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Surfactant-polymer interaction: effect of hydroxypropylmethyl cellulose on the surface and solution properties of gemini surfactants

  • Prashant Bhardwaj
  • Mohammad Kamil
  • Manorama Panda
Original Contribution
  • 15 Downloads

Abstract

Interaction of a nonionic polymer hydroxypropylmethyl cellulose (HPMC) with the cationic gemini surfactants, ethane-1,2-diyl bis (N,N-dimethyl-N-hexadecylammoniumacetoxy) dichloride (16-E2-16), pentanediyl-1,5-bis (dimethylcetylammonium bromide) (16-5-16), hexanediyl-1,6-bis(dimethylcetylammonium bromide) (16-6-16), and the conventional surfactant (cetyltrimethylammonium bromide, CTAB) has been investigated by surface tension and rheology measurements. Stronger interaction of HPMC with the geminis as compared to the conventional surfactant is indicated by the values of physicochemical parameters which include the critical aggregation concentration (cac), critical micelle concentration (cmc), ΔG \( {}_m^o \) (standard Gibbs free energy of micellization), Γmax (maximum surface excess concentration at the air/solution interface), Amin (minimum area per surfactant molecule), and η (viscosity). Interaction between the surfactant and polymer in the mixed systems results in the formation of polymer-surfactant micelles; strength of the interaction is found to be dependent upon the nature of surfactant. On increasing the polymer concentrations, cac as well as cmc of the surfactant increases.

Graphical abstract

Effect of [16-E2-16] on the viscosity of polymer solutions at different temperatures and concentrations of HPMC: a 0%, b 0.1%, c 0.5%, and d 1% (w/v)

Keywords

Gemini surfactant Nonionic polymer Surface tension Rheology Critical aggregation concentration Critical micelle concentration 

Notes

Funding information

Financial assistance (Award number PDFWM-2012-13-GE-UTT-17492) by the University Grants Commission, Government of India, is gratefully acknowledged.

Compliance with ethical standards

Conflicts of interest

The authors declare that they have no conflict of interest.

Supplementary material

396_2018_4409_MOESM1_ESM.doc (538 kb)
ESM 1 (DOC 538 kb)

