic systems, to regional metamorphism and host-rock partial melting, Cooma Complex, southeastern Australia. Aust J Earth Sci 48:557–580CrossRefGoogle Scholar
  80. Wilson JA (1984) Crandallite group minerals in the Helikian Athabasca group in Alberta, Canada. Can J Earth Sci 22:637–641CrossRefGoogle Scholar
  81. Zi JW, Rasmussen B, Muhling JR, Fletcher IR, Thorne AM, Johnson SP, Cutten HN, Dunkley DJ, Korhonen FJ (2015) In situ U-Pb geochronology of xenotime and monazite from the Abra polymetallic deposit in the Capricorn Orogen, Australia: dating hydrothermal mineralization and fluid flow in a long-lived crustal structure. Precambrian Res 260:91–112CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.Economic Geology Research CentreJames Cook UniversityTownsvilleAustralia

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