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Applied Physics A

, 125:606 | Cite as

Physical properties of o-LiMnO2

  • R. BagtacheEmail author
  • R. Brahimi
  • K. Abdmeziem
  • M. Trari
Article
  • 27 Downloads

Abstract

Pure o-LiMnO2 synthesized by solid-state reaction under Ar atmosphere at 850 °C crystallizes in an orthorhombic symmetry (S.G. Pmnm) with the lattice constants a = 0.2805, b = 0.5751 and c = 0.4573 nm. The UV–visible diffuse reflectance revealed a direct transition at 1.92 eV, assigned to the crystal field splitting of Mn3+ in octahedral coordination. The Raman spectroscopy of o-LiMnO2 shows the characteristic bands of Mn–O–Mn, Mn–O and LiO6. The electrical conductivity follows an exponential law. The conduction is thermally activated and increases with increasing temperature, indicating a semi-conducting behavior with activation energy of 0.68 eV.

Notes

Acknowledgements

The authors are grateful to Dr. R. Laib for his technical assistance.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • R. Bagtache
    • 1
    Email author
  • R. Brahimi
    • 2
  • K. Abdmeziem
    • 1
  • M. Trari
    • 2
  1. 1.Laboratory of Electrochemistry-Corrosion, Metallurgy and Inorganic Chemistry, Faculty of ChemistryUSTHBAlgiersAlgeria
  2. 2.Laboratory of Storage and Valorization of Renewable Energies, Faculty of ChemistryUSTHBAlgiersAlgeria

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