Applied Physics A

, 125:281 | Cite as

Structural, optical and magnetic behaviors of Fe/Mn-doped and co-doped CdS thin films prepared by spray pyrolysis method

  • R. Murugesan
  • S. SivakumarEmail author
  • K. Karthik
  • P. Anandan
  • M. Haris


CdS thin films doped and co-doped with Fe and Mn were prepared by spray pyrolysis technique and the films were portrayed by X-ray diffraction, laser Raman, XPS, FESEM with EDAX, UV–Vis, PL, and VSM analyses. The structural parameters were identified and the crystalline nature of the films was confirmed by X-ray diffraction patterns. The different optical phonon modes of vibrations present in the films were studied using laser Raman analysis. XPS analysis was used to study the binding states of electrons at various energy levels and the binding energy shift due to doping in the thin films under study was also determined. The morphology of the thin films was studied using FESEM technique and the change in the morphologies due to doping is evident from the images. To resolve the band gap of the material of the thin films before and after doping, UV–Vis absorption spectra have been recorded using UV–Vis spectrophotometer. It is found that the band gap has been tuned due to doping. PL spectral studies and VSM studies have been employed to study the luminescence and magnetic properties, respectively, with respect to the doping elements. The presence of weak ferromagnetic nature of the doped films indicates that the defects created by the doped elements induced ferromagnetic property even in the CdS thin film.



The authors are thankful to the Research Institute of Electronics, Shizuoka, Japan, for laser-Raman, FESEM and XPS characterization.


