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Polymer Bulletin

, Volume 76, Issue 1, pp 469–494 | Cite as

An escalation of anticorrosion and microelectrical properties of polyurethane nanocomposites from green Brassica nigra oil

  • V. SelvarajEmail author
  • T. R. Rhagavarshini
  • K. Krishnadevi
Original Paper
  • 60 Downloads

Abstract

Brassica nigra oil-based polyurethane composites have been synthesized and characterized by various analytical techniques such as Fourier transform infrared, NMR, X-ray diffraction, scanning electron microscope, atomic force microscopy, DSC and TGA. Broadband dielectric spectroscopy confirms the improvement in the dielectric properties of the prepared composites (AGO/BNP/PH) with respect to increasing AGO content. The analytical results conclude that graphene oxide-reinforced Brassica nigra oil-based polyurethane nanocomposites show improved thermal, Tg, dielectric constant and decreased dielectric loss with respect to different ratios of amine-functionalized graphene oxide. Further, the corrosion resistance behavior analysis results conclude that the prepared bio-composites have excellent corrosion-resistant property (96.93%) compared to neat Brassica nigra oil-based polyurethane polymer, which can be used as coating material for marine and also in microelectronic applications.

Keywords

Brassica nigra oil (BNO) Methylene diphenyl diisocyanate (MDI) Amine-functionalized graphene oxide (AGO) Polyurethane 

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • V. Selvaraj
    • 1
    Email author
  • T. R. Rhagavarshini
    • 1
  • K. Krishnadevi
    • 2
  1. 1.Nanotech Research Laboratory, Department of ChemistryUniversity College of Engineering Villupuram (A Constituent College of Anna University, Chennai-25)VillupuramIndia
  2. 2.Department of ChemistryVignan UniversityGunturIndia

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