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Applied Physics A

, 125:156 | Cite as

Investigation of crystal structure and improved magnetic and dielectric properties of Ti-substituted Bi0.90Ho0.10FeO3 multiferroics

  • Jogender Singh
  • Ashish Agarwal
  • Sujata SanghiEmail author
  • Manisha Yadav
  • Tanvi Bhasin
  • Umesh Bhakar
Article
  • 18 Downloads

Abstract

Bi0.90Ho0.10Fe1−xTixO3 multiferroics (with x = 0.00, 0.05, 0.10, and 0.15) were synthesized by method of solid state reaction. The XRD, SEM, dielectric properties, and magnetic measurements of the compounds were carried out. The X-ray patterns show structural change for x = 0.15. Rietveld refinement of the XRD patterns deduces that the samples for x = 0.00, 0.05, and 0.10 are found to fit well with rhombohedral R3c symmetry, while for x = 0.15, sample accomplishes best fitting by the mixed-phase setting of rhombohedral R3c and triclinic P1 space group. The micro-Raman scattering observation also confirms the phase transformation. The change in crystal structure is attributed to the distortion of FeO6 octahedra due to replacing a part of B-site Fe ions by Ti ions. Magnetic measurements were performed at room temperature up to an external magnetic field of ± 10 kOe. Dielectric behaviour of all prepared ceramic samples was carried by impedance/gain phase analyser within the frequency range from 100 Hz to 7 MHz at different temperatures. It was observed that the Ti co-doping shows a significant role for the improving multiferroics properties.

Notes

Acknowledgements

We gratefully acknowledge Department of Science and Technology, Government of India for providing XRD facility through FIST scheme. We thank Dr. Bhupendra Kumar Chudasama, Thapar University, School of Physics and Materials Science, Patiala for access to VSM facility. SS is also thankful to DST, New Delhi for providing funds under PURSE program no. SR/PURSE Phase 2/40(G). J. Singh is thankful to University Grant Commission (UGC), India for providing JRF.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Jogender Singh
    • 1
  • Ashish Agarwal
    • 1
  • Sujata Sanghi
    • 1
    Email author
  • Manisha Yadav
    • 1
  • Tanvi Bhasin
    • 1
  • Umesh Bhakar
    • 1
  1. 1.Department of PhysicsGuru Jambheshwar University of Science and TechnologyHisarIndia

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