  1. 1.
    M. Gilic, J. Trajic, N. Romcevic, M. Romcevic, D.V. Timotijevic, G. Stanisic, I.S. Yahia, Optical properties of CdS thin films. Opt. Mater. 35, 1112–1117 (2013)ADSCrossRefGoogle Scholar
  2. 2.
    Y. Chang-Feng, L. Yow-Jon, L. Chia-Jyi, W. Chi-Ann, Dependences of the structural, compositional and photoluminescent properties of electrodeposited CdS films upon thermal annealing. J. Lumin. 146, 109–113 (2014)CrossRefGoogle Scholar
  3. 3.
    Y.X. Han, C.L. Yang, J.S. Yang, Effect of doping Fe and Si on electronic structure and optical properties of CdS. Phys. B 417, 17–23 (2013)ADSCrossRefGoogle Scholar
  4. 4.
    Pragati Kumar, Nupur Saxena, Ramesh Chandra, Vinay Gupta, Avinash Agarwal, Dinakar Kanjilal, Nanotwinning and structural phase transition in CdS quantum dots. Nanoscale Res. Lett. 584, 1–7 (2012)Google Scholar
  5. 5.
    B. Sajid, A. Nazar, N. Adnan, A. Zulfiqar, M. Asghri, Influence of film thickness and in-doping on physical properties of CdS thin films. J Alloys Compd. 587, 582–587 (2014)CrossRefGoogle Scholar
  6. 6.
    V. Narasimman, V.S. Nagarethinam, K. Usharani, A.R. Balu, Structural, morphological, optical and electrical properties of spray deposited ternary CdZnS thin films int. J. Thin. Film. Sci. Technol. 5, 17–24 (2016)Google Scholar
  7. 7.
    S. Thanikaikarasan, T. Mahalingam, L. Soonil, L. Hanjo, S. Velumani, R. Jin-Koo, Electrosynthesis and studies on cadmium–iron–sulphide thin films. Mater. Sci. Eng., B 174, 231–235 (2010)CrossRefGoogle Scholar
  8. 8.
    M. El-Hagary, E.R. Shaaban, M. Emam-Ismail, S. Althoyaib, Microstructural and optoelectronic properties of diluted magnetic semiconducting Cd1−xFexS nanocrystalline films. J. Alloys Compd. 520, 140–145 (2012)CrossRefGoogle Scholar
  9. 9.
    C.A. Reddy, P. Sreehith, C.S. Reddy, P.S. Reddy, A.S. Reddy, Influence of Fe-doping concentration on microstructural and magnetic properties of Fe doped Cds thin films. Chalcogenide Lett. 13, 41–45 (2016)Google Scholar
  10. 10.
    Z.K. Heiba, M.M. Bakr, N.G. Imamc, Biphasic quantum dots of cubic and hexagonal Mn-doped CdS; necessity of Rietveld analysis. J. Alloys Compd. 618, 280–286 (2015)CrossRefGoogle Scholar
  11. 11.
    N. Phasook, S. Kamoldirok, W. Yindeesuk, Optical properties of Mn-doped CdS thin films grown by the SILAR method. IOP Conf. Ser. J. Phys. Conf. Ser. 1144, 012009 (2018)CrossRefGoogle Scholar
  12. 12.
    S. Aksu, E. Bacaksiz, M. Parlak, S. Yılmaz, I. Polat, M. Altunbas, M. Türksoy, R. Topkaya, K. Ozdogan, Structural, optical and magnetic properties of Mn diffusion-doped CdS thin films prepared by vacuum evaporation Mater. Chem. Phys. 130, 340–345 (2011)Google Scholar
  13. 13.
    G. Murali, D.A. Reddy, G. Giribabu, R.P. Vijayalakshmi, R. Venugopal, Room temperature ferromagnetism in Mn-doped CdS nanowires. J Alloys Compd. 581, 849–855 (2013)CrossRefGoogle Scholar
  14. 14.
    S. Mohamed, M. Mona, A.M. El Sayed, Structural, optical, and photocatalytic properties of the spray deposited nanoporous CdS thin films; influence of copper doping, annealing, and deposition parameters. Mat. Sci. Semicon. Proc. 56, 329–343 (2016)CrossRefGoogle Scholar
  15. 15.
    M. Ligang, A. Xiaoqian, W. Xiaoshan, Effect of substrate and Zn doping on the structural, optical and electrical properties of CdS thin films prepared by CBD method. J. Alloys and Compd. 691, 399–406 (2017)CrossRefGoogle Scholar
  16. 16.
    A.J. Khimani, S.H. Chaki, T.J. Malek, J.P. Tailor, S.M. Chauhan, M.P. Deshpande, Cadmium sulphide (CdS) thin films deposited by chemical bath deposition (CBD) and dip coating techniques—a comparative study. Mater. Res. Express 5, 3 (2018)CrossRefGoogle Scholar
  17. 17.
    S. Rondiya, A. Rokade, A. Funde, M. Kartha, H. Pathan, S. Jadkar, Synthesis of CdS thin films at room temperature by RF-magnetron sputtering and study of its structural, electrical, optical and morphology properties. Thin Solid Films 631, 41–49 (2017)ADSCrossRefGoogle Scholar
  18. 18.
