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Effect of polymeric diisocyanate addition on bonding performance of a demethylated-pyrolysis-oil-based adhesive

  • Alexandre Santos PimentaEmail author
  • Rosilani Trianoski
  • Antonio Pizzi
  • Francisco Jose Santiago-Medina
  • Elias Costa de Souza
  • Thays Vieira da Costa Monteiro
  • Maíra Fasciotti
  • Renato Vinicius Oliveira Castro
Original
  • 29 Downloads

Abstract

After demethylation, eucalyptus pyrolysis oil has higher reactivity with formaldehyde in alkaline media than the raw oil. The objective of the present work was to evaluate the effect of adding polymeric diphenylmethane diisocyanate (PMDI) on a demethylated oil-based adhesive. Chemical composition of pyrolysis oil was determined by gas chromatography/mass spectrometry. Before and after demethylation, the eucalyptus pyrolysis oil was analyzed by carbon-13 nuclear magnetic resonance spectroscopy (13C NMR) and matrix-assisted laser desorption ionization-time of flight (MALDI-TOF). Demethylated oil-based adhesive was analyzed by MALDI-TOF. Plywood panels were produced with adhesives supplemented with 0, 4, 8, 16 and 20% PMDI and an extra treatment applying a reference phenolic adhesive. The experiment encompassed six treatments with four replicates, totaling 24 panels. As demonstrated by nuclear magnetic resonance analysis, the demethylation reaction was effective in removing methyl groups from the methoxyls of syringol and derivatives, turning them, respectively, into pyrogallol and its derivatives. PMDI was effective as a cross-linking agent, enhancing the mechanical performance of the original demethylated-pyrolysis-oil adhesive. In dry condition and after boiling test, plywood manufactured with formulations adding 16 and 20% PMDI had shear strengths statistically equal to panels bonded with the reference phenolic adhesive.

Notes

Acknowledgements

This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior-Brazil (CAPES), finance code 001. We are grateful to Ibiré Negócios Sustentáveis Ltda (www.ibire.com.br) for financial support and as well for supplying analytical material and chemical reagents.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Agricultural Sciences Academic Unit, Forest EngineeringFederal University of Rio Grande do Norte (UFRN)NatalBrazil
  2. 2.Laboratory of Wood Panels, Department of Forest EngineeringFederal University of Paraná (UFPR)CuritibaBrazil
  3. 3.Ecole Nationale Supérieure des Technologies et Industries du Bois (ENSTIB-LERMAB)University of LorraineÉpinalFrance
  4. 4.Laboratory of Organic AnalysisNational Institute of Metrology, Quality and TechnologyDuque de CaxiasBrazil
  5. 5.Department of Agricultural SciencesFederal University of São João del-Rei (UFSJ)São João del-ReiBrazil

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