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Microchimica Acta

, 186:12 | Cite as

A carbon paste electrode modified with a nickel titanate nanoceramic for simultaneous voltammetric determination of ortho- and para-hydroxybenzoic acids

  • Fahimeh Zeraatkar Kashani
  • Sayed Mehdi Ghoreishi
  • Asma Khoobi
  • Morteza Enhessari
Original Paper
  • 84 Downloads

Abstract

An electrochemical sensor is described for the simultaneous determination of ortho-hydroxybenzoic acid (OHB) and para-hydroxybenzoic acid (PHB). The sensor consists of a carbon paste electrode modified with nickel titanate nanoceramics (NiTiO3/CPE). The NiTiO3 nanoceramics and the nanostructured modified CPE were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, electrochemical impedance spectroscopy and cyclic voltammetry. Differential pulse voltammetry indicates that the response to OHB (best measured at 0.90 V vs. Ag/AgCl) and PHB (measured at 0.80 V vs. Ag/AgCl) is significantly improved at the modified CPE compared to a bare CPE. The limits of detection (at S/N = 3) are 0.38 and 0.10 μM for OHB and PHB, respectively. The method was applied to the determination of the two isomers in peeling skin lotion and during the Kolbe-Schmitt reaction.

Graphical abstract

Nickel titanate nanoceramics (NiTiO3) were synthesized by a sol-gel method. Then, a carbon paste electrode modified with NiTiO3 (NiTiO3/CPE) was constructed. The modified electrode was applied to the interference-free and simultaneous determination of ortho-hydroxybenzoic acid (OHB) and para-hydroxybenzoic acid (PHB).

Keywords

Nanostructured sensor Interference-free determination Monohydroxy benzoic acid isomers Salicylic acid Microscopic and electrochemical techniques 

Notes

Acknowledgements

The authors are grateful to University of Kashan for supporting this work by grant no. 211037-28.

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2018_3113_MOESM1_ESM.doc (1.3 mb)
ESM 1 (DOC 1342 kb)

