Summary
Epoxy resin/CdS nanocomposite was prepared by a novel method and its cure behavior was investigated by the HLX-II Resin Curemeter based on the dynamic torsional vibration method (DTVM). The non-equilibrium thermodynamic fluctuation theory, the Avrami equation and the Flory’s gelation theory have been used to analysis the cure behavior of the composite systems with different CdS and cure agent loadings at various temperatures. The results show that the addition of CdS nanoparticles reduces the gel time t g , but has little effect on the mechanism of the cure reaction. The theoretical prediction is in good agreement with the experimental results. The Avrami exponent of n decreases a little when the temperature increases.
Similar content being viewed by others
References
Winiarz JG, Zhang LM, Lal MN (1999) J Am Chem Soc 121:5287
Pyun L, Matyjaszewski K (2001) Chem Mater 13:3436
Moffitt M, Vali H, Eisenberg A (1998) Chem Mater 10:1021
Albrecht TT, Schotter J, Kastle (2000) Science 290:2126
Dabbousi BO, Bawendi MG, Onitsuka O (1995) Appl Phys Lett 66:1316
Gonsalves KE, Carlson G, Chen X (1996) Nanostruct Mater 3:293
Ho PKH, Friend RH (2002) J Chem Phys 116:6782
Chen XG, Yang CL, Qin JG (2002) J Incl Phenom Macro 42:71
Brown JM, Curliss D and Vaia RA (2000) Chem Mater 12:3376
Lee DC, Jang LW (1998) J Appl Polym Sci 68:1997
Hsiue GH, Liu YL, Liao HH (2001) J Polym Sci A 39:986
Zerda AS, Lesser AJ (2001) J Polym Sci B 39:1137
Weller H (1993) Ange Chem Int Ed. Engl 32:41
Pan LJ, Chen DZ, He PS, Zhu X, Weng LQ (2004) Mater Res Bull 39:243
Pan LJ, He PS, Zou G, Chen DH (2003) Mater Lett 58:176
Pan LJ, Wu XS, Zou G, He PS, Zhu X (2004) Mater Res Bull 39:1
Stevens GC(1981) J Appl Polym Sci 26: 4279
Sacher E (1973) Polymer 14: 91
Xu WB, He PS, Chen DZ (2003) Eur Polym J 39:617
Chen DZ, He PS, Pan LJ (2003) Polym Test 22:689
He PS, Li CE (1999) Modern Scientific Instruments 6:17 Chin
He PS, Li CE (1991) J Appl Polym Sci 43:1011
Chen DZ, He PS (2003) J Compos Mater 37:1275
Zou G, Fang K, He PS (2002) J Mater Sci Lett 21:761
Xu WB, He PS (2001) J Func Polym 14 (3):66
Chen DZ, He PS (2004) Compos Sci Technol 64:2501
Hsich HS-Y(1982) J Appl Sci 27:3265
Avrami M (1940) J Chem Phys 8:212
Lu MG, Shim MJ, Kim SJ (1999) J Therm Anal Calorim 58:701
Flory PJ, (1953) Principles of Polymer Chemistry. New York: Cornell University Press
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yuan, Y., Dazhu, C., Pingsheng, H. et al. Cure behavior of epoxy resin/CdS/2,4-EMI nanocomposites investigated by dynamic torsional vibration method (DTVM). Polym. Bull. 57, 219–230 (2006). https://doi.org/10.1007/s00289-006-0550-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00289-006-0550-2