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Microchimica Acta

, 186:674 | Cite as

Green ultrasound assisted magnetic nanofluid-based liquid phase microextraction coupled with gas chromatography-mass spectrometry for determination of permethrin, deltamethrin, and cypermethrin residues

  • Mahboube ShiraniEmail author
  • Behrouz Akbari-adergani
  • Masoud Boroumand Jazi
  • Ali Akbari
Original Paper

Abstract

Ultrasound-assisted magnetic nanofluid-based liquid-phase microextraction was coupled to GC-MS in a method for simultaneous determination of the pyrethroid insecticides permethrin, deltamethrin, and cypermethrin. A highly efficient extraction solvent called “magnetic nanofluid (MNF)” is introduced for preconcentration of pyrethroids. The MNF consists of magnetic multiwalled carbon nanotubes (MMWCNTs) and deep eutectic solvent. Following microextraction, the MNF was detached by an external magnet from the medium without the need for centrifugation. 2-Pyridinecarboxamide, choline chloride, and anhydrous ferric chloride were used for the synthesis of the deep eutectic solvent. The effects of pH value, volume of MNF, sonication time, sample volume, and ionic strength, type and amount of back extraction solvent were investigated. Under optimum conditions of MNF volume of 50 μL, time of 5 min, 100 μL acetone as back extraction solvent, NaCl concentration of 1 mol.L−1 and sample volume of 30 mL, the detection limits are 2.8, 2.7 and 2.0 ng·mL−1 for permethrin, deltamethrin and cypermethrin, respectively. The linear response ranges are between 0.01 and 250 ng·mL−1, and relative standard deviations (for n = 7) are 3.5, 3.2 and 2.8%. The method was successfully applied to the determination of trace levels of permethrin, deltamethrin and cypermethrin in (spiked) milk samples.

Graphical abstract

Schematic representation of ultrasound assisted magnetic nanofluid-based liquid phase microextraction separation/preconcentration of permethrin, deltametrin, and cypermethrin residues in milk using GC-MS.

Keywords

Magnetic nanofluid Liquid phase microextraction Deep eutectic solvent Pyrethroids, milk, gas chromatography-mass spectrometry 

Notes

Acknowledgements

The authors gratefully appreciate University of Jiroft.

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2019_3763_MOESM1_ESM.doc (181 kb)
ESM 1 (DOC 181 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  • Mahboube Shirani
    • 1
    Email author
  • Behrouz Akbari-adergani
    • 2
  • Masoud Boroumand Jazi
    • 3
  • Ali Akbari
    • 1
  1. 1.Department of Chemistry, Faculty of ScienceUniversity of JiroftJiroftIran
  2. 2.Food and Drug Laboratory Research CenterFood and Drug Administration Ministry of Health and Medical EducationTehranIslamic Republic of Iran
  3. 3.Animal Science Research DepartmentIsfahan Agricultural and Natural Resources Research and Education Center, Agricultural Research, Education and Extension Organization (AREEO), Isfahan, IranEsfahanIran

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