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Monatshefte für Chemie - Chemical Monthly

, Volume 150, Issue 11, pp 1893–1894 | Cite as

Correction to: Contributions to the stereochemistry of zirconium oxysalts—part III: syntheses and crystal structures of M2+Zr(SO4)3 with M = Mg, Mn, Co, Ni, Zn and Cd, and a note on (Fe3+,2+,Zr)2(SO4)3 and Fe2(SO4)3

  • Gerald GiesterEmail author
  • Dominik Talla
  • Manfred Wildner
Correction

Correction to: Monatshefte für Chemie - Chemical Monthly  https://doi.org/10.1007/s00706-019-02496-2

The original version of this article unfortunately contained a mistake in Table 3. The corrected Table 3 is given below.

The original article has been corrected.

Table 3

Crystal data and details of the intensity measurements and structure refinements for M2+Zr(SO4)3 compounds with M = Mg, Mn, Co, Ni, Zn and Cd as well as (Fe3+,2+,Zr)2(SO4)3 and Fe2(SO4)3

Crystal data

MgZr

MnZr

CoZr

NiZr

Space group

Pc

P21/n

P21/n

P21/n

a

14.902 (2)

8.706 (1)

8.580 (1)

8.537 (2)

b

8.759 (1)

8.911 (1)

8.824 (1)

8.782 (2)

c

14.896 (2)

12.219 (2)

12.030 (2)

11.964 (3)

β

108.70 (1)

90.61 (1)

90.32 (1)

90.45 (1)

V3

1841.7 (5)

947.9 (2)

910.7 (3)

896.9 (3)

Z

8

4

4

4

ρcalc/g cm−3

2.912

3.043

3.197

3.244

µ/MoKα (mm−1)

2.01

3.15

3.72

4.03

Crystal size/μm3

100 × 50 × 25

200 × 175 × 150

175 × 100 × 75

300 × 175 × 125

Data and refinement

Unique data

22677

5847

5617

5531

Data with Fo > 4σ/Fo

19890

5220

4463

4790

Variables

623

155

155

155

R1 [for Fo > 4σ/Fo]1

0.0360

0.0193

0.0248

0.0250

wR2 [for all Fo2]1

0.0727

0.0481

0.0583

0.0667

a, b 2

0.028, 0.0

0.017, 0.69

0.022, 0.62

0.031, 0.74

∆ρmin/max/e Å−3

− 1.03/0.90

− 0.54/0.70

− 0.75/0.88

− 0.99/1.30

Crystal data

ZnZr

CdZr

Fe3+Fe2+Zr

FeFe

Space group

P21/n

P21/n

P21/n

P21/n

a

8.556 (1)

8.710 (2)

8.341 (1)

8.279 (1)

b

8.796 (1)

9.002 (2)

8.599 (1)

8.530 (2)

c

11.997 (2)

12.312 (3)

11.702 (2)

11.604 (2)

β

90.39 (1)

91.09 (1)

90.79 (1)

90.78 (1)

V3

902.8 (1)

965.2 (4)

839.2 (1)

819.4 (1)

Z

4

4

4

4

ρcalc/g cm−3

3.272

3.385

3.225

3.242

µ/MoKα (mm−1)

4.57

3.99

4.17

4.38

Crystal size/μm3

200 × 200 × 100

250 × 200 × 100

250 × 175 × 150

200 × 200 × 100

Data and refinement

Unique data

5594

5981

5144

5065

Data with Fo > 4σ/Fo

5313

5739

4245

4837

Variables

155

155

159

155

R1 [for Fo > 4σ/Fo]1

0.0164

0.0162

0.0266

0.0186

wR2 [for all Fo2]1

0.0403

0.0421

0.0513

0.0481

a, b 2

0.013, 0.59

0.015, 0.90

0.012, 1.22

0.018, 0.56

∆ρmin/max/e Å−3

− 0.52/0.64

− 0.73/0.70

− 0.71/0.77

− 0.82/0.60

1R1 =  Σ || Fo  |−| Fc  || / Σ  |Fo  |; wR2 = [Σw(Fo2Fc2)2w(Fo2)2]½

2w  = 1/[σ2(Fo2) + (a × P)2 + b × P]; P = {[max of (0 or Fo2)] + 2Fc2}/3

Notes

Copyright information

© The Author(s) 2019

Authors and Affiliations

  1. 1.Institut für Mineralogie und KristallographieUniversität WienViennaAustria

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