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Microchimica Acta

, 186:453 | Cite as

Eggshell membrane-templated gold nanoparticles as a flexible SERS substrate for detection of thiabendazole

  • Qi Ding
  • Zewen Kang
  • Xingsheng He
  • Minggong Wang
  • Mengshi LinEmail author
  • Hetong LinEmail author
  • Da-Peng YangEmail author
Original Paper
  • 25 Downloads

Abstract

The authors describe a three-dimensional (3D) flexible interconnected porous nanocomposite membrane for use in surface-enhanced Raman scattering (SERS). It was obtained via in -situ deposition of gold nanoparticles (AuNPs, ca. 10 nm) on eggshell membranes (ESM). The AuNP/ESM nanocomposites were used as a SERS substrate for detection of the pesticide thiabendazole (TBZ) with prominent Raman bands at 1180, 1280, and 1580 cm−1. The abundant “hot spots” are generated by the closely arranged AuNPs in the 3D geometry of the ESM networks. This makes the SERS substrate highly sensitive because of remarkable signal amplification. The substrates were applied to the rapid detection of TBZ in Oolong tea. The limit of detection for TBZ is 0.1 ppm.

Graphical abstract

Schematic presentation of a three-dimensional flexible interconnected porous nanocomposite membrane as surface-enhanced Raman scattering (SERS) substrate for detection of thiabendazole (TBZ) in tea.

Keywords

Hot spot Network Pesticides Food safety Tea analysis Nanotechnology 

Notes

Acknowledgements

This study was supported by the National Natural Science Foundation of China (Grant No. 81472001), the Tongjiang Scholars Program of Quanzhou City, Natural Science Foundation of Fujian Province (2015 J05030), and Quanzhou City Science & Technology Program of China (2017G023).

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2019_3543_MOESM1_ESM.docx (105 kb)
ESM 1 (DOCX 104 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of Food ScienceFujian Agriculture and Forestry UniversityFuzhouPeople’s Republic of China
  2. 2.College of Chemical Engineering and Materials ScienceQuanzhou Normal UniversityQuanzhouPeople’s Republic of China
  3. 3.Food Science Program, Division of Food System & BioengineeringUniversity of MissouriColumbiaUSA

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