    H.I. Salim, O.I. Olusola, A.A. Ojo, K.A. Urasov, M.B. Dergacheva, I.M. Dharmadasa, Electrodeposition and characterisation of CdS thin films using thiourea precursor for application in solar cells. J. Mater. Sci. Mater. El. 27, 6786–6799 (2016)CrossRefGoogle Scholar
  19. 19.
    B. Neetu, G.C. Mohanta, K. Singh, Effect of Mn2+ and Cu2+ co-doping on structural and luminescent properties of ZnS nanoparticles. Ceram. Int. 43, 7193–7201 (2017)CrossRefGoogle Scholar
  20. 20.
    G.S. Harish, P.S. Reddy, Synthesis and characterization of Ce Cu co-doped ZnS nanoparticles. Phys. B 473, 48–53 (2015)ADSCrossRefGoogle Scholar
  21. 21.
    L. Kewei, J.Y. Zhang, W. Xiaojie, L. Binghui, L. Bingsheng, L. Youming, F. Xiwu, S. Dezhen, Fe-doped and (Zn, Fe) co-doped CdS films: could the Zn doping affect, the concentration of Fe2+ and the optical properties? Phys. B 389, 248–251 (2007)CrossRefGoogle Scholar
  22. 22.
    S. Yılmaz, S.B. Töreli, İ. Polat, M.A. Olgar, M. Tomakin, E. Bacaksız, Enhancement in the optical and electrical properties of CdS thin films through Ga and K co-doping. Mat. Sci. Semicon. Proc. 60, 45–52 (2017)CrossRefGoogle Scholar
  23. 23.
    S. Yılmaz, Y. Atasoy, M. Tomakin, E. Bacaksız, Comparative studies of CdS, CdS: Al, CdS: Na and CdS:(Al–Na) thin films prepared by spray pyrolysis. Superlattice. Microst. 88, 299–307 (2015)ADSCrossRefGoogle Scholar
  24. 24.
    T. Sivaraman, V.S. Nagarethinam, A.R. Balu, Structural, morphological, optical and electrical properties of CdS thin films simultaneously doped with magnesium and chlorine. J. Mater. Sci.: Mater. Electron. 27, 1158–1164 (2016)Google Scholar
  25. 25.
    K. Karthik, S. Dhanuskodi, C. Gobinath, S. Prabukumar, S. Sivaramakrishnan, Andrographis paniculata extract mediated green synthesis of CdO nanoparticles and its electrochemical and antibacterial studies. J. Mater. Sci: Mater. Electron. 28, 1–11 (2017)Google Scholar
  26. 26.
    R. Sachin, R. Avinash, G. Bharat, P. Subhash, C. Madhavi, D. Abhijit, C. Minakshi, P. Habib, J. Sandesh, Effect of bath temperature on optical and morphology properties of CdS thin films grown by chemical bath deposition. Energy Procedia 110, 202–209 (2017)CrossRefGoogle Scholar
  27. 27.
    M.F. Saleem, H. Zhang, Y. Deng, D. Wanga, Resonant Raman scattering in nanocrystalline thin CdS film. J. Raman Spectrosc. 48, 224–229 (2016)ADSCrossRefGoogle Scholar
  28. 28.
    A. Firdous, M.A. Baba, D. Singh, A.H. Bhat, Optical and impedance studies of pure and Ba doped ZnS quantum dot. Appl. Nanosci. 5, 201–206 (2015)ADSCrossRefGoogle Scholar
  29. 29.
    J. Tauc, Amorphous and liquid semiconductors (Plenum, New York, 1974)CrossRefGoogle Scholar
  30. 30.
    R. Murugesan, S. Sivakumar, P. Anandan, M. Haris, Structural, optical and magnetic properties of Ba and Ni-doped CdS thin films prepared by spray pyrolysis method. J. Mater. Sci. Mater. Electron. 28(17), 12432–12439 (2017)CrossRefGoogle Scholar
  31. 31.
    Y. Belghazi, G. Schmerber, S. Colis, J.L. Rehspringer, A. Berrada, A. Dinia, Room-temperature ferromagnetism in Co-doped ZnO thin films prepared by sol-gel method. J. Magn. Magn. Mater. 310, 2092–2094 (2007)ADSCrossRefGoogle Scholar
  32. 32.
    A. Lewicki, A.I. Schinder, J.K. Furdyna, W. Giriat, Magnetic susceptibility of Zn1−xCoxS and Zn1−xCoxSe alloys. Phys. Rev. B. 40, 2379–2382 (1989)ADSCrossRefGoogle Scholar
  33. 33.
    Y.D. Reddy, D.S. Reddy, B.K. Reddy, R.V.S.S.N. Ravikumar, D.R. Reddy, DC-magnetic susceptibility and EPR studies of vapour phase grown Cd1−xCoxTe crystals. J. Alloys Compd. 470, 12–15 (2009)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • R. Murugesan
    • 1
    • 2
  • S. Sivakumar
    • 2
    Email author
  • K. Karthik
    • 3
  • P. Anandan
    • 1
  • M. Haris
    • 4
  1. 1.Department of PhysicsThiru Kolanjiappar Government Arts CollegeVriddhachalamIndia
  2. 2.Department of PhysicsGovernment Arts College (Autonomous)SalemIndia
  3. 3.School of PhysicsBharathidasan UniversityTiruchirappalliIndia
  4. 4.Department of PhysicsKarunya Institute of Technology and SciencesCoimbatoreIndia

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