References

  1. 1.
    Gennes PG (1990) Interactions between polymers and surfactants. J Phys Chem 94:8407–8413CrossRefGoogle Scholar
  2. 2.
    Lindman B, Antunes F, Aidarova S, Miguel M, Nylander T (2014) Polyelectrolyte ⎯ surfactant association from fundamentals to applications. Colloid J 76:585–594CrossRefGoogle Scholar
  3. 3.
    Bahadur P, Dubin P, Roa YK (1995) Complex formation between sodium dodecyl sulfate and poly (4-vinylpyridine N-oxide). Langmuir 11:1951–1955CrossRefGoogle Scholar
  4. 4.
    Nilsson S (1995) Interactions between water-soluble cellulose derivatives and surfactants .1. The HPMC/SDS/water system. Macromolecules 28:7837–7844CrossRefGoogle Scholar
  5. 5.
    Sardar N, Kamil M, Ali MS, Kabir-ud-Din (2011) Solution behavior of nonionic polymer hydroxypropylmethyl cellulose: effect of salts on the energetics at the cloud point. J Chem Eng Data 56:984–987CrossRefGoogle Scholar
  6. 6.
    Sardar N, Kamil M, Kabir-ud-Din (2012) Interaction between nonionic polymer hydroxypropyl methyl cellulose (HPMC) and cationic gemini/conventional surfactants. Ind Eng Chem Res 51:1227–1235CrossRefGoogle Scholar
  7. 7.
    Fatma N, Panda M, Ansari WH, Kabir-ud-Din (2015) Environment-friendly ester bonded gemini surfactant: mixed micellization of 14-E2-14 with ionic and nonionic conventional surfactants. J Mol Liq 211:247–255CrossRefGoogle Scholar
  8. 8.
    Panda M, Kamil M (2017) Polymer-amphiphile interactions: an overview. Eurasian Chem Tech J 19:99–113CrossRefGoogle Scholar
  9. 9.
    Hait SK, Moulik SP (2002) Gemini surfactants: a distinct class of self-assembling molecules. Curr Sci 82:1101–1111Google Scholar
  10. 10.
    Ansari WH, Fatma N, Panda M, Kabir-ud-Din (2013) Solubilization of polycyclic aromatic hydrocarbons by novel biodegradable cationic Gemini surfactant ethane-1,2-Diylbis(N,N-dimethyl-N-hexadecylammoniumacetoxy) dichloride and its binary mixtures with conventional surfactants. Soft Matter 9:1478–1487CrossRefGoogle Scholar
  11. 11.
    Panda M, Fatma N, Kabir-ud-Din (2016) Enhanced aqueous solubility of polycyclic aromatic hydrocarbons by green diester-linked cationic gemini surfactants and their binary solutions. J Mol Struct 1115:109–116CrossRefGoogle Scholar
  12. 12.
    Siddiqui H, Kamil M, Panda M, Kabir-ud-Din (2014) Solubilization of phenanthrene and fluorene in equimolar binary mixtures of gemini/conventional surfactants. Chin J Chem Eng 22:1009–1015CrossRefGoogle Scholar
  13. 13.
    Goddard ED (1990) Polymer/surfactant interaction. J Soc Cosmet Chem 41:23–49Google Scholar
  14. 14.
    Katona JM, Jaroslav M, Sovilj VJ, Petrovi LB, Mucic NZ (2010) Tensiometric investigation of the interaction and phase separation in a polymer mixture – ionic surfactant ternary system. J Serb Chem Soc 75:823–831CrossRefGoogle Scholar
  15. 15.
    Wu X, Han M, Zahrani BH, Guo L (2015) Effect of surfactant-polymer interaction on the interfacial properties for chemical EOR Baharain, SPE-172706-MSGoogle Scholar
  16. 16.
    Bogdanova YG, Dolzhikova VD (2008) Surface and bulk properties of aqueous binary mixtures of pluronic F68 and low-molecular-weight cationic surfactants : 1. Surface tension and association in aqueous solutions. Colloid J 70:160–165Google Scholar
  17. 17.
    Banipal TS, Kaur H, Banipal PK, Sood AK (2014) Effect of head groups, temperature and polymer concentration on surfactant – polymer interactions. J Surfactant Deterg 17:1181–1191CrossRefGoogle Scholar
  18. 18.
    Joshi SC (2011) Sol-gel behavior of hydroxypropyl methylcellulose (HPMC) in ionic media including drug release. Materials 4:1861–1905CrossRefGoogle Scholar
  19. 19.
    Khan IA, Anjum K, Koya PA, Kabir-ud-Din (2014) Tensiometric and conductometric studies of the effect of polymers on the aggregation behavior of cationic amphiphilic drugs IMP and PMT. J Mol Liq 193:6–12CrossRefGoogle Scholar
  20. 20.
    Khan IA, Anjum K, Koya PA, Kabir-ud-Din (2013) Effect of inorganic salts on the clouding behavior of hydroxypropyl methyl cellulose in presence of amphiphilic drugs. Colloids Surf B 103:496–501CrossRefGoogle Scholar
  21. 21.