References

  1. 1.
    Li Z, Yue Y, Hao Y, Feng S, Zhou X (2018) A glassy carbon electrode modified with cerium phosphate nanotubes for the simultaneous determination of hydroquinone, catechol and resorcinol. Microchim Acta 185:215–224CrossRefGoogle Scholar
  2. 2.
    Goulart LA, Gonçalves R, Correa AA, Pereira EC, Mascaro LH (2018) Synergic effect of silver nanoparticles and carbon nanotubes on the simultaneous voltammetric determination of hydroquinone, catechol, bisphenol A and phenol. Microchim Acta 185:12–21CrossRefGoogle Scholar
  3. 3.
    Huang W, Zhang T, Hu X, Wang Y, Wang J (2018) Amperometric determination of hydroquinone and catechol using a glassy carbon electrode modified with a porous carbon material doped with an iron species. Microchim Acta 185:37–44CrossRefGoogle Scholar
  4. 4.
    Farhoosh R, Johnny S, Asnaashari M, Molaahmadibahraseman N, Sharif A (2016) Structure–antioxidant activity relationships of o-hydroxyl, o-methoxy, and alkyl ester derivatives of p-hydroxybenzoic acid. Food Chem 194:128–134CrossRefGoogle Scholar
  5. 5.
    Shen Y, Rao D, Sheng Q, Zheng J (2017) Simultaneous voltammetric determination of hydroquinone and catechol by using a glassy carbon electrode modified with carboxy-functionalized carbon nanotubes in a chitosan matrix and decorated with gold nanoparticles. Microchim Acta 184:3591–3601CrossRefGoogle Scholar
  6. 6.
    Palanisamy S, Ramaraj SK, Chen SM, Velusamy V, Yang TC, Chen TW (2017) Voltammetric determination of catechol based on a glassy carbon electrode modified with a composite consisting of graphene oxide and polymelamine. Microchim Acta 184:1051–1057CrossRefGoogle Scholar
  7. 7.
    Buleandra M, Rabinca AA, Badea IA, Balan A, Stamatin I, Mihailciuc C, Ciucu AA (2017) Voltammetric determination of dihydroxybenzene isomers using a disposable pencil graphite electrode modified with cobalt-phthalocyanine. Microchim Acta 184:1481–1488CrossRefGoogle Scholar
  8. 8.
    Gao SY, Li H, Wang L, Yang LN (2010) Simultaneous separation and determination of benzoic acid compounds in the plant medicine by high performance capillary electrophoresis. J Chin Chem Soc 57:1374–1380CrossRefGoogle Scholar
  9. 9.
    Shi S, Guo J, You Q, Chen X, Zhang Y (2014) Selective and simultaneous extraction and determination of hydroxybenzoic acids in aqueous solution by magnetic molecularly imprinted polymers. Chem Eng J 243:485–493CrossRefGoogle Scholar
  10. 10.
    El-Samman FM, Abdulahed-Malalla H, Amin D (1985) Titrimetric microdetermination of salicylic, acetylsalicylic, and p-hydroxybenzoic acids by amplification reactions. Microchem J 31:224–226CrossRefGoogle Scholar
  11. 11.
    Shabir GA (2011) Simultaneous determination of p-hydroxybenzoic acid, 2-phenoxyethanol, methyl-p-hydroxybenzoate, ethyl-p-hydroxybenzoate, propyl-p-hydroxybenzoate, iso-butyl-p-hydroxybenzoate, and n-butyl-p-hydroxybenzoate in senselle lubricant formulation by HPLC. J Liq Chromatogr Relat Technol 34:679–689CrossRefGoogle Scholar
  12. 12.
    Negishi O, Ozawa T (1996) Determination of hydroxycinnamic acids, hydroxybenzoic acids, hydroxybenzaldehydes, hydroxybenzyl alcohols and their glucosides by high-performance liquid chromatography. J Chromatogr A 756:129–136CrossRefGoogle Scholar
  13. 13.
    Sottofattori E, Anzaldi M, Balbi A, Tonello G (1998) Simultaneous HPLC determination of multiple components in a commercial cosmetic cream. J Pharm Biomed Anal 18:213–217CrossRefGoogle Scholar
  14. 14.
    Lee MR, Lin CY, Li ZG, Tsai TF (2006) Simultaneous analysis of antioxidants and preservatives in cosmetics by supercritical fluid extraction combined with liquid chromatography–mass spectrometry. J Chromatogr A 1120:244–251CrossRefGoogle Scholar
  15. 15.
    Koršič J, Milivojevič D, Smerkolj R, Kučan E, Prošek M (1981) Quantitative analysis of some preservatives in pharmaceutical formulations by different chromatographic methods. J High Resolut Chromatogr 4:24–26CrossRefGoogle Scholar
  16. 16.
    Radus TP, Gyr G (1983) Determination of antimicrobial preservatives in pharmaceutical formulations using reverse-phase liquid chromatography. J Pharm Sci 72:221–224CrossRefGoogle Scholar
  17. 17.
    Wang L, Huang P, Bai J, Wang H, Zhang L, Zhao Y (2006) Simultaneous electrochemical determination of phenol isomers in binary mixtures at a poly (phenylalanine) modified glassy carbon electrode. Int J Electrochem Sci 1:403–413Google Scholar
  18. 18.
    Ahmad R, Wolfbeis OS, Hahn YB, Alshareef HN, Torsi L, Salama KN (2018) Deposition of nanomaterials: a crucial step in biosensor fabrication. Mater Today Commun 17:289–321CrossRefGoogle Scholar
  19. 19.
    Taylor DJ, Fleig PF, Page RA (2002) Characterization of nickel titanate synthesized by sol–gel processing. Thin Solid Films 408:104–110CrossRefGoogle Scholar
  20. 20.
    Dharmaraj N, Park HC, Kim CK, Kim HY, Lee DR (2004) Nickel titanate nanofibers by electrospinning. Mater Chem Phys 87:5–9CrossRefGoogle Scholar
  21. 21.
    Beenakumari KS (2013) Electrochemical method for synthesis of nickel titanate nano particles. J Exp Nanosci 5:265–269Google Scholar
  22. 22.
    Beenakumari KS (2009) Corrosion prevention of mild steel in tap water by in-situ deposi-tion of nickel titanate produced by co-precipitation method. Mater Sci Res India 6:235–240Google Scholar
  23. 23.
    Sadjadi MS, Zare K, Khanahmadzadeh S, Enhessari M (2008) Structural characterization of NiTiO3 nanopowders prepared by stearic acid gel method. Mater Lett 62:3679–3681CrossRefGoogle Scholar
  24. 24.
    Beitollahi H, Taher MA, Ahmadipour M, Hosseinzadeh R (2014) Electrocatalytic determination of captopril using a modified carbon nanotube paste electrode: application to determination of captopril in pharmaceutical and biological samples. Measurement 47:770–776CrossRefGoogle Scholar
  25. 25.
    Bard AJ, Faulkner LR (2002) Fundamentals and applications. Wiley, New York, pp 1364–1365Google Scholar
  26. 26.
    Wang Y, Chen ZZ (2009) A novel poly (taurine) modified glassy carbon electrode for the simultaneous determination of epinephrine and dopamine. Colloids Surf B 74:322–327CrossRefGoogle Scholar
  27. 27.
    Bressolle F, Bromet-Petit M, Audran M (1996) Validation of liquid chromatographic and gas chromatographic methods applications to pharmacokinetics. J Chromatogr B 686:3–10CrossRefGoogle Scholar
  28. 28.
    Park J, Eun C (2016) Electrochemical behavior and determination of salicylic acid at carbon-fiber electrodes. Electrochim Acta 194:346–356CrossRefGoogle Scholar
  29. 29.
    Shah S, Dhanani T, Kumar S (2013) Validated HPLC method for identification and quantification of p-hydroxy benzoic acid and agnuside in Vitex negundo and Vitex trifolia. JPA 3:500–508PubMedGoogle Scholar
  30. 30.
    Díaz AN, Algarra M, Feria LS, Sanchez FG (2008) Fluorimetric determination of p-hydroxybenzoic acid in beer as α-cyclodextrin inclusion complex. Anal Lett 41:1802–1810CrossRefGoogle Scholar
  31. 31.
    Rawlinson S, McLister A, Kanyong P, Davis J (2018) Rapid determination of salicylic acid at screen printed electrodes. Microchem J 137:71–77CrossRefGoogle Scholar
  32. 32.
    Huang ZH, Wang ZL, Shi BL, Wei D, Chen JX, Wang SL, Gao BJ (2015) Simultaneous determination of salicylic acid, jasmonic acid, methyl salicylate, and methyl jasmonate from Ulmus pumila leaves by GC-MS. Int J Anal Chem:1–7Google Scholar
  33. 33.
    Xie Y, Yuan C (2003) Visible-light responsive cerium ion modified titania sol and nanocrystallites for X-3B dye photodegradation. Appl Catal B Environ 46:251–259CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Austria, ein Teil von Springer Nature 2018

Authors and Affiliations

  • Fahimeh Zeraatkar Kashani
    • 1
  • Sayed Mehdi Ghoreishi
    • 1
  • Asma Khoobi
    • 1
  • Morteza Enhessari
    • 2
  1. 1.Department of Analytical Chemistry, Faculty of ChemistryUniversity of KashanKashanIslamic Republic of Iran
  2. 2.Department of ChemistryIslamic Azad UniversityNaraghIran

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