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Applied Physics A

, 125:92 | Cite as

Electrical properties and scaling studies of Na3+x ZrxSc2−x(PO4)3 glass ceramic electrolyte for use in Na-ion batteries

  • Shyam Sundar Gandi
  • Suman Gandi
  • Naresh Kumar Katari
  • Dimple P. Dutta
  • Balaji Rao RavuriEmail author
Article
  • 11 Downloads

Abstract

Na-ion conducting Na3+x[ZrxSc2−x(PO4)3] (x = 0, 0.25, 0.5 and 0.75 mol%) glass samples with NASICON-type phase were synthesized by melt quenching method and glass–ceramics were formed by heat treating the precursor glasses at their crystallization temperatures. The major and minor crystalline phases such as [Na3Sc2(PO4)3 (ICSD-27740) (NASICON), ZrP2O7 (ICSD-15084), ZrO2 (ICSD-66781) and Zr2O(PO4)2 (ICSD-1922)] are precipitated in all the glass–ceramic samples. The best bulk conductivity has been observed for Na3.5Zr0.5Sc1.5(PO4)3 glass–ceramic sample (σb = 1.92 × 10−4 S/cm) which exhibits lowest activation energy of 0.492 eV. The single master curve in the scaling analysis revealed that this glass samples show evidence of temperature-independent conduction transport mechanism.

Notes

Acknowledgements

This work has been funded by Board of Research in Nuclear Sciences (BRNS), Department of Atomic Energy (DAE), Govt. of INDIA, Grant no.: 34/14/06/2018-BRNS/34082. The authors thank Dr. K.S Rama Rao, Sr. Principal Scientist, CSIR-Indian Institute of Chemical Technology, Hyderabad, India for kindly extending the facility to acquire SEM micrographs.

Compliance with ethical standards

Conflict of interest

The authors declare no competing financial interest.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Shyam Sundar Gandi
    • 1
  • Suman Gandi
    • 1
  • Naresh Kumar Katari
    • 2
  • Dimple P. Dutta
    • 3
  • Balaji Rao Ravuri
    • 1
    Email author
  1. 1.High Energy Materials Research Laboratory, Department of physics, School of TechnologyGITAM Deemed to be UniversityHyderabadIndia
  2. 2.Department of Chemistry, School of TechnologyGITAM Deemed to be UniversityHyderabadIndia
  3. 3.Chemistry DivisionBhabha Atomic Research CentreMumbaiIndia

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