    Abbas G, Irawan S, Kumar S, Memon KR, Khalwar SA (2014) Characteristics of oil well cement slurry using hydroxypropylmethylcellulose. J App Sci 14:1154–1160CrossRefGoogle Scholar
  22. 22.
    Phadtare D, Phadtare G, Asawat M (2014) Hypromellose – a choice of polymer in extended release tablet formulation. World J Pharm Sci 3:551–566Google Scholar
  23. 23.
    Ali MS, Anjum K, Khan JM, Khan RH, Kabir-ud-Din (2011) Complexation behavior of gelatin with amphiphilic drug imipramine hydrochloride as studied by conductimetry, surface tensiometry and circular dichroism studies. Colloids Surf. B 82:258–262CrossRefGoogle Scholar
  24. 24.
    Yan P, Chen L, Xioa JX, Zhu BY, Zhao GX (2005) Polymer effects on the equimolar mixed cationic – anionic surfactants. Colloids Surf A 259:55–61CrossRefGoogle Scholar
  25. 25.
    Mirgorodskaya AB, Yatskevich EI, Zakharova LY, Konovalov AI (2012) Gemini surfactant – nonionic polymer mixed micellar systems. Colloid J 74:96–103CrossRefGoogle Scholar
  26. 26.
    Tajik B, Beheshteh S, Amani R, Hashemianzadeh SM (2013) The study of polymer – surfactant interaction in catanionic surfactant mixtures. Colloids Surf A 436:890–897CrossRefGoogle Scholar
  27. 27.
    Khan IA, Anjum K, Koya PA, Qadeer A, Kabir-ud-Din (2014) Cloud point, fluorimetric and 1H NMR studies of ibuprofen-polymer systems. J Mol Stru 1056–1057:254–261CrossRefGoogle Scholar
  28. 28.
    Kabir-ud-Din, Fatma W, Khan ZA, Dar AA (2007) 1H NMR and viscometric studies on cationic gemini surfactants in presence of aromatic acids and salts. J Phys Chem B 111:8860–8867CrossRefGoogle Scholar
  29. 29.
    Ali MS, Suhail M, Ghosh G, Kamil M, Kabir-ud-Din (2009) Interactions between cationic gemini/conventional surfactants with polyvinylpyrrolidone: specific conductivity and dynamic light scattering studies. Colloids Surf A 350:51–56CrossRefGoogle Scholar
  30. 30.
    Khan MY, Samanta A, Ojha K, Mandal A (2008) Interaction between aqueous solutions of polymer and surfactant and its effect on physicochemical properties. Asia Pac J Chem Eng 3:579–585CrossRefGoogle Scholar
  31. 31.
    Chattoraj DK, Birdi S (1984) Adsorption and the Gibbs surface excess. Plenum, New YorkCrossRefGoogle Scholar
  32. 32.
    Alami EG, Beinert G, Marie P, Zana R (1993) Alkanediyl-R,-bis(dimethylalkylammonium bromide) surfactants. 3. Behavior at the air-water interface. Langmuir 9:1465–1467CrossRefGoogle Scholar
  33. 33.
    Panda M, Kabir-ud-Din (2011) Study of surface and solution properties of gemini-conventional surfactant mixtures and their effects on solubilization of polycyclic aromatic hydrocarbons. J Mol Liq 163:93–98CrossRefGoogle Scholar
  34. 34.
    Panda M, Kabir-ud-Din (2013) Solubilization of polycyclic aromatic hydrocarbons by gemini-conventional mixed surfactant systems. J Mol Liq 187:106–113CrossRefGoogle Scholar
  35. 35.
    Panda M, Kamil M (2017) Interaction of oxy-diester-linked cationic gemini surfactants with nonionic amphiphiles in aqueous medium. Colloid Polym Sci 295:2363–2371Google Scholar
  36. 36.
    Zhang JY, Wang XP, Liu HY, Jiang L (1998) Interfacial rheology investigation of polyacrylamide surfactant interactions. Colloid Surf A 132:9–16CrossRefGoogle Scholar
  37. 37.
    Sardar N, Kamil M, Kabir-ud-Din (2013) Interaction between polyvinylpyrrolidone and cationic gemini/conventional surfactants. Chem Eng Commun 200:1683–1700CrossRefGoogle Scholar
  38. 38.
    Majidaie S, Muhammad MM, Tan IM, Demiral B, Lee SYC (2012) Non-petrochemical surfactant for enhanced oil recovery. Soc Petroleum Eng SPE-153493-MSGoogle Scholar
  39. 39.
    Hu Z, Azmi SM, Raza G, Glover PWJ, Wen D (2016) Nanoparticle-assisted water-flooding in Berea Sandstones. Energy Fuels 30:2791–2804CrossRefGoogle Scholar
  40. 40.
    Abadli, F. (2011) Investigation of polymer flooding for improved oil recovery. Semester Project, Norwegian Univ. Sci Technol, Trondheim, NorwayGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Prashant Bhardwaj
    • 1
  • Mohammad Kamil
    • 1
  • Manorama Panda
    • 1
  1. 1.Department of Petroleum StudiesAligarh Muslim UniversityAligarhIndia

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