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Polymer Bulletin

, Volume 76, Issue 2, pp 595–613 | Cite as

Photophysical properties of new fluorene-based conjugated polymers containing polyphenylene-substituted dendronized core

  • Rupashri K. Kadu
  • Pramod B. Thakur
  • Vishwanath R. PatilEmail author
Original Paper

Abstract

Rapid synthesis of new fluorene-based conjugated polymers P1P8 is reported by polymerization of polyphenylene-substituted dendronized monomer 2,7-dibromo-9,9-di(4-(2,3,4,5-tetraphenylphenyl)-benzyl) fluorene (M1) and 2,7-dibromo-9,9-di(4-pentaphenylphenyl)-benzyl) fluorene (M2) with different 9,9-disubstituted 2,7-dibromo fluorene monomers (M3M6) under microwave irradiation. The structure of these synthesized polymers P1P8 was established by FTIR, 1H NMR, 13C NMR, and gel permeation chromatography techniques. The photophysical studies of these polymers P1P8 shows good results desirable for light-emitting material. These polymers exhibited UV–Vis absorption peak with the maxima in 344–386 nm in THF solution. Similarly, the fluorescence spectra of these polymers showed PL maxima in 414–418 nm with shoulder peak in 437–440 nm. From this study, the stoke shifts was observed in 30–73 nm, and quantum efficiency was found in 0.41–0.57. Polymers had thermal stability up to 200 °C; however, for dihexyl-substituted dendronized polymer, P1 and P5 showed thermal decomposition at 490 and 430 °C, respectively. In addition to this, polymers P1P8 were also analyzed by electrochemical study in which the onset of the irreversible oxidation wave of dendronized polymers P1P8 is recorded in the range of 0.88–0.99 V. The results of these various studies showed that the synthesized polymers P1P8 can be promising materials for blue-light-emitting diodes because of their high photoluminescence (PL), quantum efficiencies, and thermal stability.

Keywords

Fluorene Polyphenylene Dendrimers Microwave chemistry Polymerization 

Notes

Acknowledgements

The author (RKK) would like to acknowledge the University of Mumbai, for providing the financial support under the UGC scheme.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

289_2018_2401_MOESM1_ESM.docx (3.1 mb)
Electronic Supplementary information can be found in the online version of this article (DOCX 3166 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Rupashri K. Kadu
    • 1
  • Pramod B. Thakur
    • 2
  • Vishwanath R. Patil
    • 1
    Email author
  1. 1.Department of ChemistryUniversity of MumbaiSantacruz (E), MumbaiIndia
  2. 2.Department of Chemistry, Rayat Shikshan Sanstha’sMahatma Phule Arts, Science and Commerce CollegePanvel, District-RaigadIndia

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